# US 5,348,626 A · Electrolytic recovery of reactor metal fuel > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,348,626 A - Document ID: US5348626A - Status: Granted - Kind: A - Application number: 08/012,713 - Filed: 1993-02-03 - Granted: 1994-09-20 - Earliest claimed: 1993-02-03 - Assignees: The United States of America as represented by the United States Department of Energy - Inventors: William E. Miller; Zygmunt Tomczuk - Web page: https://patentgrep.com/patent/US5348626A ## CPC - C25C 3/34: of metals not provided for in groups C25C3/02 - C25C3/32 - C25C: PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR ## Abstract A new electrolytic process and apparatus are provided using sodium, cerium or a similar metal in alloy or within a sodium beta or beta"-alumina sodium ion conductor to electrolytically displace each of the spent fuel metals except for cesium and strontium on a selective basis from the electrolyte to an inert metal cathode. Each of the metals can be deposited separately. An electrolytic transfer of spent fuel into the electrolyte includes a sodium or cerium salt in the electrolyte with sodium or cerium alloy being deposited on the cathode during the transfer of the metals from the spent fuel. The cathode with the deposit of sodium or cerium alloy is then chanted to an anode and the reverse transfer is carried out on a selective basis with each metal being deposited separately at the cathode. The result is that the sodium or cerium needed for the process is regenerated in the first step and no additional source of these reactants is required. ## Claims ### Claim 1 An electrolytic process of recovering a nuclear reactor metal fuel comprising the steps of: providing an electrolytic cell including a fused salt electrolyte containing metal halides of the reactor metal fuel, an anode electrode and a cathode electrode in contact with the electrolyte, and said anode being an active metal capable of displacing a select group of metals from said metal halides contained in said electrolyte and with said cathode being an inert metal when in contact with said select group of metals; operating the cell during a cathode deposition step by limiting a cell current generated during said cathode deposition to selectively deposit metals onto said cathode electrode from said metal halides in said electrolyte. ### Claim 2 (depends on 1) An electrolytic process as recited in claim 1 wherein sodium or cerium at said active metal anode electrode is used for displacing each of the metals deposited at said cathode electrode during said cathode deposition step. ### Claim 3 (depends on 1) An electrolytic process as recited in claim 1 wherein said active metal anode electrode is sodium contained in a sodium beta-alumina or sodium beta"-alumina conductor. ### Claim 4 (depends on 1) An electrolytic process as recited in claim 1 wherein said active metal anode electrode is a sodium or cerium alloy. ### Claim 5 (depends on 1) An electrolytic process as recited in claim 1 wherein said inert cathode electrode is a noble metal cathode collector. ### Claim 6 (depends on 1) An electrolytic process as recited in claim 1 wherein said inert cathode electrode includes inert metal surfaces selected from the group consisting of Mo or W. ### Claim 7 (depends on 1) An electrolytic process as recited in claim 1 wherein said step of selectively depositing metals at said cathode electrode is achieved by passing current to generate a cell voltage in a range from about +1.35 volt to +0.44 volt. ### Claim 8 (depends on 1) An electrolytic process as recited in claim 1 wherein said step of operating the cell during a cathode deposition step includes operating the cell as a discharging battery and limiting current flow, whereby the metals plate out in a predetermined order as the cell voltage drops. ### Claim 9 An electrolytic process of recovering a nuclear reactor metal fuel comprising the steps of: providing an electrolytic cell including a fused salt electrolyte, an anode electrode and a cathode electrode in contact with the electrolyte, and a source of electrical voltage to said electrodes; operating the cell during an anodic dissolution step with a metal fuel basket containing said metal fuel being anode wherein said basket being of a metal which will not undergo oxidation during said anodic dissolution step and with an active metal alloy electrode being said cathode to transfer nuclear reactor metal fuel contained in said metal fuel basket into said electrolyte; and operating the cell during a cathode deposition step by limiting a cell current generated during said cathode deposition with said active metal alloy electrode being said anode, said active metal capable of displacing nuclear reactor metal fuel from said electrolyte, and with an inert metal cathode to selectively deposit metals from said nuclear reactor metal fuel transferred into said electrolyte at said cathode electrode, said cathode being inert when in contact with the deposited metals. ### Claim 10 (depends on 9) An electrolytic process as recited in claim 9 wherein said cathode electrode during said anodic dissolution step is a sodium .beta. or .beta."-alumina sodium ion conductor. ### Claim 11 (depends on 9) An electrolytic process as recited in claim 9 wherein said anode electrode during said cathode deposition step is a sodium .beta. or .beta."-alumina sodium ion conductor containing sodium. ### Claim 12 (depends on 9) An electrolytic process as recited in claim 9 wherein said cathode electrode during said anodic dissolution step is said anode electrode during said cathode deposition step. ### Claim 13 (depends on 9) An electrolytic process as recited in claim 9 wherein sodium or cerium at said active metal anode electrode is used for displacing each of the metals deposited at said cathode electrode during said cathode deposition step. ### Claim 14 (depends on 9) An electrolytic process as recited in claim 9 during said cathode deposition step said inert cathode electrode is an inert metal current collection electrode selected from the group consisting of MO or W. ### Claim 15 (depends on 9) An electrolytic process as recited in claim 9 wherein said step of operating the cell during said anodic dissolution step includes the step of applying an external voltage up to approximately -1.35 volt. ### Claim 16 An electrolytic process as recited in claim wherein said step of operating the cell during said cathode deposition step includes the step of passing current to generate a voltage in a range between approximately +1.35 volt to 0.44 volt.