# US 5,348,712 A · Use of carbonates in metal ion extraction

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- Number: US 5,348,712 A
- Document ID: US5348712A
- Status: Granted
- Kind: A
- Application number: 08/015,017
- Filed: 1993-02-09
- Granted: 1994-09-20
- Earliest claimed: 1993-02-09
- Assignees: Texaco Chemical Company
- Inventors: Edward T. Marquis; Martin J. Plishka
- Web page: https://patentgrep.com/patent/US5348712A

## CPC

- C22B 3/362: {Heterocyclic compounds of a single type}
- C22B 3/26: by liquid-liquid extraction using organic compounds
- C22B 11/04: {by wet processes (extraction of metal compounds by leaching in organic solutions C22B3/16; treatment or purification of solutions by liquid-liquid extraction C22B3/26)}
- Y02P 10/20: Recycling
- C22B: PRODUCTION AND REFINING OF METALS (electrolytic C25); PRETREATMENT OF RAW MATERIALS
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

It has been discovered that relatively large cyclic and open chain carbonates are extremely efficient in the selective extraction of metal ions, such as gold, silver, platinum and mercury from aqueous solution without the need for a potentially hazardous, organic solvent or use of a corrosive salt, such as NaCl. For example, 1,2-decane carbonate extracted >99.9% mercury, 99.76% gold, 97.5% silver and 79.0% platinum. The homologous 1,2-dodecane carbonate was found to extract 99.9% gold and silver from aqueous solution and 95.8% platinum. Didecyl carbonate extracted 77% gold from aqueous solution. The method of this invention is simpler than prior techniques and eliminates the need for potentially hazardous solvents (toxic, flammable and environmentally unfavorable) and corrosive additives, such as salt, NaCl, used as a salting agent in prior methods.

## Claims

### Claim 1

A process for extracting metal ions from aqueous solutions comprising contacting an aqueous solution containing metal ions with at least about 5 wt. % of an organic carbonate based on the weight of the aqueous solution, the organic carbonate being selected from the group consisting of cyclic 1,2-alkane carbonates having the formula: ##STR3## where R is a straight or branched alkyl group of 8 to 20 carbon atoms, and open chain carbonates having the formula: ##STR4## where each R' is independently a straight or branched alkyl of at least 10 carbon atoms and where the total number of carbon atoms in both R' groups is between 20 to 36, in the absence of an organic solvent and in the absence of an alkali metal salt, where the metal ions are selected from the group consisting of gold, silver, platinum, mercury and mixtures thereof.

### Claim 2 (depends on 1)

The process of claim 1 where the organic carbonate is used in an amount ranging from about 5 to about 300 wt. % based on the weight of the aqueous solution.

### Claim 3 (depends on 1)

The process of claim 1 where the metal ions in aqueous solution are bound in salts or complexes.

### Claim 4

A process for extracting metal ions from aqueous solutions comprising contacting an aqueous solution containing metal ions with at least 5 wt. % of an organic carbonate based on the weight of the aqueous solution, the organic carbonate being selected from the group consisting of cyclic 1,2-alkane carbonates having the formula: ##STR5## where R is a straight or branched alkyl group of 8 to 20 carbon atoms, and open chain carbonates having the formula: ##STR6## where each R' is independently a straight or branched alkyl of at least 10 carbon atoms and where the total number of carbon atoms in both R' groups is between 20 to 36, in the absence of an organic solvent and in the absence of an alkali metal salt, where the metal ions are selected from the group consisting of gold, silver, platinum, mercury and mixtures thereof, and they are extracted in a proportion of at least 95%.

### Claim 5 (depends on 4)

The process of claim 4 where the metal ions in aqueous solution are bound in salts or complexes.

### Claim 6

A process for extracting metal ions from aqueous solutions comprising contacting an aqueous solution containing metal ions with at least 5 wt. % of an organic carbonate based on the weight of the aqueous solution, the organic carbonate being selected from the group consisting of cyclic 1,2-alkane carbonates having the formula: ##STR7## where R is a straight or branched alkyl group of 8 to 20 carbon atoms, in the absence of an organic solvent and in the absence of an alkali metal salt, where the metal ions are selected from the group consisting of gold, silver, platinum, mercury and mixtures thereof.

### Claim 7

A process for extracting metal ions front aqueous solutions comprising contacting an aqueous solution containing metal ions with at least 5 wt. % of an organic carbonate based on the weight of the aqueous solution, the organic carbonate being selected from the group consisting of open chain carbonates having the formula: ##STR8## where each R' is independently a straight or branched alkyl of at least 10 carbon atoms and where the total number of carbon atoms in both R' groups is between 20 to 36, in the absence of an organic solvent and in the absence of an alkali metal salt where the metal ions are selected from the group consisting of gold, silver, platinum, mercury and mixtures thereof.