# US 5,348,719 A · Process for producing carbon fibers having high strand strength

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- Number: US 5,348,719 A
- Document ID: US5348719A
- Status: Granted
- Kind: A
- Application number: 07/795,376
- Filed: 1991-11-21
- Granted: 1994-09-20
- Earliest claimed: 1990-11-21
- Assignees: Mitsubishi Kasei Corporation
- Inventors: Iwao Yamamoto; Akihiko Yoshiya; Akira Nakagoshi
- Web page: https://patentgrep.com/patent/US5348719A

## CPC

- D01F 9/145: from pitch or distillation residues
- D01F 9/15: from coal pitch
- D01F 11/12: with inorganic substances {; Intercalation}
- D01F: CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS

## Abstract

A process for producing carbon fibers having high strand strength, which comprises subjecting pitch fibers obtained by melt-spinning pitch, followed by gathering, to infusible treatment to obtain infusible fibers, followed by carbonization treatment, and if necessary, graphitization treatment, to obtain carbon fibers, wherein the infusible fibers or the carbon fibers are heat-treated in an atmosphere containing steam or carbon dioxide at a temperature of from 500.degree. to 1,800.degree. C.

## Claims

### Claim 1

A process for producing carbon fibers, which consists essentially of:
preparing pitch fibers by melt-spinning pitch, at least 40% of which is of an optically anisotropic structure;
gathering the resulting fibers;
infusibilizing the gathered fibers;
carbonizing the infusibilized fibers at a temperature of 400.degree. to 1800.degree. C. in an inert gas;
if necessary, graphitizing said carbonized fibers; and
heat treating said infusibilized fibers or carbonized fibers at a temperature of from 500.degree.-1800.degree. C. in an atmosphere consisting essentially of an inert gas with an effective amount of at least one of steam and carbon dioxide to enhance the tensile strength of the carbon strand product to a level of at least 210 kg/mm.sup.2.

### Claim 2 (depends on 1)

The process for producing carbon fibers according to claim 1, wherein the heat-treatment in the atmosphere containing steam or carbon dioxide is conducted at a temperature of from 1,050.degree. to 1,400.degree. C.

### Claim 3 (depends on 1)

The process for producing carbon fibers according to claim 1, wherein the concentration of steam in the steam-containing atmosphere is within a range of from 1,000 ppm to 100 vol. %.

### Claim 4 (depends on 1)

The process for producing carbon fibers according to claim 1, wherein the concentration of carbon dioxide in the carbon dioxide-containing atmosphere is within a range of from 5,000 ppm to 100 vol. %.

### Claim 5 (depends on 2)

The process for producing carbon fibers according to claim 2, wherein the heat-treatment in the atmosphere containing steam or carbon dioxide is conducted for from 0.1 second to 24 hours.

### Claim 6 (depends on 1)

The process for producing carbon fibers according to claim 1, wherein the infusible fibers or the carbon fibers having been heat-treated in the atmosphere containing steam or carbon dioxide, are further subjected to carbonization or graphitization treatment.

### Claim 7 (depends on 3)

The process for producing carbon fibers according to claim 3, wherein the heat treatment in the atmosphere containing steam is conducted at a temperature of from 1,050.degree. C. to 1,400.degree. C. for from 5 seconds to 90 minutes at a concentration of steam of from 3,000 ppm to 60 vol. %.

### Claim 8 (depends on 4)

The process for producing carbon fibers according to claim 4, wherein the heat treatment in the atmosphere containing carbon dioxide is conducted at a temperature of from 1,050.degree. C. to 1,400.degree. C. for from 5 seconds to 90minutes at a concentration of carbon dioxide of from 5,000 ppm to 70 vol. %.

### Claim 9 (depends on 1)

The process for producing carbon fibers according to claim 1, wherein said inert gas is nitrogen or argon.