# US 5,348,820 A · Zinc electrode for alkaline storage battery

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- Number: US 5,348,820 A
- Document ID: US5348820A
- Status: Granted
- Kind: A
- Application number: 08/089,750
- Filed: 1993-07-09
- Granted: 1994-09-20
- Earliest claimed: 1992-07-10
- Assignees: Nippon Oil Co., Ltd.
- Inventors: Masanobu Suga; Seiichi Akita; Nobuyuki Kuroda
- Web page: https://patentgrep.com/patent/US5348820A

## CPC

- H01M 4/244: {Zinc electrodes}
- Y02E 60/10: Energy storage using batteries
- Y10T 29/49115: including coating or impregnating
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A negative zinc electrode for an alkaline storage battery capable of suppressing the occurrence of dendrite and shape change is provided. The negative zinc electrode comprises an electrode using zinc as an active material and a polymer layer formed substantially in direct contact with the electrode, the polymer layer comprising a polymer having an oxygen permeability constant of not less than 1.times.10.sup.-10 cm.sup.3 (STP) cm.sup.-1 s.sup.-1 cmHg.sup.-1.

## Claims

### Claim 1

A negative zinc electrode for an alkaline storage battery, comprising an electrode using zinc as an active material and a polymer layer coated on said electrode, said polymer layer comprising a polymer having an oxygen permeability constant of not less than 1.times.10.sup.-10 cm.sup.3 (STP) cm.sup.-1 s.sup.-1 cmHg.sup.-1.

### Claim 2 (depends on 1)

A negative zinc electrode as set forth in claim 1, wherein the polymer layer comprises at least two kinds of polymers.

### Claim 3 (depends on 1)

A negative zinc electrode as set forth in claim 1, wherein the polymer is a polymer having a molecular weight of about 1,000 to about 2,000,000 and is selected from the group consisting of polydimethylsiloxanes, polyorganosiloxanes, polyvinyltriorganosiloxanes, polyalkylsulfones, poly(4-methylpentene-1), poly(2,6-dimethylphenylene oxide) and low-density polyethylenes.

### Claim 4 (depends on 1)

A negative zinc electrode as set forth in claim 1, wherein the polymer comprises at least one functional group introduced therein, the functional group is selected from the group consisting of --COOH, --CN, --CONH.sub.2 and --N.sup.+ R.sub.3 wherein R is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and the functional group is introduced in the polymer in a proportion of 1 to 50 units for 10 monomer units of the polymer.

### Claim 5 (depends on 3)

A negative zinc electrode as set forth in claim 3, wherein the polymer contains a further polymer is an amount sufficient to decrease an internal impedance, said further polymer exhibiting an ion conductivity of 10.sup.-3 to 10.sup.1 S/cm in a fully swollen condition in an electrolyte.

### Claim 6 (depends on 5)

A negative zinc electrode as set forth in claim 5, wherein said further polymer is polyvinyl alcohol, carboxymethyl cellulose, polyacrylonitrile, polyacrylic acid, polymethacrylic acid, polyacrylate, polymethacrylate, polyvinylpyrrolidine, polyparabanic acid, polyoxazoline, or polyethylene oxide.

### Claim 7

A method for making a negative zinc electrode for an alkaline storage battery, comprising the steps of forming on a zinc electrode a coating containing at least a polymer precursor which is in the state of a sol and then causing gelation of the polymer precursor sol to form a polymer layer coated on the zinc electrode, said polymer layer having an oxygen permeability constant of not less than 1.times.10.sup.-10 cm.sup.3 (STP) cm.sup.-1 s.sup.-1 cmHg.sup.-1.

### Claim 8 (depends on 1)

An alkaline storage battery comprising the negative zinc electrode described in claim 1, a separator, a positive electrode and an electrolyte.