# US 5,346,612 A · Distillate hydrogenation utilizing a catalyst comprising platinum, palladium, and a beta zeolite support > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,346,612 A - Document ID: US5346612A - Status: Granted - Kind: A - Application number: 08/021,530 - Filed: 1993-02-19 - Granted: 1994-09-13 - Earliest claimed: 1993-02-19 - Assignees: Amoco Corporation - Inventors: Simon G. Kukes; Frederick T. Clark; P. Donald Hopkins - Web page: https://patentgrep.com/patent/US5346612A ## CPC - C10G 45/54: containing crystalline alumino-silicates, e.g. molecular sieves - B01J 29/7415: {Zeolite Beta} - C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS ## Abstract A process and catalyst are provided for the hydrogenation of a hydrocarbon feedstock consisting essentially of hydrocarbon boiling between about 150.degree. F. and 700.degree. F. at atmospheric pressure. The process comprises reacting the feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising hydrogenation metals and a support comprising beta zeolite. The hydrogenation metals comprise from about 0.1 percent by weight to about 2.0 percent by weight each of palladium and platinum measured as a percentage of the catalyst. The beta zeolite comprises from about 1 ppm by weight to about 3.0 percent by weight sodium calculated as a percentage of said beta zeolite. ## Claims ### Claim 1 A process for the hydrogenation of a hydrocarbon feedstock consisting essentially of hydrocarbon boiling between about 150.degree. F. and 700.degree. F. at atmospheric pressure which comprises reacting said feedstock with hydrogen at hydrogenation conditions in the presence of a catalyst comprising hydrogenation metals and a support comprising beta zeolite, said hydrogenation metals comprising from about 0.1 percent by weight to about 2.0 percent by weight each of palladium and platinum and measured as a percentage of said catalyst, and said beta zeolite comprising sodium in an amount ranging from about 1 ppm by weight to about 3.0 percent by weight of said beta zeolite. ### Claim 2 (depends on 1) The process of claim 1 wherein said support comprises from about 40 percent by weight to about 85 percent by weight beta zeolite. ### Claim 3 (depends on 1) The process of claim 1 wherein said beta zeolite comprises from about 1 ppm by weight to about 2.0 percent by weight sodium. ### Claim 4 (depends on 1) The process of claim 1 wherein said beta zeolite has a silicon to aluminum atomic ratio ranging from about 10 to about 30. ### Claim 5 (depends on 1) The process of claim 1 wherein said feedstock comprises from about 10 percent by weight to about 70 percent by weight aromatics, from about 10 ppm to about 0.9 percent by weight elemental sulfur, and from about 5 ppm by weight to about 900 ppm by weight nitrogen. ### Claim 6 (depends on 1) The process of claim 1 wherein said hydrogenation conditions comprise a reaction temperature ranging from about 400.degree. F. to about 750.degree. F., a reaction pressure ranging from about 300 psig to about 2000 psig, a liquid hourly space velocity ranging from about 0.2 hr.sup.-1 to about 10.0 hr.sup.-1, and a hydrogen injection rate ranging from about 500 SCF/Bbl to about 20,000 SCF/Bbl. ### Claim 7 (depends on 5) The process of claim 5 wherein at least 65 percent of said aromatics present in said feedstock are saturated, calculated as a percentage by weight. ### Claim 8 A process for the hydrogenation of a hydrocarbon feedstock consisting essentially of distillate hydrocarbon boiling between about 150.degree. F. and 700.degree. F. at atmospheric pressure which comprises reacting said feedstock with hydrogen at hydrogenation conditions comprising a reaction temperature ranging from about 400.degree. F. to about 750.degree. F. and a reaction pressure ranging from about 300 psig to about 2000 psig in the presence of a catalyst comprising hydrogenation metals and a support comprising beta zeolite, said hydrogenation metals comprising from about 0.1 percent by weight to about 2.0 percent by weight each of palladium and platinum and measured as a percentage of said catalyst, and said beta zeolite comprising sodium in an amount ranging from about 1 ppm by weight to about 2.0 percent by weight of said beta zeolite. ### Claim 9 (depends on 8) The process of claim 8 wherein said beta zeolite comprises from about 1 ppm by weight to about 1.5 percent by weight sodium. ### Claim 10 (depends on 8) The process of claim 8 wherein said feedstock comprises from about 10 percent by weight to about 70 percent by weight aromatics, from about 10 ppm to about 0.9 percent by weight elemental sulfur, and from about 5 ppm by weight to about 900 ppm by weight nitrogen. ### Claim 11 (depends on 8) The process of claim 8 wherein said hydrogenation conditions comprise a reaction temperature ranging from about 500.degree. F. to about 700.degree. F., a reaction pressure ranging from about 500 psig to about 1500 psig, a liquid hourly space velocity ranging from about 0.5 hr.sup.-1 to about 4.0 hr.sup.-1, and a hydrogen injection rate ranging from about 1000 SCF/Bbl to about 15,000 SCF/Bbl. ### Claim 12 (depends on 10) The process of claim 10 wherein at least 65 percent of said aromatics present in said feedstock are saturated, calculated as a percentage by weight. ### Claim 13 (depends on 8) The process of claim 8 wherein said feedstock is hydrogenated into a hydrogenated product and said hydrogenated product has a cetane number 8 numbers higher than said feedstock. ### Claim 14 (depends on 8) The process of claim 8 wherein said feedstock is hydrogenated into a hydrogenated product and said volume of said hydrogenated product increases by at least 3.5 percent.