# US 5,347,073 A · Fixation of heavy metals, mercury recovery and dioxins destruction in municipal solid waste incinerator ash

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- Number: US 5,347,073 A
- Document ID: US5347073A
- Status: Granted
- Kind: A
- Application number: 08/053,798
- Filed: 1993-04-28
- Granted: 1994-09-13
- Earliest claimed: 1993-04-28
- Assignees: Air Products and Chemicals, Inc.
- Inventors: Wolfgang A. Hochleitner; Stephen P. Goff
- Web page: https://patentgrep.com/patent/US5347073A

## CPC

- A62D 3/38: by oxidation; by combustion
- A62D 3/33: by chemical fixing the harmful substance, e.g. by chelation or complexation
- B09B 3/40: involving thermal treatment, e.g. evaporation (processes using mineral binders involving a melting or softening step B09B3/29; involving radiation B09B3/50)
- C04B 18/106: {Fly ash from waste incinerators}
- A62D 2101/08: Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
- A62D 2101/22: containing halogen
- A62D 2101/40: Inorganic substances
- A62D 2101/43: containing heavy metals, in the bonded or free state
- A62D 2203/04: Combined processes involving two or more non-distinct steps covered by groups A62D3/10 - A62D3/40
- Y02W 30/91: Use of waste materials as fillers for mortars or concrete
- Y10S 106/01: Fly ash
- A62D: CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- B09B: DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

Fly ash generated from incineration of municipal solid waste (MSW) when placed in landfills can under mild acid conditions 1each lead and cadmium. A process for stabilizing lead in this fly ash is presented which involves calcining a mixture of the fly ash and certain calcium-containing compounds in the presence of an oxygen containing gas stream at a temperature greater than about 475.degree. C. and less than about 600.degree. C. for times from about 30 minutes up to about 5 hours. Such treated MSW fly ash will give leachates containing lead concentrations less than the EPA regulatory limit.

## Claims

### Claim 1

In a process for the stabilization of heavy metals-containing fly ash obtained by subjecting flue gas to particulate separation, which process comprises forming a mixture of the fly ash and a calcium-containing material, said calcium-containing material being present in the mixture so as to provide a weight ratio of calcium to fly ash from about 0.04 to about 0.5:1, heating the mixture to a temperature in the range of from about 475.degree. C. to about 650.degree. C. and maintaining said temperature for a period of time from about 30 minutes to about five hours while in the presence of an oxygen-containing gas to produce a thermally treated fly ash and a purge gas, the improvement for (1) volatilizing and subsequently recovering any mercury which may be contained in the fly ash; (2) destroying any dioxins which may be contained in the fly ash and (3) preventing any elemental arsenic and selenium which may be contained in the fly ash from volatilizing and subsequently contaminating the purge gas comprising:
(a) narrowing said temperature range from about 475 .degree. C.-650.degree. C. to about 475.degree. C.-600.degree. C.;
(b) separating the thermally treated fly ash from the purge gas; and
(c) cooling the separated purge gas to a temperature below 357.degree. C. in order to condense out and recover at least a portion of the mercury.