# US 5,348,425 A · Piston cylinder device with a protective coating and method of producing such a coating > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,348,425 A - Document ID: US5348425A - Status: Granted - Kind: A - Application number: 07/974,270 - Filed: 1992-11-10 - Granted: 1994-09-20 - Earliest claimed: 1992-11-10 - Inventors: Robert W. Heiliger - Web page: https://patentgrep.com/patent/US5348425A ## CPC - F16J 10/04: Running faces; Liners - E21D 15/44: Hydraulic, pneumatic, or hydraulic-pneumatic props {(see also E21D15/51)} - F05C 2203/0882: Carbon, e.g. graphite - F16F 2226/02: Surface treatments - F16J: PISTONS {(specially adapted for dampers F16F9/32)}; CYLINDERS; SEALINGS - E21D: SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS (soil-conditioning or soil-stabilising materials C09K17/00; drilling or cutting machines for mining or quarrying E21C; safety devices, transport, rescue, ventilation or drainage E21F) - F05C: INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES - F16F: SPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION ## Abstract A method is described for protecting piston cylinder devices against corrosion by a pressure resistant thermoset or cured material coating. At least the outer and inner cylindrical surfaces, for example, of a mine prop, that cooperate with a sealing device, are coated with a three-dimensionally cross-linked, cured or thermoset material having a sufficient thickness on the one hand for providing the intended protection against corrosion and on the other hand to avoid excessive radially directed elastic deformations of the coating. An additive is included in the coating to improve the dry lubricating characteristics, and thus the cooperation between the coating and the sealing devices. The three-dimensionally interlinked thermoset material fills all surface irregularities so that gas and water pockets, for example, in a mine prop, are avoided. ## Claims ### Claim 1 A method for producing a protective thermoset coating at least on one surface that cooperates with a sealing device in a piston cylinder unit wherein said at least one surface is in sliding contact with said sealing device, comprising the following steps: (a) preparing a powder mixture of a three-dimensionally cross-linking thermosetting uncured powder material and a lubricant additive in powder form, (b) roughly preparing said at least one surface to provide a prepared surface for a powder coating operation, (c) applying a layer of said powder mixture to said prepared surface to form a powder coating layer on said prepared surface, and (d) heating said powder coating layer sufficiently for curing said thermosetting powder material to cause a three-dimensional cross-linking to form said protective thermoset coating with a coating thickness of about 500 .mu.m at the most. ### Claim 2 (depends on 1) The method of claim 1, wherein said three-dimensionally cross-linking thermosetting powder material is selected from the group consisting of epoxy resins cross-linked with polyamines, polyamino derivatives, polyamido derivatives, polyisocyanates, carboxylic acid and anhydrides thereof, amino resins, phenolic resins, polyphenols, solid amines and combination of these cross-linking members, and polyesters cross-linked with isocyanates, and wherein said lubricant is selected from the group consisting of graphite, molybdenum sulfide, soot, polyethylene, polypropylene, polyamide, fluorine containing polymers, and silicone oil. ### Claim 3 (depends on 1) The method of claim 1, wherein said thermosetting powder material is present in said powder mixture within the range of 70% by weight to 99.5% by weight, and wherein said lubricant in powder form is present within the range of 0.5% by weight to 30% by weight of the whole powder mixture. ### Claim 4 (depends on 1) The method of claim 1, wherein said at least one surface is a surface selected from the group consisting of a cylindrical outer surface of a piston of said unit and a cylindrical inner surface of a cylinder of said unit, and wherein said step of preparing said at least one surface is performed as a cleaning step without any material removal machining. ### Claim 5 (depends on 4) The method of claim 4, wherein said step of preparing said at least one surface is performed by cutting a section off a cold drawn high strength steel pipe and cleaning an inner surface of said cold drawn high strength steel pipe section. ### Claim 6 (depends on 1) The method of claim 1, wherein said step of preparing said at least one surface is performed as a cleaning step by sandblasting. ### Claim 7 (depends on 1) The method of claim 1, wherein said step of preparing said at least one surface is performed as a cleaning step by brushing. ### Claim 8 (depends on 1) The method of claim 1, wherein said step of preparing said at least one surface is performed as a cleaning step by descaling. ### Claim 9 (depends on 1) The method of claim 1, further comprising pre-heating said at least one surface to a temperature within the range of about 100.degree. C. to about 350.degree. C. to store heat in said at least one surface sufficient for performing said heating of said powder in step (d) by causing a substantially immediate curing of said thermosetting powder when it is applied in step (c) to form said protective thermoset coating. ### Claim 10 (depends on 1) The method of claim 1, wherein said step of heating is performed by heating said at least one surface and said powder coating layer together to a temperature within the range of about 100.degree. C. to about 350.degree. C. to supply heat sufficient