# US 5,347,064 A · Multiple split feed isoparaffin-olefin alkylation

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- Number: US 5,347,064 A
- Document ID: US5347064A
- Status: Granted
- Kind: A
- Application number: 08/045,435
- Filed: 1993-04-12
- Granted: 1994-09-13
- Earliest claimed: 1993-04-12
- Assignees: Mobil Oil Corporation
- Inventors: Jonathan E. Child; Kenneth J. Del Rossi; Albin Huss, Jr.; Robert S. Kurtas
- Web page: https://patentgrep.com/patent/US5347064A

## CPC

- C10G 50/00: Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
- C07C 2/62: with acids
- C07C 9/16: Branched-chain hydrocarbons
- C07C 2527/1213: Boron fluoride
- C07C 2527/173: Phosphoric acid or other acids with the formula Hn+2PnO3n+1
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

An isoparaffin-olefin alkylation process is disclosed which improves alkylate quality by segregating the olefin feed into intermediate feedstreams which are enriched in propene, 1-butene, and/or 2-butenes with respect to the olefin feed, and alkylating these intermediate feedstreams in separate reaction zones at reaction temperatures specific to the olefin feed to increase the ratio of trimethylpentanes to dimethylhexanes in the resulting alkylate product.

## Claims

### Claim 1

An isoparaffin-olefin alkylation process comprising the steps of:
(a) providing a feed comprising propene, 1-butene, and 2-butenes;
(b) separating a first intermediate stream from said feed, said first intermediate stream being enriched in propene in comparison to said feed;
(c) separating a second intermediate stream from said feed, said second intermediate stream being enriched in 1-butene in comparison to said feed;
(d) separating a third intermediate stream from said feed, said third intermediate stream being enriched in 2-butenes in comparison to said feed;
(e) contacting said first intermediate stream with excess isobutane in a first reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under isobutane-propene alkylation conversion conditions including temperature T.sub.1 to produce a first alkylate product enriched in isoparaffins having more than 4 carbon atoms;
(f) contacting said second intermediate stream with excess isobutane in a second reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under isobutane-1-butene alkylation conversion conditions including temperature T.sub.2, wherein T.sub.2 <T.sub.1, to produce a second alkylate product enriched in isoparaffins having more than 5 carbon atoms;
(g) contacting said third intermediate stream with excess isobutane in a third reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under isobutene-2-butenes alkylation conversion conditions including temperature T.sub.3, wherein T.sub.3 <T.sub.2 <T.sub.1, to produce a third alkylate product enriched in isoparaffins having more than 5 carbon atoms; and
(h) recovering said alkylate products from steps (e), (f), and (g).

### Claim 2 (depends on 1)

The process of claim 1 wherein T.sub.1 is from about 80.degree. to about 120.degree. F.

### Claim 3 (depends on 2)

The process of claim 2 wherein T.sub.2 is from about 80.degree. to about 110.degree. F.

### Claim 4 (depends on 3)

The process of claim 3 wherein T.sub.3 is from about 20 to about 60.degree. F.

### Claim 5 (depends on 1)

The process of claim 1 further comprising charging said isobutane to said first reaction zone at a rate sufficient to maintain an isobutane:propene molar ratio in said first reaction zone of from about 5:1 to about 20:1.

### Claim 6 (depends on 1)

The process of claim 1 further comprising charging said isobutane to said second reaction zone at a rate sufficient to maintain an isobutane:1-butene molar ratio in said second reaction zone of from about 5:1 to about 20:1.

### Claim 7 (depends on 1)

The process of claim 1 further comprising charging said isobutane to said third reaction zone at a rate sufficient to maintain an isobutane:2-butene molar ratio in said third reaction zone of from about 5:1 to about 20:1.

