# US 5,348,816 A · Alkaline battery

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 5,348,816 A
- Document ID: US5348816A
- Status: Granted
- Kind: A
- Application number: 07/896,969
- Filed: 1992-06-11
- Granted: 1994-09-20
- Earliest claimed: 1991-06-11
- Assignees: Fuji Electrochemical Co., Ltd.
- Inventors: Kenichi Shinoda; Akihide Izumi; Kiyohide Tsutsui; Katsuhiro Yamashita; Hidenori Tsuzuki; Takashi Matsuo
- Web page: https://patentgrep.com/patent/US5348816A

## CPC

- H01M 6/06: Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
- H01M 4/12: of consumable metal or alloy electrodes (use of alloy compositions as active materials H01M4/38)
- H01M 4/62: Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M 4/02: Electrodes composed of, or comprising, active material
- H01M 2004/027: {Negative electrodes}
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

## Abstract

A method for producing a gel form negative electrode of an alkaline battery while avoiding use of mercury enables uniform dispersion of zinc or zinc alloy powder and an effective metal which can be one or more of an oxide or hydroxide of indium, lead, gallium, bismuth, by stirring for a substantially reduced period. The method employs dry mixing of the zinc or zinc alloy powder and the effective metal in advance of mixing with a gel form alkaline electrolyte. Also, in order to obtain satisfactorily high vibration strength and impact resistance, fiber material can be added to the gel form negative electrode. The fiber material may be selected among rayon, vinylon, acryl, vinyon, polyamide, polypropylene, polyethylene, mercerized pulp, linter pulp.

## Claims

### Claim 1

A method for producing a gel form negative electrode for an alkaline battery, said method comprising the steps of:
preparing by dry mixing a dry mixture of one or more of an oxide or hydroxide of indium, lead, gallium and bismuth and zinc or zinc alloy powder;
putting said dry mixture into a gel form alkaline electrolyte; and
mixing and dispersing said dry mixture in the gel form alkaline electrolyte.

### Claim 2 (depends on 1)

A method as set forth in claim 1, wherein said step of preparing said dry mixture is performed by dry mixing one or more of said metal oxide or metal hydroxide, said zinc or zinc alloy powder and a powder state gelling agent.

### Claim 3 (depends on 2)

A method as set forth in claim 2, wherein said alkaline electrolyte is a potassium hydroxide electrolyte.

### Claim 4 (depends on 1)

A method as set forth in claim 1, wherein said alkaline electrolyte is a potassium hydroxide electrolyte.

### Claim 5 (depends on 1)

A method as set forth in claim 1, wherein said step of mixing and dispersing is performed at least for five minutes.

### Claim 6 (depends on 5)

A method as set forth in claim 5, wherein said step of mixing and dispersing is performed for about ten minutes.

### Claim 7 (depends on 1)

A method as set forth in claim 1, wherein said step of preparing said dry mixture is performed by mixing one or more of said metal oxide or metal hydroxide and said zinc or zinc alloy powder for approximately 60 seconds.

### Claim 8

A method for producing a gel form negative electrode of an alkaline battery, said method comprising the steps of:
preparing a gel form alkaline electrolyte by mixing a potassium hydroxide electrolyte and polyacrylic acid;
preparing by dry mixing a dry mixture of a zinc or zinc alloy powder and indium oxide;
putting said dry mixture into said gel form alkaline electrolyte; and
stirring said gel form alkaline electrolyte with said dry mixture therein and thereby mixing and dispersing said dry mixture therein.

### Claim 9

A method for producing a gel form negative electrode of an alkaline battery, said method comprising the steps of:
preparing by dry mixing a dry mixture of a zinc or zinc alloy powder, indium oxide and polyacrylic acid;
putting said dry mixture into a potassium hydroxide electrolyte; and
stirring said potassium hydroxide electrolyte with said dry mixture therein and thereby mixing and dispersing said dry mixture therein.