# US 5,348,732 A · Toothpaste composition

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- Number: US 5,348,732 A
- Document ID: US5348732A
- Status: Granted
- Kind: A
- Application number: 07/966,212
- Filed: 1992-10-26
- Granted: 1994-09-20
- Earliest claimed: 1991-10-29
- Assignees: Chesebrough-Pond's USA Co., Division of Conopco, Inc.
- Inventors: Jonathan E. Creeth; Paul I. Riley; Mark E. Laing
- Web page: https://patentgrep.com/patent/US5348732A

## CPC

- A61K 8/02: characterised by special physical form
- A61K 8/676: {Ascorbic acid, i.e. vitamin C}
- A61Q 11/00: Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
- B65D 35/24: with auxiliary devices
- B65D 81/24: Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants (with thermal insulation B65D81/38)
- A61K 2800/88: Two- or multipart kits
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- B65D: CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES

## Abstract

Packaged toothpaste formulations which contain air sensitive components, e.g. vitamin C, are prevented from discoloring or otherwise degrading, by placing adjacent to an area of the packaging which may allow air access to the formulation, e.g. an air permeable collar, a nozzle, or the wall of an air permeable tube, a body (e.g. plug or layer) of material which does not contain any air sensitive components. Preferably, the latter body of material is the packaged toothpaste but without the air sensitive components.

## Claims

### Claim 1

A method for preventing a packaged toothpaste formulation containing at least one air sensitive component from degrading through contact with air, said formulation held within packaging comprising a laminated tube with an air permeable collar, said method comprising placing adjacent to said air permeable collar a plug or layer of said formulation absent said at least one air sensitive component.

### Claim 2 (depends on 1)

A method according to claim 1, wherein said packaged toothpaste formulation further comprises an oxygen scavenger compound present in an effective amount to prevent degradation of said at least one air sensitive component.

### Claim 3 (depends on 2)

A method according to claim 2, wherein said oxygen scavenger compound is selected from the group consisting of stannous compounds and sodium metabisulphite.

### Claim 4 (depends on 1)

A method according to claim 1, wherein said packaged toothpaste formulation absent said at least one air sensitive component comprises from 1 to 20% of total amount of said packaged toothpaste formulation held within said packaging.

### Claim 5 (depends on 1)

A method according to claim 1, wherein said packaging includes a nozzle via which said toothpaste formulation is dispensed and said plug or layer of said toothpaste formulation absent said at least one air sensitive component is placed adjacent to said nozzle.

### Claim 6 (depends on 1)

A method according to claim 1, wherein said air sensitive component is selected from the group consisting of: ene-diols; vitamins; catechols; tannins; metal salts in low oxidation states which change colour on air-oxidation; iodide salts; flavour molecules which are susceptible to loss of or change in flavour upon air-oxidation; and mixtures thereof.

### Claim 7

A method according to 1, wherein said air sensitive component is vitamin C.