# US 5,348,644 A · Process and apparatus for contacting a hydrocarbon feedstock with hot solid particles in a tubular reactor with a rising fluidized bed

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- Number: US 5,348,644 A
- Document ID: US5348644A
- Status: Granted
- Kind: A
- Application number: 07/612,322
- Filed: 1990-11-13
- Granted: 1994-09-20
- Earliest claimed: 1989-11-10
- Assignees: Compagnie de Raffinage et de Distribution Total France
- Inventors: Pierre Maroy; Roben Loutaty; Thierry Patureaux
- Web page: https://patentgrep.com/patent/US5348644A

## CPC

- C10G 11/18: according to the "fluidised-bed" technique
- B01J 8/1818: {Feeding of the fluidising gas (B01J8/44 takes precedence)}
- B01J 8/1863: {followed by a downward movement outside the reactor and subsequently re-entering it}
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

In a fluidized catalytic cracking (FLC) type unit for contacting of a hydrocarbon feedstock with hot solid particles in a fluidized bed in an upright tubular-type upflow hydrocarbon conversion reactor, there is provided, between the means for fluidization and the means for injection of the feedstock, a means for causing the fluidized phase at the periphery of the reactor to rotate about the axis of the reactor.

## Claims

### Claim 1

A process for contacting a hydrocarbon feedstock with hot solid particles in a centrally-open substantially vertical tubular reactor operated with a rising dilute fluidized bed having an injection zone for the hydrocarbon feedstock, said process comprising introducing the particles into the tubular reactor in an uprising, vertical flow direction, fluidizing the particles so as to provide a vertically rising, axially moving fluidized bed, injecting feedstock into the injection zone and, at a point in the tubular reactor downstream from the introducing and fluidizing steps, imparting at the outer periphery of said bed a rotational motion about the axis of the reactor effective to counteract backmixing and reduce the residence time of particles at least at the periphery of said bed and also reduce particle density at the periphery of said bed for more uniform particle distribution so that at the injection zone the speed of rotation of the fluidized bed at the periphery of the reactor, in a plane normal to this axis, is from approximately 0.5 to approximately 1.5 times the velocity of the fluids flowing vertically along the axis of the reactor.

### Claim 2 (depends on 1)

A process as defined in claim 1 wherein imparting the rotational motion is at a point in the reactor downstream from the introducing and fluidizing steps but upstream from the injecting step.

### Claim 3

A process for contacting a hydrocarbon feedstock with hot solid particles in a centrally-open substantially vertical tubular reactor which is operated with a vertically rising, axially moving dilute fluidized bed, said process comprising
a. providing a centrally-open substantially vertical reactor for contacting a hydrocarbon feedstock with hot solid particles and which is operated with a vertically rising, axially moving fluidized bed,
b. introducing hot solid particles into said reactor in an uprising, vertical flow direction,
c. fluidizing said particles in a fluidization zone so as to provide said vertically rising, axially moving fluidized bed;
d. injecting a hydrocarbon feedstock into said reactor in a zone of injection located above the point of injection of the hot solid particles and
e. imparting the fluidized bed in a portion of the reactor located above the fluidization zone and below the zone of injection of the hydrocarbon feedstock a rotational motion about the central axis of the reactor so as to produce an equalization of moduli of fluids directly below the zone of injection and so that at the level of introduction of the feedstock rotational speed has been imparted to the fluidized bed at the periphery of the reactor.

### Claim 4 (depends on 3)

A process as defined by claim 3, wherein the speed of rotation of the fluidized bed at the periphery of the reactor, in the plane normal to its axis, is from approximately 0.5 to approximately 1.5 times the velocity of the fluids circulating along the axis of the reactor.

### Claim 5 (depends on 4)

A process as defined in claim 4, wherein
the average upward velocity of the particles in the fluidized bed where the feedstock is injected is greater than approximately 1 meter per second,
the speed of rotation of the fluidized bed at the periphery of the tubular reactor at the level of injection of the hydrocarbon feedstock is between approximately 1 and approximately 15 meters per second, and
the hydrocarbon feedstock to be converted is injected into the reactor as droplets with a diameter of less than approximately 200 microns.

### Claim 6 (depends on 3)

A process as defined in claim 3, wherein substantially all of the solid particles and substantially all of the feedstock in the fluidized bed have an overall upward motion.

### Claim 7 (depends on 3)

A process as defined in claim 3, wherein the average upward velocity of the particles in the fluidized bed where the feedstock is injected is greater than approximately 1 meter per second.

### Claim 8 (depends on 7)

A process as defined in claim 7, wherein said average upward velocity is between 2 and 10 meters per second.

### Claim 9 (depends on 3)

A process as defined in claim 3, wherein the speed of rotation of the fluidized bed at the periphery of the tubular reactor at the level of injection of the hydrocarbon feedstock is between approximately 1 and approximately 15 meters per second.

### Claim 10 (depends on 3)

A process as defined in claim 3, wherein the hydrocarbon feedstock to be converted is injected into the reactor as droplets with a diameter of less than approximately 200 microns.

### Claim 11 (depends on 10)

A process as defined in claim 10, wherein said diameter is less than approximately 100 microns.

### Claim 12 (depends on 2)

A process as defined in claim 2, wherein the imparting of the rotational motion is by injecting fluids and, the fluids injected are of the same type as those used for fluidization of the solid particles.

### Claim 13 (depends on 3)

A process as defined in claim 3, wherein the reactor has an interior wall, the rotational motion is imparted by passing the fluidized bed over one or more rigid strips attached to the reactor interior wall and arranged as a spiral, said strips being positioned downstream of the fluidization zone and upstream of the zone of injection of the hydrocarbon feedstock.

### Claim 14 (depends on 3)

A process as defined in claim 3, wherein the rotational motion is imparted by injecting a fluid into the fluidized bed at the outer periphery thereof at a position downstream of the fluidization zone and upstream of the zone of injection of the hydrocarbon feedstock.

### Claim 15 (depends on 14)

A process as defined in claim 14, wherein the injection of the fluid is from at least two points located symmetrically relative to and at an upward or perpendicular angle to the axis of the reactor.