# US 5,348,811 A · Recording medium and method of performing recording/producing on the recording medium > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,348,811 A - Document ID: US5348811A - Status: Granted - Kind: A - Application number: 07/338,509 - Filed: 1989-04-14 - Granted: 1994-09-20 - Earliest claimed: 1986-07-25 - Assignees: Fuji Photo Film Co., Ltd. - Inventors: Makoto Nagao; Goro Akashi - Web page: https://patentgrep.com/patent/US5348811A ## CPC - G11B 9/10: using electron beam; Record carriers therefor (G11B9/08 takes precedence {see provisional also G11B11/03}) - Y10S 428/908: Impression retention layer, e.g. print matrix, sound record - Y10T 428/12493: Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] - Y10T 428/12535: with additional, spatially distinct nonmetal component - Y10T 428/12583: Component contains compound of adjacent metal - Y10T 428/2457: Parallel ribs and/or grooves - Y10T 428/24612: Composite web or sheet - G11B: INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER (recording measured values in a way that does not require playback through a transducer G01D9/00; recording or playback apparatus using mechanically marked tape, e.g. punched paper tape, or using unit records, e.g. punched or magnetically marked cards G06K; transferring data from one type of record carrier to another G06K1/18; circuits for coupling output of reproducer to radio receiver H04B1/20; gramophone pick-ups or like acoustic electromechanical transducers or circuits therefor H04R) - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract A recording medium and method of performing recording/reproducing on the recording medium. The recording medium includes a multi-layer structure wherein at least two kinds of atomic layers are alternately laminated on a support. The elements of the atomic layers are selected so that they have secondary electron emission characteristics, such as secondary electron emission efficiency or secondary electron energy spectrums different from each other and do not form any alloy with each other, or so that a reacted mixture between the at least two kinds of atomic layers has secondary electron characteristics different from the atomic layers. The recording is performed by irradiating the surface of the recording medium with a recording beam selected from an electron beam, a charged particle beam, and a neutral particle beam to expose the next lower different kind of atomic layer of forma mixture. The reproducing is performed by irradiating the surface of the recording medium carrying information recorded thereon with a reproducing beam selected from the electron beam, a charged particle beam, and a neutral particle beam to emit secondary electrons from its surface thereof, and detecting the difference in the secondary electron emission characteristic between the emitted secondary electrons. ## Claims ### Claim 1 A multi-layer recording medium, comprising: a support; at least one first metal layer; and at least two second metal layers having secondary electron emission characteristics different from said first metal layer, with one of said second metal layers being formed on said support, said first metal layer being laminated between said second metal layers with respective adjacent layers being made of different kinds of metal from one another, and the other of said second metal layers having portions thereof selectively removed to expose said first metal layer to thereby represent information recorded in said recording medium. ### Claim 2 (depends on 1) A recording medium as claimed in claim 1, wherein said portions of said second metal layer are removable by means of irradiation by a recording beam, and [wherein elements constituting any one of said metal layers will not substantially form any alloy with elements constituting any adjacent one of said metal layers. ### Claim 3 (depends on 2) A recording medium as claimed in claim 2, wherein said secondary electron emission characteristics of said at least one first metal layer and said at least two second metal layers both comprise the same one of the group consisting of a secondary electron emission efficiency and a secondary electron energy spectrum. ### Claim 4 (depends on 2) A recording medium as claimed in claim 2, wherein said recording beam comprises a beam selected from the group consisting of an electron beam, a charged particle beam and a neutral particle beam. ### Claim 5 (depends on 1) A recording medium as claimed in claim 1, wherein said support comprises a material selected from the group consisting of a metal having a smooth surface, an oxide of said metal, glass and plastic film. ### Claim 6 (depends on 1) A recording medium as claimed in claim 1, wherein said first metal layer and second metal layers have different secondary electron emission efficiency from one another. ### Claim 7 (depends on 1) A recording medium as claimed in claim 1, wherein said first metal layer is formed of a material having a higher secondary emission efficiency than the material of said second metal layers and wherein said material having a higher secondary emission efficiency is selected from the group consisting of: Ag--Mg, Cs--Te, Sb--CS, Cu--Be, Ga--As--Cs, Ga--Cs--P, Ga--P, Cs, Na, Li, Ca, and Ag--O--Cs. ### Claim 8 (depends on 6) A recording medium as claimed in claim 6, wherein one of said at least one first metal layer and said at least two second metal layers is formed of materials having low secondary electron emission efficiency. ### Claim 9 (depends on 6) A recording medium as claimed in claim 6, wherein said first metal layer is formed of a material having a lower secondary emission efficiency than the material of said second metal layers, and wherein said material having lower secondary emission efficiency is selected from the group consisting of: As, Ag, Al, Au, Be, Bi, C, Cd, Co, Cr, Cu, Ga, Ge, Mo, Ni, Pt, Re, Sb, S, Ti, Ta, Te, V, W, Zn, Zr, Ir, Bi--Te, and Na--Cl. ### Claim 10 (depends on 1) A recording medium as claimed in claim 1, wherein each of said second metal layers is formed of a material having a higher secondary emission efficiency than the material of said first metal layer. ### Claim 11 (depends on 6) A recording medium as claimed in claim 6, wherein said second metal layers are formed of a material having a higher secondary emission efficiency than the material of said first metal layer, and wherein said material having higher secondary electron emission efficiency is selected from the group consisting of: Ag--Mg, Cs--Te, Sb--CS, Cu--Be, Ga--As--Cs, Ga--Cs--P, Ga--P, Cs, Na, Li, Ca, and Ag--O--Cs. ### Claim 12 (depends on 6) A recording medium as claimed in claim 6, wherein said second metal layers are formed of a material having a lower secondary emission efficiency than the material of said first metal layer, and wherein said material having lower secondary emission efficiency is selected from the group consisting of: As, Ag, Al, Au, Be, Bi, C, Cd, Co, Cr, Cu, Ga, Ge, Mo, Ni, Pt, Re, Sb, S, Ti, Ta, Te, V, W, Zn, Zr, Ir, Bi--Te, and Na--Cl. ### Claim 13 A multi-layer recording medium carrying information thereon, said medium comprising: a support; at least one first metal layer; and at least two second metal layers having secondary electron emission characteristics different from said first metal layer, with one of said second metal layers being formed on said support, said first metal layer being disposed between said second metal layers with respective adjacent layers being of different kinds of metal from one another, and the other of said second metal layers having gaps therein for exposing said first metal layer to thereby represent said information.