### Claim 8

An isoparaffin-olefin alkylation process comprising the steps of:
(a) providing a feed comprising propene, 1-butene, 2-butenes, and isobutene;
(b) separating a first intermediate stream from said feed, said first intermediate stream being enriched in propene in comparison to said feed, to evolve a second propene-lean intermediate stream, said second propene-lean intermediate stream being lean in propene in comparison to said feed;
(c) contacting said second propene-lean intermediate stream with methanol in a first reaction zone containing an etherification catalyst under conversion conditions to selectively convert isobutene to methyl tertiary butyl ether;
(d) recovering methyl tertiary butyl ether from said second propene-lean intermediate stream;
(e) separating a third intermediate stream from said feed, said third intermediate stream being enriched in 1-butene in comparison to said feed;
(f) separating a fourth intermediate stream, said fourth intermediate stream being enriched in 2-butenes in comparison to said feed;
(g) contacting said first intermediate stream with excess isobutane in a first reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under isobutane-propene alkylation conversion conditions including temperature T.sub.1 to produce a first alkylate product enriched in isoparaffins having more than 4 carbon atoms;
(h) contacting said third intermediate stream with excess isobutane in a second reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under isobutane-1-butene alkylation conversion conditions including temperature T.sub.2, wherein T.sub.2 <T.sub.1, to produce a second alkylate product enriched in isoparaffins having more than 5 carbon atoms;
(i) contacting said fourth intermediate stream with excess isobutane in a third reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under isobutane-2-butenes alkylation conversion conditions including temperature T.sub.3, wherein T.sub.3 <T.sub.2 <T.sub.1, to produce a third alkylate product enriched in isoparaffins having more than 5 carbon atoms; and
(j) recovering said alkylate products from steps (g), (h), and (i).

### Claim 9 (depends on 8)

The process of claim 8 wherein T.sub.1 is from about 80.degree. to about 120.degree. F.

### Claim 10 (depends on 9)

The process of claim 9 wherein T.sub.2 is from about 80.degree. to about 110.degree. F.

### Claim 11 (depends on 10)

The process of claim 10 wherein T.sub.3 is from about 20.degree. to about 60.degree. F.

### Claim 12 (depends on 8)

The process of claim 8 further comprising charging said isobutane to said first reaction zone at a rate sufficient to maintain an isobutane:propene molar ratio in said first reaction zone of from about 5:1 to about 20:1.

### Claim 13 (depends on 8)

The process of claim 8 further comprising charging said isobutane to said second reaction zone at a rate sufficient to maintain an isobutane:l-butene molar ratio in said second reaction zone of from about 5:1 to about 20:1.

### Claim 14 (depends on 8)

The process of claim 8 further comprising charging said isobutane to said third reaction zone at a rate sufficient to maintain an isobutane:2-butenes molar ratio in said third reaction zone of from about 5:1 to about 20:1.

### Claim 15

A process for alkylating an isoparaffin with an olefin comprising the steps of:
(a) providing a feed comprising propene, 1-butene, and 2-butenes;
(b) separating a first intermediate stream from said feed, said first intermediate stream being enriched in propene and 1-butene in comparison to said feed;
(c) separating a second intermediate stream from said feed, said second intermediate stream being enriched in 2-butenes in comparison to said feed;
(d) contacting said first intermediate stream with excess isobutane in a first reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under a first set of alkylation conversion conditions including temperature T.sub.1 to produce a first alkylate product enriched in isoparaffins having more than 4 carbon atoms;
(e) contacting said second intermediate stream with excess isobutane in a second reaction zone containing BF.sub.3 and H.sub.3 PO.sub.4 in BF.sub.3 :H.sub.3 PO.sub.4 molar ratios of from about 0.5:1 to about 1.5:1 under a second set of alkylation conversion conditions including temperature T.sub.2, wherein T.sub.2 <T.sub.1, to produce a second alkylate product enriched in isoparaffins having more than 5 carbon atoms; and
(g) recovering said alkylate products from steps (d) and (e).

### Claim 16 (depends on 15)

The process of claim 15 wherein T.sub.1 is from about 80.degree. to about 110.degree. F.

### Claim 17 (depends on 16)

The process of claim 16 wherein T.sub.2 is from about 20.degree. to about 60.degree. F.

### Claim 18 (depends on 15)

The process of claim 15 further comprising charging said isobutane to said first reaction zone at a rate sufficient to maintain an isobutane:propene molar ratio in said first reaction zone of from about 5:1 to about 20:1.

### Claim 19 (depends on 15)

The process of claim 15 further comprising charging said isobutane to said second reaction zone at a rate sufficient to maintain an isobutane:l-butene molar ratio in said second reaction zone of from about 5:1 to about 20:1.