for a substantially immediate curing of said thermosetting powder to form said protective thermoset coating. ### Claim 11 (depends on 1) The method of claim 1, wherein said step of heating is performed by applying induction heat to said at least one surface. ### Claim 12 (depends on 1) The method of claim 1, wherein said protective thermoset coating is formed with a thickness within the range of about 150 .mu.m to about 500 .mu.m. ### Claim 13 A piston cylinder device, comprising an outer cylindrical pipe section with an inwardly facing first cylindrical surface and a piston with an outwardly facing second cylindrical surface, sealing means in sliding contact with at least one of said first and second cylindrical surfaces, a protective thermoset, cured coating of a three-dimensionally cross-linked powder-based thermosetting material including a lubricant additive in said coating on at least one of said first and second cylindrical surfaces for improving a dry sliding characteristic of said sliding contact, said coating having a thickness within the range of about 100 .mu.m to about 500 .mu.m, said lubricant additive being dispersed and embedded in said coating, said thermoset, cured coating comprising macro-molecules formed by said three-dimensional cross-linking and said cured coating being substantially non-compressible and substantially impervious to gases, water and water vapor. ### Claim 14 (depends on 13) The piston cylinder device of claim 13, wherein at least said pipe section is a length of a cold drawn, high strength steel, of which said inwardly facing first cylindrical surface carries said thermoset, cured coating of said thermosetting material with said lubricant embedded in said thermosetting material. ### Claim 15 (depends on 13) The piston cylinder device of claim 13, wherein said outer cylindrical pipe section comprises a length of cold drawn, high strength steel, and wherein said piston also comprises a length of cold drawn, high strength steel to form a mine prop, and wherein said thermoset, cured coating is carried on said first and second cylindrical surfaces. ### Claim 16 (depends on 13) The piston cylinder device of claim 13, wherein said coating has a thickness within the range of about 150 .mu.m to about 500 .mu.m. ### Claim 17 (depends on 13) The piston cylinder device of claim 13, wherein said thermosetting material of said thermoset, cured three-dimensional cross-linked coating is selected from the group consisting of: epoxy resins cross-linked with polyamines, polyamino derivatives, polyamido derivatives, polyisocyanates, carboxylic acid and anhydrides thereof, amino resins, phenolic resins, polyphenols, solid amines and combinations of these cross-linking members, and polyesters cross-linked with isocyanates, and wherein said lubricant additive is selected from the group consisting of graphite, molybdenum disulfide, soot, polyethylene, polypropylene, polyamide, fluorine containing polymers, and silicone oil. ### Claim 18 A mine prop, comprising a piston cylinder device including at least one outer cylindrical pipe (5) and an inner cylindrical pipe (6) slidingly guided in said outer cylindrical pipe, a piston (7) connected to an inner end of said inner cylindrical pipe, piston sealing means (34) in sliding, guided contact with an inner surface of said outer cylindrical pipe (5), at least one further sealing means (4) in sliding contact with an outer surface of said inner cylindrical pipe (6), a sleeve ring (8) connecting said further sealing means (4) with an upper end of said outer cylindrical pipe (5), a first protective, thermoset coating at least on said inner surface of said outer cylindrical pipe, a second protective, thermoset coating at least on said outer surface of said inner cylindrical pipe, each of said first and second protective coatings comprising a thermoset, cured coating of a three-dimensionally cross-linked powder-based thermosetting material including a lubricant additive in said coating on at least one of said first and second cylindrical surfaces for improving a dry sliding characteristic of said sliding contact, said coating having a thickness within the range of about 100 .mu.m to about 500 .mu.m, said lubricant additive being dispersed and embedded in said coating, said thermoset, cured coating comprising macro-molecules formed by said three-dimensional cross-linking and said cured coating being substantially non-compressible and substantially impervious to gases, water and water vapor. ### Claim 19 (depends on 18) The mine prop of claim 18, wherein said coating has a thickness within the range of about 150 .mu.m to about 500 .mu.m. ### Claim 20 (depends on 18) The mine prop of claim 18, wherein said mine prop is made of cold drawn, high strength steel. ### Claim 21 (depends on 1) The method of claim 1, wherein said lubricant additive participates in said three-dimensional cross-linking. ### Claim 22 (depends on 1) The method of claim 1, wherein said lubricant additive does not participate in said three-dimensional cross-linking. ### Claim 23 (depends on 13) The device of claim 13, wherein said lubricant additive participates in said three-dimensional cross-linking. ### Claim 24 (depends on 13) The device of claim 13, wherein said lubricant additive does not participate in said three-dimensional cross-linking. ### Claim 25 (depends on 18) The mine prop of claim 18, wherein said lubricant additive participates in said three-dimensional cross-linking. ### Claim 26 (depends on 18) The mine prop of claim 18, wherein said lubricant additive does not participate in said three-dimensional cross-linking.