# US 5,346,785 A · Photochargeable air battery > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,346,785 A - Document ID: US5346785A - Status: Granted - Kind: A - Application number: 08/005,301 - Filed: 1993-01-19 - Granted: 1994-09-13 - Earliest claimed: 1992-01-21 - Assignees: Nippon Telegraph and Telephone Corporation - Inventors: Keiji Akuto; Naoki Kato; Tsutomu Ogata; Masaaki Takeuchi - Web page: https://patentgrep.com/patent/US5346785A ## CPC - H01M 4/62: Selection of inactive substances as ingredients for active masses, e.g. binders, fillers - H01G 9/20: Light-sensitive devices - H01M 4/02: Electrodes composed of, or comprising, active material - H01M 4/38: of elements or alloys - H01M 4/90: Selection of catalytic material - H01M 10/465: {with solar battery as charging system} - H01M 14/005: {Photoelectrochemical storage cells (light sensitive devices H01G9/20, semiconductors sensitive to light H10F)} - Y02E 60/10: Energy storage using batteries - Y02E 60/50: Fuel cells - H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY - H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10) - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract A photochargeable air battery is disclosed possessing a negative electrode 22 which discharges by oxidation of metal material 22a, a positive electrode 21 comprising a oxygen catalyst, electrolyte 23 filling the inside of battery case 27 between negative electrode 22 and positive electrode 21, and battery case 27 housing positive electrode 21, negative electrode 22 and electrolyte 23 in addition to possessing light receptor 22a which injects light into negative electrode 22. As a result, discharging is performed by oxidation of metal material 22a comprising negative electrode 22, while charging is performed by reducing the oxidized metal material by means of irradiating light from light receptor 27a onto the metal material 22 which is oxidized by this discharging. Consequently, a photochargeable air battery with a simplified construction which does not require a large amount of electrolyte or a switch, can be achieved since the cell reaction is not based on redox reactions and reduction of electrolyte 23 does not occur. On the other hand, by exciting electrons using light energy, it is also possible to electrically communicate photo-electrode 30 which reduces metal material 22a oxidized by these electrons to negative electrode 22. ## Claims ### Claim 1 A photochargeable air battery Comprising: a positive electrode comprising an oxygen catalyst; a negative electrode comprising a metal, metal oxide, metal alloy, or metal complex; electrolyte for communicating said positive electrode and said negative electrode; and a battery case for housing said negative electrode, said positive electrode and said electrolyte so that external light is irradiated onto said negative electrode; wherein said photochargeable air battery is discharged by means of oxidation of said negative electrode, and is charged by means of reducing said negative electrode using light energy, wherein said battery case comprises a means for containing said electrolyte and for allowing contact of air to said positive electrode, said containing means including an oxygen permeable material. ### Claim 2 (depends on 1) A photochargeable air battery according to claim 1, wherein a means is provided between said positive electrode and said containing means for preventing outward flow and permeation of said electrolyte. ### Claim 3 (depends on 2) A photochargeable air battery according to claim 2, wherein diffusion paper for uniformly diffusing oxygen over the surface of said positive electrode is provided between said preventing means and said containing means. ### Claim 4 (depends on 1) A photochargeable air battery according to claim 1, wherein said positive electrode comprises an oxygen catalyst and a means for preventing outward flow and permeation of said electrolyte via said containing means. ### Claim 5 (depends on 1) A photochargeable air battery according to claim 1, wherein diffusion paper for uniformly diffusing oxygen over the surface of said positive electrode is provided between said positive electrode and said containing means. ### Claim 6 A photochargeable air battery comprising: a positive electrode; a negative electrode comprising a metal, metal oxide, metal alloy, or metal complex; a photo-electrode comprising a N-type semiconductor electrically communicating to said negative electrode; electrolyte for communicating said positive electrode and said negative electrode; and a battery case for housing said negative electrode, said positive electrode and said electrolyte so that external light is irradiated onto said photo-electrode; wherein said photochargeable air battery is discharged by means of oxidation of said negative electrode, and is charged by means of reducing said negative electrode using light energy irradiated onto said photo-electrode. ### Claim 7 (depends on 6) A photochargeable air battery according to claim 6, wherein a side of said photo-electrode onto which light is irradiated is in contact with said battery case. ### Claim 8 (depends on 6) A photochargeable air battery according to claim 6, wherein said battery case is combined with said photo-electrode. ### Claim 9 (depends on 4, 6) A photochargeable air battery according to one of claims 4 or 6, wherein at least one portion of said negative electrode includes one of a composite metal and alloy comprising one of an oxide of said metal and a plurality of said metals. ### Claim 10 (depends on 6) A photochargeable air battery according to claim 6, wherein a compound or a composite compound of one of metal oxide, nitride, carbide and hydroxide formed by contact of said metal, metal oxide, metal alloy, or metal complex with one of oxygen, nitrogen and carbon dioxide in the air, and said electrolyte is incorporated in said negative electrode. ### Claim 11 (depends on 6) A photochargeable air battery according to claim 6, wherein said positive electrode comprises an oxygen catalyst. ### Claim 12 (depends on 11) A photochargeable air battery according to claim 11, wherein said battery case comprises a means for containing said electrolyte and for allowing contact of air to said positive electrode, said containing means having air holes in the vicinity of said positive electrode. ### Claim 13 (depends on 11) A photochargeable air battery according to claim 11, wherein said battery case comprises a means for containing said electrolyte and for allowing contact of air to said positive electrode, said containing means being made of an oxygen permeable material. ### Claim 14 (depends on 12, 13) A photochargeable air battery according to one of claims 12 or 13, wherein said positive electrode comprises an oxygen catalyst and a means for preventing outward flow and permeation of said electrolyte. ### Claim 15 (depends on 12, 13) A photochargeable air battery according to one of claims 12 or 13, further including means, between said positive electrode and said containing means, for preventing outward flow and permeation of said electrolyte via the containing means of said battery case. ### Claim 16 (depends on 15) (Amended) A photochargeable air battery according to claim 15, wherein diffusion paper for uniformly diffusing oxygen over the surface of said positive electrode is provided between said preventing means and said containing means. ### Claim 17 (depends on 11) A photochargeable air battery according to claim 11, wherein diffusion paper for uniformly diffusing oxygen over the surface of said positive electrode is provided between said positive electrode and said containing means.