# US 5,347,066 A · Alkylation process for reacting an olefin feed being substantially free of isobutylene which utilizes a hydrogen fluoride and sulfone catalyst

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- Number: US 5,347,066 A
- Document ID: US5347066A
- Status: Granted
- Kind: A
- Application number: 08/057,372
- Filed: 1993-05-06
- Granted: 1994-09-13
- Earliest claimed: 1993-05-06
- Assignees: Phillips Petroleum Company
- Inventors: Bruce B. Randolph
- Web page: https://patentgrep.com/patent/US5347066A

## CPC

- C07C 2/62: with acids
- C07C 2527/1206: Hydrogen fluoride
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

A process for producing an alkylate product having an improved octane value from an olefin stream having a reduced concentration of the butene isomer of isobutylene. The olefin feed stream to the process system is substantially free of isobutylene and can have undergone prior processing to remove isobutylene therefrom. The olefin feed is subjected to an alkylation reaction catalyzed by a mixture of hydrogen fluoride and sulfone.

## Claims

### Claim 1

A method of improving the quality of an alkylate product produced form the alkylation of 1-butene in an alkylation process which uses a hydrogen fluoride-containing catalyst, the method comprises the steps of:
providing with said hydrogen fluoride-containing catalyst a concentration of a sulfone;
contacting an admixture comprising an isoparaffin and an olefin feed having a volumetric ratio of isobutylene to 1-butene of less than 1:10, with said hydrogen fluoride-containing catalyst within a reaction zone; and
producing said alkylate product.

### Claim 2 (depends on 1)

A method as recited in claim 1 wherein said olefin feed has an absence of isobutylene.

### Claim 3 (depends on 2)

A method as recited in claim 2 wherein said concentration of said sulfone in said hydrogen fluoride-containing catalyst is such as to give a weight ratio of hydrogen fluoride to sulfone in said hydrogen-fluoride containing catalyst in the range of from about 1:1 to 40:1.

### Claim 4 (depends on 3)

A method as recited in claim 3 wherein said sulfone is sulfolane.

### Claim 5 (depends on 4)

A method as recited in claim 4 wherein the contacting step occurs under alkylation conditions in which the alkylation reaction temperature is in the range of from about 0.degree. F. to about 150.degree. F. and the alkylation reaction pressure is sufficient to maintain said admixture of said isoparaffin and said olefin feed in the liquid phase.

### Claim 6 (depends on 5)

A method as recited in claim 5 wherein the molar ratio of isoparaffin to olefin in said admixture is in the range of from about 2:1 to about 25:1.

### Claim 7

An improved alkylation process of the type including contacting, within a reaction zone, a mixed olefin stream, comprising 1-butene and isobutylene, and an isoparaffin with a hydrogen fluoride catalyst and producing an alkylate product, wherein the improvement comprises:
removing from said mixed olefin stream, prior to contacting it with said hydrogen fluoride catalyst, a portion of the isobutylene contained therein to provide an olefin feed having a volumetric ratio of isobutylene to 1-butene of less than 1:10; and
providing a concentration of a sulfone in said hydrogen fluoride catalyst to thereby enhance the quality of 1-butene alkylate produced from the hydrogen fluoride catalyzed alkylation of 1-butene.

### Claim 8 (depends on 7)

A process as recited in claim 7 wherein said mixed olefin stream includes a concentration of butylene olefins in the range of from about 5 to about 40 volume percent.

### Claim 9 (depends on 8)

A process as recited in claim 8 wherein said olefin feed has an absence of isobutylene.

### Claim 10 (depends on 9)

A process as recited in claim 9 wherein said concentration of said sulfone in said hydrogen fluoride catalyst provided is such as to give a weight ratio of hydrogen fluoride to sulfone in said hydrogen fluoride catalyst in the range of from about 1:1 to about 40:1.

### Claim 11 (depends on 10)

A process as recited in claim 10 wherein the molar ratio of isoparaffin to olefin contacted within said reaction zone is in the range of from about 2:1 to about 25:1.

### Claim 12 (depends on 11)

A process as recited in claim 11 wherein the contacting step occurs under alkylation conditions in which the alkylation reaction temperature is in the range of from about O.degree. F. to about 150.degree. F. and the alkylation reaction pressure is sufficient to maintain said admixture of said isoparaffin and said olefin feed in the liquid phase.