# US 5,348,685 A · Ferroelectric liquid crystal composition

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- Number: US 5,348,685 A
- Document ID: US5348685A
- Status: Granted
- Kind: A
- Application number: 08/107,191
- Filed: 1993-08-17
- Granted: 1994-09-20
- Earliest claimed: 1992-10-09
- Assignees: Fujitsu Limited; Mitsui Toatsu Chemicals, Inc.; Sanyo Chemical Industries, Ltd.
- Inventors: Akihiro Mochizuki; Shigeo Kasahara; Tetsuya Makino; Masashi Watanabe; Masakatsu Nakatsuka; Kunikiyo Yoshio; Masahiro Satoh; Tetsuya Watanabe; Naoko Sugita; Tatsuroh Yanagi
- Web page: https://patentgrep.com/patent/US5348685A

## CPC

- C09K 19/46: containing esters
- C09K 19/42: Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

This invention is directed to reduce the viscosity of a naphthalene type mixed liquid crystal and to improve display quality while maintaining a bookshelf layer structure. The ferroelectric liquid crystal composition of the present invention comprises 70 to 97 parts by weight of a naphthalene base mixed liquid crystal and 3 to 30 parts by weight of a predetermined tolan type liquid crystal.

## Claims

### Claim 1

A ferroelectric liquid crystal composition comprising:
70 to 97 parts by weight of a naphthalene base mixed liquid crystal containing at least three kinds of liquid crystals selected from the following five kinds of liquid crystals expressed by the general formulas I to V: ##STR68## wherein each of R.sub.1, R.sub.3, R.sub.6, R.sub.7 and R.sub.17 independently represents mutually a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; each of R.sub.2 *, R.sub.4 *, R.sub.5 *, R.sub.8 * and R.sub.18 * independently represents a C.sub.4-16 alkyl group having asymmetric carbon at the connecting bond thereof; X represents a hydrogen atom or a fluorine atom; and l and m represent an integer of 1 to 5, respectively; and
3to 30 parts by weight of a tolan type liquid crystal expressed by the following general formula VI: ##STR69## wherein R.sub.13 represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; R.sub.14 * represents a C.sub.4-16 alkyl group having asymmetric carbon; each of A and B independently represents a hydrogen atom or a fluorine atom; and y represents --(CH.sub.2).sub.i --, with the proviso that i represents an integer of 0 to 5.

### Claim 2

A ferroelectric liquid crystal composition comprising:
70 to 97 parts by weight of a naphthalene base mixed liquid crystal containing at least three kinds of liquid crystals selected from the following five kinds of liquid crystals expressed by the general formulas I to V: ##STR70## wherein each of R.sub.1, R.sub.3, R.sub.6, R.sub.7 and R.sub.17 independently represents mutually a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; each of R.sub.2 *, R.sub.4 *, R.sub.5 *, R.sub.8 * and R.sub.18 * independently represents a C.sub.4-16 alkyl group having asymmetric carbon at the connecting bond thereof; X represents a hydrogen atom or a fluorine atom; and l and m represents an integer of 1 to 5, respectively; and
3to 30 parts by weight of a tolan type liquid crystal expressed by the following general formula VII: ##STR71## wherein R.sub.15 represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; R.sub.16 represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; and A represents a hydrogen atom or a fluorine atom.

### Claim 3

A ferroelectric liquid crystal composition comprising:
70 to 97 parts by weight of a naphthalene base mixed liquid crystal containing at least three kinds of liquid crystals selected from the following five kinds of liquid crystals expressed by the general formulas VIII to XI and V; ##STR72## wherein each of R.sub.1, R.sub.6, R.sub.9, R.sub.11 and R.sub.17 independently represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; each of R.sub.2 *, R.sub.5 *, R.sub.10 *, R.sub.12 * and R.sub.18 * independently represents a C.sub.4-16 alkyl group having asymmetric carbon at the connecting bond thereof; and l represents an integer of 1 to 5; and
3to 30 parts by weight of a tolan type liquid crystal expressed by the general formula VI: ##STR73## wherein R.sub.13 represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; R.sub.14 * represents a C.sub.4-16 alkyl group having asymmetric carbon; A and B each independently represents a hydrogen atom or a fluorine atom; and y represents a --(CH.sub.2).sub.i --, with the proviso that i represents an integer of 0 to 5.

### Claim 4

A ferroelectric liquid crystal composition comprising:
70 to 97 parts by weight of a naphthalene base mixed liquid crystal containing at least three kinds of liquid crystals selected from the following five kinds of liquid crystals expressed by the general formulas VIII to XI and V: ##STR74## wherein each of R.sub.1, R.sub.6, R.sub.9, R.sub.11 and R.sub.17 independently represents mutually a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; each of R.sub.2 *, R.sub.5 *, R.sub.10 *, R.sub.12 * and R.sub.18 * independently represents a C.sub.4-16 alkyl group having asymmetric carbon at the connecting bond thereof; and l represents an integer of 1 to 5; and
3to 30 parts by weight of a tolan type liquid crystal expressed by the following general formula VII: ##STR75## wherein each of R.sub.15 and R.sub.16 independently represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; and A represents a hydrogen atom or a fluorine atom.

### Claim 5

A ferroelectric liquid crystal composition comprising:
70 to 97 parts by weight of a naphthalene base mixed liquid crystal containing at least three kinds of liquid crystals selected from the following five kinds of liquid crystals expressed by the general formulas I to V: ##STR76## wherein each of R.sub.1, R.sub.3, R.sub.6, R.sub.7 and R.sub.17 independently represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; each of R.sub.2 *, R.sub.4 *, R.sub.5 *, R.sub.8 * and R.sub.18 * independently represents a C.sub.4-16 alkyl group having asymmetric carbon at the connecting bond thereof; X represents a hydrogen atom or a fluorine atom; and l and m represent an integer of 1 to 5,respectively; and
3to 30 parts by weight of a tolan type liquid crystal expressed by the following general formulas VI and VII: ##STR77## wherein each of R.sub.13, R.sub.15 and R.sub.16 independently represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; R.sub.14 * represents a C.sub.4-16 alkyl group having asymmetric carbon; A and B each independently represents a hydrogen atom or a fluorine atom; and y represents --(CH.sub.2).sub.i --, with the proviso that i is an integer of 0 to 5.

### Claim 6

A ferroelectric liquid crystal composition comprising:
70 to 97 parts by weight of a naphthalene base mixed liquid crystal containing at least three kinds of liquid crystals selected from the following five kinds of liquid crystals expressed by the following general formulas VIII to XI and V: ##STR78## wherein each of R.sub.1, R.sub.6, R.sub.9, R.sub.11 and R.sub.17 independently represents mutually a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; each of R.sub.2 *, R.sub.5 *, R.sub.10 *, R.sub.12 * and R.sub.18 * independently represents mutually a C.sub.4-16 alkyl group having asymmetric carbon at the connecting bond thereof; and l represents an integer of 1 to 5; and
5to 30 parts by weight of a tolan type mixed liquid crystal expressed by the following general formulas VI and VII: ##STR79## wherein each of R.sub.13, R.sub.15 and R.sub.16 independently represents a C.sub.6-16 alkyl group or a C.sub.6-16 alkoxy group; R.sub.14 * represents a C.sub.4-16 alkyl group having asymmetric carbon; A and B each independently represents a hydrogen atom or a fluorine atom; and y represents --(CH.sub.2).sub.i --, with the proviso that i is an integer of 0 to 5.