# US 5,350,540 A · Method of making alkaline earth metal halophosphate phosphor using metal phosphide reducing agent

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- Number: US 5,350,540 A
- Document ID: US5350540A
- Status: Granted
- Kind: A
- Application number: 08/104,229
- Filed: 1993-08-09
- Granted: 1994-09-27
- Earliest claimed: 1992-10-22
- Assignees: Osram Sylvania Inc.
- Inventors: Chung-Nin Chau
- Web page: https://patentgrep.com/patent/US5350540A

## CPC

- C09K 11/76: also containing phosphorus and halogen, e.g. halophosphates
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

Metal phosphide used as a raw material in the synthesis of alkaline earth metal halophosphate phosphor activated by antimony and manganese acts as a reducing agent to prevent oxidation of the antimony and manganese. The result is maximum availability of trivalent antimony and divalent manganese for incorporation into the phosphor lattice.

## Claims

### Claim 1

A method of improving the brightness of a calcium chlorofluoroapatite phosphor activated with antimony and manganese, comprising the steps of: forming a uniform mixture of calcium hydrogen phosphate, calcium carbonate, calcium fluoride, a source of chloride, manganese carbonate, antimony trioxide, and from about 0.001 to about 0.0035 mole of zinc phosphide, said zinc phosphide being in an amount sufficient to reduce any pentavalent antimony to the trivalent state and any tetravalent manganese to the divalent state and to maintain antimony and manganese in the trivalent and divalent states, respectively; firing said mixture at 1150.degree. C. for two hours in a nitrogen atmosphere to obtain a phosphor cake; washing said phosphor cake in a weakly acidic solution and then in a weakly basic solution to obtain a washed phosphor; and drying and screening said phosphor, said phosphor exhibiting a higher brightness than the phosphor prepared as above, absent zinc phosphide.

### Claim 2 (depends on 1)

A method according to claim 1 wherein said source of chloride is ammonium chloride.

### Claim 3 (depends on 1)

A method according to claim 1 wherein said source of chloride is calcium chlorospodiosite.