# US 5,347,068 A · Method of simultaneous disposal of solid and liquid wastes

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 5,347,068 A
- Document ID: US5347068A
- Status: Granted
- Kind: A
- Application number: 07/901,492
- Filed: 1992-06-19
- Granted: 1994-09-13
- Earliest claimed: 1991-08-01
- Assignees: Energiewerke Schwarze Pumpe Aktiengesellschaft
- Inventors: Wolfgang Rabe; Lutz Groschel; Karl Sowka; Gunter Scholz; Gunter Seifert; Manfred Durlich; Emil Reichl; Heinz Polenski
- Web page: https://patentgrep.com/patent/US5347068A

## CPC

- C10J 3/02: Fixed-bed gasification of lump fuel
- C10J 3/20: Apparatus; Plants
- C10J 3/42: Rotary grates
- C10J 3/485: {Entrained flow gasifiers}
- C10J 3/721: {Multistage gasification, e.g. plural parallel or serial gasification stages}
- C10J 3/84: with means for removing dust or tar from the gas
- C10K 1/002: {Removal of contaminants}
- C10K 1/08: by washing with liquids; Reviving the used wash liquors (gas washers B01D)
- C10J 2300/1693: with storage facilities for intermediate, feed and/or product
- C10J 2300/1838: Autothermal gasification by injection of oxygen or steam
- Y02E 50/30: Fuel from waste, e.g. synthetic alcohol or diesel
- C10J: PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES (synthesis gas from liquid or gaseous hydrocarbons C01B; underground gasification of minerals E21B43/295); CARBURETTING AIR OR OTHER GASES
- C10K: PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Method for simultaneous disposal of solid and liquid wastes including the steps of gasifying in a fixed bed pressure gasifier a gasification material containing coal and 1 to 70% of a solid waste material containing sulfur, hydrocarbons, PCBs, dioxins and/or heavy metals, to form a pollutant and dust-containing fixed bed pressure gasification crude gas; post-gasifying in a post-gasifier at a temperature greater than 1,000.degree. C. and with a dwell time of more than 2 seconds the crude gas together with an oxygen-containing gas and a liquid waste portion having a heat content of greater than 20,000 kJ/kg and containing hydrocarbons, PCBs and/or heavy metals to form a disposal gas; cooling the disposal gas to less than 200.degree. C. and cleaning it or process waste water to form a mixture of pollutant slurries; gasifying in an additional flow gasifier a mixture of the pollutant slurries, another liquid waste portion having a heat content of greater than 20,000 kJ/kg and containing hydrocarbons, sulfur, PCBs, heavy metals and/or dioxins and 3 to 35% of solid components containing greater than 10% mineral components and sulfur, heavy metals, PCBs, dioxins, furans and/or hydrocarbons, at a temperature more than 50.degree. C. above a melting point of the mineral components.

## Claims

### Claim 1

Method for simultaneous disposal of solid and liquid wastes comprising the steps of:
a. gasifying in a fixed bed pressure gasifier a gasification material consisting of 99 to 30% of brown coal briquettes and 1 to 70% of a solid waste material containing at least one member selected from the group consisting of sulfur, hydrocarbons, PCBs, dioxins and heavy metals, to form a fixed bed pressure gasification crude gas;
b. post-gasifying in a post-gasifier at a temperature greater than 1,000.degree. C. and with a dwell time of more than 2 seconds the crude gas from step a) together with an oxygen-containing gas and a liquid waste portion having a heat content of greater than 20,000 kJ/kg and containing at least one member selected from the group consisting of hydrocarbons, PCBs and heavy metals to form a disposal gas;
c. cooling said disposal gas to less than 200.degree. C. and quenching to form a soot water; and
d. gasifying in a flow gasifier said soot water together with at least one pollutant slurry, another liquid waste portion having a heat content of greater than 20,000 kJ/kg and containing at least one member selected from the group consisting of hydrocarbons, sulfur, PCBs, heavy metals and dioxins and solid components comprising a solid waste, said solid components containing greater than 10% mineral components and at least one member selected from the group consisting of sulfur, heavy metals, PCBs, dioxins, furans and hydrocarbons, the solid components being present in an amount equal to 3 to 35% by weight of a total amount of said soot water, said at least one pollutant slurry, said other liquid waste portion and the solid components, at a temperature more than 50.degree. C. above a melting point of said mineral components.

### Claim 2 (depends on 1)

Method as defined in claim 1, wherein said post-gasifier and said flow gasifier are operated so as to convert said liquid waste portion and said crude gas in said post-gasifier into said disposal gas so that said disposal gas is free of PCBs and hydrocarbons after said cooling and quenching and to convert said soot water, said at least one pollutant slurry, said other liquid waste portion and the solid components in said flow gasifier into a slag having a heavy metal component fused therein for disposal and a dioxin-free product gas.

### Claim 3

Method for simultaneous disposal of solid and liquid wastes comprising the steps of:
a. gasifying in a fixed bed pressure gasifier a gasification material consisting of 99 to 30% of brown coal briquettes and 1 to 70% of a solid waste material containing at least one member selected from the group consisting of sulfur, hydrocarbons, PCBs, dioxins and heavy metals, to form a fixed bed pressure gasification crude gas;
b. post-gasifying in a post-gasifier at a temperature greater than 1,000.degree. C. and with a dwell time of more than 2 seconds the crude gas from step a) together with an oxygen-containing gas and a liquid waste portion having a heat content of greater than 20,000 kJ/kg and containing at least one member selected from the group consisting of hydrocarbons, PCBs and heavy metals to form a disposal gas;
c. cooling said disposal gas to less than 200.degree. C. and quenching with water to form a soot water;
d. gasifying in a flow gasifier said soot water together with at least one pollutant slurry, another liquid waste portion having a heat content of greater than 20,000 kJ/kg and containing at least one member selected from the group consisting of hydrocarbons, sulfur, PCBs, heavy metals and dioxins and solid components comprising a solid waste, said solid components containing greater than 10% mineral components and at least one member selected from the group consisting of sulfur, heavy metals, PCBs, dioxins, furans and hydrocarbons, the solid components being present in an amount equal to 3 to 35% by weight of a total amount of said soot water, said at least one pollutant slurry, said other liquid waste portion and the solid components, at a temperature more than 50.degree. C. above a melting point of said mineral components; and
e. operating said fixed bed pressure gasifier, said post-gasifier and said flow gasifier so as to simultaneously dispose of said solid waste material, said liquid waste portions and said solid components.

### Claim 4 (depends on 3)

Method as defined in claim 3, wherein said gasifying in said fixed bed pressure gasifier occurs at 25 bar and 1350.degree. C.