# US 5,346,769 A · Process for preparing a prepeg comprising a resin derived from dialkenylbenzene and polyarylamine reactants

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- Number: US 5,346,769 A
- Document ID: US5346769A
- Status: Granted
- Kind: A
- Application number: 08/071,426
- Filed: 1993-06-02
- Granted: 1994-09-13
- Earliest claimed: 1991-12-26
- Assignees: Shell Oil Company
- Inventors: Larry S. Corley
- Web page: https://patentgrep.com/patent/US5346769A

## CPC

- C08J 5/244: {using glass fibres}
- C08J 5/249: {characterised by the additives used in the prepolymer mixture}
- C08J 2325/00: Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- Y10T 428/31504: Composite [nonstructural laminate]
- Y10T 428/31645: Next to addition polymer from unsaturated monomers
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A solventless thermosettable composition comprising a dialkenylbenzene and an effective amount of an alkylbenzenesul fonic acid curina aqent exhibits reduced tendency to gel during cure with the addition of a polyarylamine. The cured material, which is particularly useful in electrical/electronic applications, exhibits low dielectric constant and good fracture toughness.

## Claims

### Claim 1

A process for preparing a prepreg comprising:
impregnating a fibrous glass substitute with a solventless thermosettable composition comprising:
(a) a dialkenylbenzene represented by the structural formula ##STR3## in which R.sup.1 and R.sup.2 are each independently selected from the group consisting of C.sub.1-6 alkyl, C.sub.1-6 alkoxy and halogen;
(b) from about 0.05 to about 5 weight percent, based on the weight of the dialkenylbenzene, of a cationic curing agent for the dialkenylbenzene; and
(c) a polyarylamine present in an amount effective to inhibit gelation of the dialkenylbenzene and within the range of about 0.05 and 20 moles per mole of the curing agent; and subjecting said impregnated substrate to an elevated temperature effective to partially cure the thermosettable composition.

### Claim 2 (depends on 1)

The process of claim 1 in which the dialkenylbenzene comprises diisopropenyl benzene.

### Claim 3 (depends on 1)

The process of claim 1 in which the cationic curing agent is selected from the group consisting of Lewis acids, complexes of Lewis acids, protonic acids having anions of low nucleophilicity, and metal salts of such protonic acids.

### Claim 4 (depends on 1)

The process of claim 1 in which the polyarylamine comprises at least one of the group consisting of diphenylamine 4,4'-diethoxydiphenylamine 3,3', 5,5'-tetramethyldiphenylamine, 1,4-bis(phenylamino)benzene and 1,4-bis(2-naphthylamino)benzene.

### Claim 5 (depends on 2)

The process of claim 2 in which the polyarylamine is diphenylamine.

### Claim 6 (depends on 2)

The process of claim 2 in which the cationic curing agent is an alkyibenzenesulfonic acid.

### Claim 7 (depends on 3)

The process of claim 3 in which the cationic curing agent is selected from the group consisting of sulfuric acid, organic sulfonic acids, tetrafluoroboric acid, tetrafluoroboric acid, boron trifluoride etherate, hexafluorophosphoric acid, hexafluoroantimonic acid, boron trifluoride, boron trichloride, tin tetrafluoroborate and aluminum tetrafluoroborate.

### Claim 8 (depends on 7)

The process of claim 7 in which the cationic curing agent is an aklylbenzenesulfonic acid.

### Claim 9 (depends on 9)

The process of claim 9 in which the polyarylamine is present in the composition in an amount within the range of about 0.05 to about 20 moles per mole of the cationic curing agent.

### Claim 10 (depends on 1)

The process of claim 1 in which the cationic curing agent is present in the composition in an amount within the range of about 0.01 to about 10 weight percent, based on the weight of the dialkenylbenzene.

### Claim 11 (depends on 1)

The process of claim 1 in which the adsorbent substrate is glass fiber.