# US 5,347,033 A · Preparation of 5-cyanovaleramide

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- Number: US 5,347,033 A
- Document ID: US5347033A
- Status: Granted
- Kind: A
- Application number: 08/082,585
- Filed: 1993-06-28
- Granted: 1994-09-13
- Earliest claimed: 1992-07-01
- Assignees: BASF SE
- Inventors: Tom Witzel; Eberhard Fuchs; Franz Merger
- Web page: https://patentgrep.com/patent/US5347033A

## CPC

- C07C 253/30: by reactions not involving the formation of cyano groups
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

A process for preparing 5-cyanovaleramide by reacting adiponitrile with water at from 50.degree. to 200.degree. C. in the presence of a supported unionized-copper catalyst comprises employing from 1 to 15 mol of water per mole of adiponitrile and a residence time of from 5 to 60 minutes.

## Claims

### Claim 1

A process for praparing 5-cyanovalerimide by reacting adiponitrile with water at from 50.degree. and 200.degree. C. in the presence of a supported copper catalyst wherein the sole catalytic agent comprises metallic copper and a support material, which comprises employing from 1 to 15 mol of water per mol of adiponitrile and a residence time of from 5 to 60 minutes.

### Claim 2 (depends on 1)

A process as claimed in claim 1, wherein a temperature of from 70.degree. to 150.degree. C. is maintained.

### Claim 3 (depends on 1)

A process as claimed in claim 1, wherein from 2 to 11 mol of water are employed per mole of adiponitrile.

### Claim 4 (depends on 1)

A process as claimed in claim 1, wherein the support materials of the supported copper catalyst used are selected from the group consisting of aluminum silicate, magnesium silicate, aluminum oxide, silicon dioxide, titanium dioxide, and zirconium dioxide.

### Claim 5 (depends on 1)

A process as claimed in claim 1, wherein the catalyst contains from 1 to 30% by weight of at least one element selected from the group consisting of zinc, cadmium, chromium, molybdenum, tungsten, vanadium, titanium and thorium, or compounds thereof.

### Claim 6 (depends on 1)

A process as claimed in claim 1, wherein a water-miscible solvent that is inert under reaction conditions is present.

### Claim 7 (depends on 1)

A process as claimed in claim 1, wherein an alkanol of from 1 to 3 carbon atoms is present as solvent.

### Claim 8 (depends on 1)

A process as claimed in claim 1, wherein at least 5 mol of water are employed per mole of adiponitrile and a yield of at least 10% of 5-cyanovaleramide is obtained.