# US 5,346,598 A · Method for the prevention of fouling and/or corrosion of structures in seawater, brackish water and/or fresh water > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,346,598 A - Document ID: US5346598A - Status: Granted - Kind: A - Application number: 07/658,582 - Filed: 1991-02-21 - Granted: 1994-09-13 - Earliest claimed: 1988-01-19 - Assignees: Marine Environmental Research, Inc. - Inventors: William J. Riffe; Jack D. Carter - Web page: https://patentgrep.com/patent/US5346598A ## CPC - B63B 59/04: Preventing hull fouling (anti-fouling paints C09D5/16) - B08B 17/02: Preventing deposition of fouling or of dust - C23F 13/00: Inhibiting corrosion of metals by anodic or cathodic protection - C23F 15/00: Other methods of preventing corrosion or incrustation - B63B: SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING (arrangements of vessel ventilation, heating, cooling, or air-conditioning B63J2/00; floating substructures as supports of dredgers or soil-shifting machines E02F9/06) - B08B: CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL - C23F: NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE (working metal by laser beams B23K26/00; desurfacing by applying flames B23K7/00; working of metal by electro-erosion B23H; producing decorative effects by removing surface material, e.g. by engraving, by etching, B44C1/22; electrolytic etching or polishing C25F); INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25 ## Abstract A device and method for preventing fouling and/or corrosion of the exposed surfaces of a structure which is in contact with seawater, brackish water, fresh water, or a combination of these. The system includes using a structure having an exposed zinc-containing surface. At the exposed surface water interface a negative capacitive charge or an asymmetric alternating electrostatic is induced and maintained. ## Claims ### Claim 1 A method for preventing the fouling or corrosion of a structure having a surface in contact with seawater, brackish water, fresh water, or a combination of these, said method comprising using a structure having a conductive zinc-containing surface, where said structure is made of zinc or of a zinc-containing alloy or said structure is made of a conductive or non-conductive material and is equipped with a zinc-containing surface layer or with a zinc-containing coating applied thereto, wherein said conductive zinc-containing surface layer and coating form an interfacial layer between said conductive structure and said water, said coating further containing a silicate, iron oxide, di-iron phosphide, or a mixture thereof, said method further comprising: (a) inducing and maintaining a negative capacitive charge on the surface of said structure in contact with said water sufficient to prevent said fouling or said corrosion; or (b) inducing and maintaining an asymmetric alternating electrostatic potential on said conductive zinc-containing coating sufficient to prevent said fouling or said corrosion; using as a means for inducing said negative capacitive charge or for inducing said asymmetric alternating electrostatic potential, a means comprising at least one condenser bank attached to said structure, wherein said at least one condenser bank is protected from contact by said water, wherein said means for inducing said negative capacitive charge or for inducing said asymmetric alternating electrostatic potential has a terminal of a first polarity conductively connected to said zinc-containing surface and a terminal of opposite polarity capacitively connected to said zinc-containing surface, wherein said terminal polarity capacitively connected to said zinc containing surface is protected from contact by said water environment. ### Claim 2 (depends on 1) The method of claim 1, for preventing the fouling of said structure by zebra mussels. ### Claim 3 (depends on 1) The method of claim 1, comprising inducing and maintaining said negative capacitive charge. ### Claim 4 (depends on 1) The method of claim 1, comprising inducing said asymmetric alternating electrostatic potential. ### Claim 5 A method for preventing fouling or corrosion of an exterior surface or surfaces of a structure in contact with a water environment, said method comprising using a structure having an interior surface and a conductive zinc-containing exterior surface, wherein said structure is made of zinc or of a zinc-containing alloy, or said structure is made of a conductive or non-conductive material and is equipped with a zinc-containing surface layer or with a zinc-containing coating forming an interfacial layer between said exterior surface and said water, said coating further containing a silicate, iron oxide, di-iron phosphide, or a mixture of these, said method further comprising inducing and maintaining a negative capacitive charge on at least that part of said exterior surface in contact with said water, said negative capacitive charge being sufficient to prevent said fouling or said corrosion, wherein said negative capacitive charge is induced and maintained by a means comprising a power supply having a terminal of a first polarity conductively connected to said exterior surface and a terminal of opposite polarity capacitively connected to said exterior surface, wherein said power supply and said capacitive connection means are both protected from contact by said water environment. ### Claim 6 (depends on 5) The method of claim 5, for preventing the fouling of said structure by zebra mussels. ### Claim 7 (depends on 5) The method of claim 5, wherein said structure is a ship, a pipe, sheet or a bar. ### Claim 8 (depends on 7) The method of claim 7 wherein said sheet is a perforated sheet or an expanded sheet. ### Claim 9 (depends on 8) The method of claim 8, wherein said expanded sheet is a screen. ### Claim 10 (depends on 9) The method of claim 9, wherein said screen is an expanded mesh. ### Claim 11 (depends on 7) The method of claim 7, wherein said bar is a wire. ### Claim 12 A method for preventing fouling or corrosion of an exterior surface or surfaces of a structure in contact with a water environment, comprising using a structure having an interior surface and a conductive zinc-containing exterior surface, wherein said structure is made of zinc or of a zinc-containing alloy or said structure is made of a conductive or a non-conductive material and is equipped with a zinc-containing surface layer or with a zinc-containing coating forming an interfacial layer between said exterior surface and said water, said coating further containing a silicate, iron oxide, di-iron phosphide, or a mixture of these, said method further comprising inducing and maintaining a negative capacitive charge on at least the part of said exterior surface in contact with said water, said negative capacitive charge being sufficient to prevent said fouling or said corrosion, wherein said negative capacitive charge is induced and maintained by a means comprising a power supply having a terminal of a first polarity conductively connected to said exterior surface and a terminal of opposite polarity capacitively connected to said exterior surface, wherein said power supply and said capacitive connection means are both situated in the interior of said structure. ### Claim 13 (depends on 12) The method of claim 12, for preventing the fouling of said structure by zebra mussels.