# US 5,350,430 A · Oil/coal coprocessing in which agglomerated coal forms part of feedstock

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- Number: US 5,350,430 A
- Document ID: US5350430A
- Status: Granted
- Kind: A
- Application number: 08/190,984
- Filed: 1994-02-03
- Granted: 1994-09-27
- Earliest claimed: 1992-08-27
- Assignees: Energy, Mines and Resources Canada
- Inventors: Richard D. Coleman; Floyd N. Toll; Thomas W. McCracken; C. Edward Capes; Michio Ikura
- Web page: https://patentgrep.com/patent/US5350430A

## CPC

- C10L 5/06: Methods of {shaping, e.g. pelletizing or} briquetting (mechanical part of pressing briquettes B30B11/00)
- C10G 47/00: Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06)
- C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

An improved process is described for agglomerating ground coal in which a bridging oil is used as the agglomerating vehicle. This bridging oil is a mixture of a heavy gas oil obtained from coal/oil coprocessing and a heavy hydrocarbon oil, such as bitumen or heavy oil, preferably mixed in the proportion of about 23-40% heavy hydrocarbon oil and 60-77% heavy gas oil. The agglomerated product is mixed with additional heavy oil or bitumen and it becomes the feedstock to a coal/oil coprocessor, with heavy gas oil being formed as one of the product streams. At least part of this heavy gas oil product stream is recycled to the agglomeration stage as the heavy gas oil component of the bridging oil. This agglomeration procedure has the advantage of providing an agglomerate of excellent quality, while carrying out the agglomeration in a short time at ambient temperature and using less than 10% by weight of bridging oil.

## Claims

### Claim 1

In a coal/oil process in which a feed slurry comprising a mixture of (a) a heavy hydrocarbon oil at least 50% by weight of which boils above 525.degree. C. and (b) an agglomerated product comprising coal particles and a bridging liquid, is subjected to hydrocracking and the effluents obtained are separated into separate streams including a heavy gas oil stream,
the improvement which comprises forming the agglomerated product by mixing at ambient temperature and pressure an aqueous slurry of low rank coal particles with less than 10% by weight of a bridging liquid which is a mixture of (i) about 60-77% by weight of heavy gas oil obtained from said coal/oil process and boiling in the range of 335.degree.-525.degree. C. and (ii) about 23-40% by weight of said heavy hydrocarbon oil feed, to thereby form agglomerates of said coal particles and separating the agglomerated coal particles from tailings containing mineral matter.

### Claim 2 (depends on 1)

A process as claimed in claim 1 wherein the bridging liquid is a mixture containing about 60-75% by weight of said heavy gas oil and about 25-40% by weight of said heavy hydrocarbon oil.

### Claim 3 (depends on 1)

A process as claimed in claim 1 wherein the bridging liquid is a mixture containing about 66-75% by weight of said heavy gas oil and about 25-34% by weight of said heavy hydrocarbon oil.

### Claim 4 (depends on 1)

A process as claimed in claim 1 wherein the hydrocracking is carried out in the presence of a catalyst.

### Claim 5 (depends on 4)

A process as claimed in claim 4 wherein the hydrocracking is carried out in a confined hydrocracking zone maintained at a temperature above 400.degree. C., a pressure of at least 1.4 MPa and a space velocity between about 0.5 and 4 volumes of hydrocarbon oil per hour per volume of reaction zone capacity.