# US 5,351,164 A · Electrolytic double layer capacitor

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- Number: US 5,351,164 A
- Document ID: US5351164A
- Status: Granted
- Kind: A
- Application number: 07/968,185
- Filed: 1992-10-29
- Granted: 1994-09-27
- Earliest claimed: 1991-10-29
- Assignees: T.N. Frantsevich Institute for Problems in Materials Science
- Inventors: Ivan I. Grigortchak; Kornei D. Tovstjuk; Zahar D. Kovalyuk; Ivan D. Kozmik; Bogdan P. Bahmatyuk
- Web page: https://patentgrep.com/patent/US5351164A

## CPC

- H01G 11/14: Arrangements or processes for adjusting or protecting hybrid or EDL capacitors (emergency protective circuit arrangements specially adapted for capacitors, and effecting automatic switching in the event of an undesired change from normal working conditions H02H7/16; emergency protective circuit arrangements for limiting excess current or voltages without disconnection H02H9/00)
- H01G 11/24: characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
- H01G 11/30: characterised by their material
- H01G 11/62: characterised by the solute, e.g. salts, anions or cations therein
- H01M 4/581: {Chalcogenides or intercalation compounds thereof}
- Y02E 60/10: Energy storage using batteries
- Y02E 60/13: Energy storage using capacitors
- H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10)
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A double layer electrolytic capacitor of two electrodes each in contact with a common electrolyte. At least one of the electrodes is comprised of a crystalline material characterized by the presence of van der Waals channels in the material. These van der Waals channels are adapted to accommodate the electrolyte within the channels, such that a double layer of charge is formed at interfaces of the van der Waals channels and the electrolyte when a voltage is applied between the two electrodes.

## Claims

### Claim 1

A double layer electrolytic capacitor comprising two electrodes each in contact with a common liquid electrolyte, at least one of said electrodes comprising a crystalline material characterized by the presence of van der Waals channels, the van der Waals channels being adapted to accommodate the electrolyte within the channels, whereby a double layer of charge is formed at interfaces of the van der Waals channels and the electrolyte when a voltage is applied between the two electrodes.

### Claim 2

The capacitor of claim I wherein both electrodes comprise said crystalline material.

### Claim 3 (depends on 2)

The capacitor of claim 2 wherein said two electrodes each comprise a monocrystal of said crystalline material.

### Claim 4 (depends on 2)

The capacitor of claim 2 wherein said two electrodes each comprise monocrystalline powder particles of said crystalline material.

### Claim 5 (depends on 2)

The capacitor of claim 2 wherein said crystalline material is a bismuth chalcogenide.

### Claim 6 (depends on 2)

The capacitor of claim 2 wherein said crystalline material comprises a solid solution of Bi.sub.x (Te.sub.3-y Se.sub.y), where x is 1 or 2, and y is 0-3.

### Claim 7 (depends on 2, 5)

The capacitor of either of claims 2 or 5 wherein said electrolyte comprises a 1.0 M LiClO.sub.4 solution in propylene carbonate.

### Claim 8 (depends on 2, 5)

The capacitor of either of claims 2 or 5 wherein said electrolyte comprises a 1.2 M solution of organic cation of perchlorate in a mixture of propylene carbonate in dimethoxyethane.

### Claim 9 (depends on 2)

The capacitor of claim 2 wherein said electrolyte comprises an aqueous solution of potassium hydroxide.

### Claim 10 (depends on 2)

The capacitor of claim 2 wherein said electrolyte comprises an aqueous solution of single valence metal sulphates.

### Claim 11

The capacitor of claim I wherein one of said electrodes comprises an electrically conducting container in which said electrolyte and said other electrode are positioned.

### Claim 12 (depends on 4)

The capacitor of claim 4 wherein said monocrystalline powder comprises monocrystalline particles of approximately 70 microns in a largest dimension.

### Claim 13 (depends on 12)

The capacitor of claim 12 further comprising a binding agent for binding together said monocrystalline powder particles.

### Claim 14 (depends on 13)

The capacitor of claim 13 wherein said binding agent comprises 5% polyethylene dispersed in acetone.

### Claim 15 (depends on 13)

The capacitor of claim 13 wherein said binding agent comprises a 3% carboxymethylcellulose solution in water.

### Claim 16 (depends on 2, 5)

The capacitor of either of claims 2 or 5 wherein said van der Waals channels are adapted to accommodate the electrolyte by a training process comprising intercalation of the electrolyte into the van der Waals channels.

### Claim 17 (depends on 16)

The capacitor of claim 16 wherein said intercalation is produced by the application of a voltage between said electrodes, said voltage being sufficiently high to achieve solvated ionic complex penetration of said channels.

### Claim 18 (depends on 17)

The capacitor of claim 17 wherein said voltage is periodically reversed in polarity between the electrodes.

### Claim 19 (depends on 18)

The capacitor of claim 18 wherein said voltage is increased over time from a first voltage sufficient to produce faradaic processes in the electrolyte to a second voltage sufficient to achieve electrolyte penetration of said channels.

### Claim 20 (depends on 19)

The capacitor of claim 19 wherein said voltage is applied to said electrodes for approximately 600 minutes.

### Claim 21 (depends on 20)

The capacitor of claim 20 wherein said voltage is reversed in polarity approximately every 30 minutes.

### Claim 22 (depends on 18)

The capacitor of claim 18 wherein said capacitor is periodically discharged across a resistive load.