# US 5,348,475 A · Trimodal method of curing dental restorative compositions

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- Number: US 5,348,475 A
- Document ID: US5348475A
- Status: Granted
- Kind: A
- Application number: 08/051,444
- Filed: 1993-04-22
- Granted: 1994-09-20
- Earliest claimed: 1991-05-08
- Assignees: Jeneric/Pentron Incorporated
- Inventors: Samuel Waknine; Arun Prasad; Weitao Jia
- Web page: https://patentgrep.com/patent/US5348475A

## CPC

- A61C 5/30: Securing inlays, onlays or crowns
- A61C 5/70: Tooth crowns; Making thereof
- A61K 6/884: comprising natural or synthetic resins
- A61C: DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE (non-driven toothbrushes A46B; {tongue scrapers A61B17/24;} preparations for dentistry A61K6/00; preparations for cleaning the teeth or mouth A61K8/00, A61Q11/00)
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)

## Abstract

A trimodal method of curing dental composite restorative materials involves the use of visible light illumination for the initial curing of the composite resin and a combination of dry heat and vacuum for the complete cure of the composite restorative materials. More specifically, the method for preparing dental restorative materials includes the steps of forming a dental restoration from a composite resin of a type conventionally employed in the dental profession, in which the composite resin includes a photosensitizing system for initiating polymerization of the composite resin upon exposure to visible light, an initiator for initiating polymerization upon application of heat and at least one filler; exposing the thus prepared restoration to a source of visible light to at least partially cure said composite resin and then subjecting the thus prepared restoration to a combination of heat and vacuum to complete polymerization of said complete resin.

## Claims

### Claim 1

A method for preparing a composite dental restoration exhibiting improved toughness and fracture resistance comprising the steps of:
(A) forming a dental restoration from at least one layer of a composite resin, said composite resin comprising
(i) at least one binder resin,
(ii) a diluent monomer,
(iii) a photopolymerization system comprising an initiator for initiating polymerization of the composite resin upon exposure to visible light and an accelerator,
(iv) an initiator for initiating polymerization of the composite resin upon application of heat, and
(v) at least one filler, wherein each layer of the composite resin is exposed to a source of visible light to partially cure each layer of said composite resin to provide sufficient hardening to enable building up of additional layers of composite resin thereon;
(b) subjecting the thus prepared restoration to a combination of dry heat and vacuum sufficient to remove residual monomeric surface layers and anaerobically complete polymerization of said composite resin.

### Claim 2 (depends on 1)

A method according to claim 1, wherein the dental restoration is selected from the group consisting of crowns, bridges, inlays, onlays, laminates, pre-fabricated post cores, lingual splints and bio-dental prosthetic partials.

### Claim 3 (depends on 1)

A method according to claim 1, wherein the binder resin comprises a polycarbonate dimethacrylate in combination with a second resin selected from the group consisting of Bis-GMA, polyurethane dimethacrylate and oligomers thereof.

### Claim 4 (depends on 1)

A method according to claim 1, wherein the photopolymerization system comprises d,l camphoroquinone as a polymerization initiator and a tertiary amine as the accelerator and said heat polymerization initiator is benzoyl peroxide.

### Claim 5 (depends on 4)

A method according to claim 4, wherein the restoration is subjected to heat at a temperature of 225.degree. F. in step (B).

### Claim 6 (depends on 1)

A method according to claim 1, wherein the visible light curing in step (A) is conducted intraorally.

### Claim 7 (depends on 1)

A method according to claim 1, wherein the visible light curing in step (A) is conducted extraorally.