# US 5,346,737 A · Lubricated polyacetal compositions

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- Number: US 5,346,737 A
- Document ID: US5346737A
- Status: Granted
- Kind: A
- Application number: 08/090,292
- Filed: 1993-07-16
- Granted: 1994-09-13
- Earliest claimed: 1991-11-21
- Assignees: E. I. Du Pont de Nemours and Company
- Inventors: Tatsu-Hiro Takahashi; Toshikazu Kobayashi
- Web page: https://patentgrep.com/patent/US5346737A

## CPC

- C08L 59/00: Compositions of polyacetals; Compositions of derivatives of polyacetals (of polyvinyl acetals C08L29/14)
- C08L 23/08: Copolymers of ethene (C08L23/16 takes precedence)
- C08L 101/00: Compositions of unspecified macromolecular compounds
- Y10T 428/139: Open-ended, self-supporting conduit, cylinder, or tube-type article
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Incorporation of at least one lubricant and an ethylene-based polymer of the formula E/X/Y wherein E is ethylene, X is methyl acrylate, butyl acrylate, or ethyl acrylate, and Y is glycidyl methacrylate, glycidyl acrylate, or glycidyl vinyl ether into polyacetal compositions results in compositions having good wear resistance and good melt processing thermal stability. The compositions are useful, for example, when molded into parts to be used in sliding applications, such as gears, cams, and conveyor chains.

## Claims

### Claim 1

A composition consisting essentially of (A) 80-99 percent by weight of a polyacetal, (B) 0.5-10 percent by weight of at least one lubricant and (C) 0.5-10 percent by weight of an ethylene-based random polymer of the formula E/X/Y wherein
E is ethylene,
X is selected from the group consisting of methyl acrylate, butyl acrylate, and ethyl acrylate,
Y is selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, and glycidyl vinyl ether, and wherein E/X/Y comprises 60-98.5 percent by weight E, 0.5-35 percent by weight X and 1-10 percent by weight Y, as based upon the total weight of E, X, and Y only, and further provided that the weight percent of (A), (B), and (C) is based upon the total weight of (A), (B), and (C) only.

### Claim 2 (depends on 1)

The composition of claim 1 wherein the component (A) polyacetal is a homopolymer.

### Claim 3 (depends on 1)

The composition of claim 1 wherein the component (A) polyacetal is a copolymer.

### Claim 4 (depends on 1)

The composition of claim 1 wherein the component (B) lubricant is selected from the group consisting of paraffin wax, polytetrafluoroethylene, fatty esters, fatty amides, silicone oil, polyethylene glycol, polytetramethylene glycol, and polypropylene glycol.

### Claim 5 (depends on 1)

The composition of claim 1 wherein the component (B) lubricant is selected from paraffin wax, ethylene glycol distearate, ethylene bis(stearamide), polytetramethylene glycol, and polyethylene glycol.

### Claim 6 (depends on 1)

The composition of claim 1 wherein the component (C) is an ethylene/butyl acrylate/glycidyl methacrylate random polymer.

### Claim 7 (depends on 1)

The composition of claim 1 wherein the component (C) is an ethylene/glycidyl methacrylate random polymer.

### Claim 8 (depends on 1)

The composition of claim 1 further containing at least one of thermal stabilizers, antioxidants, tougheners, colorants, UV stabilizers, nucleating agents, fillers, and reinforcing agents.

### Claim 9 (depends on 1)

Shaped articles made from the composition of claim 1.

### Claim 10 (depends on 9)

A shaped article of claim 9 selected from the group consisting of gears, cams, conveyor chains, sheet, profiles, rod stock, film, filaments, fibers, strapping, tape, tubing, and pipe.