# US 5,346,953 A · Core-shell ABS copolymers and method for their preparation

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- Number: US 5,346,953 A
- Document ID: US5346953A
- Status: Granted
- Kind: A
- Application number: 08/132,951
- Filed: 1993-10-07
- Granted: 1994-09-13
- Earliest claimed: 1993-02-08
- Assignees: General Electric Company
- Inventors: James J. Scobbo, Jr.; Gregory J. Stoddard
- Web page: https://patentgrep.com/patent/US5346953A

## CPC

- C08G 81/022: {containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds}
- Y10S 525/902: Core-shell
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

Core-shell ABS copolymers having an SAN shell completely surrounding the diene core are provided by melt blending an aliphatic diene polymer with an SAN copolymer, said copolymer containing functional groups capable of reacting with the diene polymer. For example, the SAN copolymer may contain azide groups capable of reacting with the olefinic groups in the diene polymer, or both the SAN copolymer and the diene polymer may contain other functional groups capable of interreaction, such as acidic (e.g., maleic anhydride) groups in the diene and epoxy (e.g., glycidyl methacrylate) groups in the SAN copolymer.

## Claims

### Claim 1

A core-shell copolymer comprising particles wherein the core comprises particles of a diene-maleic anhydride copolymer and the shell is a copolymer of an ethylenically unsaturated nitrile, an alkenylaromatic compound and glycidyl methacrylate, said shell completely surrounding and being chemically linked to said core particles.

### Claim 2 (depends on 1)

A copolymer according to claim 1 wherein the core also comprises a copolymer of an ethylenically unsaturated nitrile and an alkenylaromatic compound.

### Claim 3 (depends on 1)

A copolymer according to claim 1 wherein the diene is butadiene, the alkenylaromatic compound is styrene and the ethylenically unsaturated nitrile is acrylonitrile.

### Claim 4

A core-shell copolymer comprising particles wherein the core comprises diene particles and the shell is a copolymer of an ethylenically unsaturated nitrile, an alkenylaromatic compound and vinylbenzyl azide, said shell completely surrounding and being chemically linked to said core particles.

### Claim 5 (depends on 4)

A copolymer according to claim 4 wherein the core also comprises a copolymer of an ethylenically unsaturated nitrile and an alkenylaromatic compound.

### Claim 6 (depends on 5)

A copolymer according to claim 5 wherein the diene is butadiene, the alkenylaromatic compound is styrene and the ethylenically unsaturated nitrile is acrylonitrile.