# US 5,346,593 A · Intermediate reboiler for a methanol plant > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,346,593 A - Document ID: US5346593A - Status: Granted - Kind: A - Application number: 08/079,063 - Filed: 1993-06-18 - Granted: 1994-09-13 - Earliest claimed: 1993-06-18 - Assignees: The M. W. Kellogg Company - Inventors: Edward J. Cialkowski; Thomas P. Ognisty - Web page: https://patentgrep.com/patent/US5346593A ## CPC - B01D 3/146: {Multiple effect distillation} - C07C 29/80: by distillation - Y10S 203/08: Waste heat - Y10S 203/09: Plural feed - Y10S 203/20: Power plant - Y10S 203/24: Mobile, marine distiller - B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28) - C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ## Abstract A methanol refining column and method using an intermediate reboiler. Use of the intermediate reboiler reduces methanol production energy requirements. A side stream at or near a fusel oil takeoff point is heated in an intermediate reboiler by a low temperature heating medium (relative to a bottoms reboiler) and returned to the column at or near the fusel oil take-off tray. The take-off tray is operated at 85.degree.-110.degree. C., and 70-90 percent of the reboiler duty is supplied through the intermediate reboiler. The remaining heat load is supplied by a bottoms steam reboiler. ## Claims ### Claim 1 A methanol refining column, consisting essentially of: an upright vessel containing vapor-liquid contacting elements disposed between upper and lower ends thereof; an overhead condenser in fluid communication with the vessel adjacent the upper end thereof; a methanol product outlet disposed adjacent the upper end of the vessel; a methanol enriching section disposed between the methanol product outlet and a mid-column feed inlet; a methanol stripping section disposed between the feed inlet and a fusel oil take-off zone; a methanol and fusel oil stripping section disposed below the fusel oil take-off zone; a bottoms reboiler in fluid communication with the vessel adjacent the lower end thereof; a bottoms outlet adjacent the lower end of the vessel; an intermediate reboiler for heating the vessel above the bottoms reboiler and adjacent the fusel oil take-off zone; and a line from the fusel oil take-off zone to feed the intermediate reboiler, and a side-stream from the intermediate reboiler feed for fusel oil take-off. ### Claim 2 (depends on 1) The column of claim 1, including a pasteurizing section disposed in the upper end of the vessel. ### Claim 3 (depends on 1) The column of claim 1, including a return line for heated fluid from the intermediate reboiler to the fusel oil stripping section adjacent the fusel oil take-off zone. ### Claim 4 (depends on 1) The column of claim 1, wherein the intermediate reboiler is operated at a temperature of from about 85.degree. C. to about 110.degree. C. ### Claim 5 A method for refining methanol from an aqueous stream containing heavier organic contaminants, consisting essentially of the steps of: (a) feeding the aqueous methanol stream to an inlet zone of a refining column below an upper rectifying section and above a lower stripping section; (b) refluxing condensate overhead; (c) recovering a refined methanol product overhead; (d) recovering a fusel oil stream from a fusel oil take-off zone in the stripping section; (e) heating the column adjacent the fusel oil take-off zone with an intermediate reboiler by recirculating fusel oil from the fusel oil take-off zone, through said intermediate reboiler, and back to said fusel oil take-off zone; (f) heating the stripping section below the intermediate reboiler with a bottoms reboiler using a heating medium; and (g) withdrawing an aqueous bottoms product. ### Claim 6 (depends on 5) The method of claim 5, further consisting essentially of the steps of: (h) feeding a crude methanol stream to a topping column; (i) recovering components less volatile than methanol overhead from the topping column; (j) recovering a bottoms product from the topping column essentially free of said volatile components; and (k) using the topping column bottoms product for said aqueous methanol stream feeding step (a) to the refining column inlet zone. ### Claim 7 (depends on 5) The method of claim 5, further consisting essentially of the step of: (1) operating a pasteurization zone disposed above a methanol take-off zone for said overhead product recovery step (c). ### Claim 8 (depends on 5) The method of claim 5, wherein said fusel oil recovery step (d) comprises taking off a side stream from the fusel oil circulated to the intermediate reboiler in step (e). ### Claim 9 (depends on 5) The method of claim 5, wherein the fusel oil take-off zone is operated at a temperature of from about 85.degree. C. to about 110.degree. C. ### Claim 10 (depends on 5) The method of claim 5, wherein the intermediate reboiler heating step (e) supplies from about 70 to about 90 percent of the total heat supplied in said heating steps. ### Claim 11 (depends on 5) The method of claim 5, wherein the first heating medium in heating step (e) has a temperature less than the temperature of the second heating medium in step (f). ### Claim 12 (depends on 5) The method of claim 5, wherein the heating medium in step (f) consisting essentially of steam. ### Claim 13 A method for refining methanol from an aqueous stream containing heavier organic contaminants, consisting essentially of the steps of: (a) feeding the aqueous methanol stream to an inlet zone of a refining column below an upper rectifying section and above a lower stripping section; (b) refluxing condensate overhead; (c) recovering a high purity methanol product overhead; (d) feeding a stream to an intermediate reboiler from a fusel oil take-off zone having a temperature of from about 85.degree. C. to about 110.degree. C.; (e) recovering a fusel oil product as a side-stream from the intermediate reboiler feed stream; (f) heating fusel oil in the intermediate reboiler with a process stream in heat exchange therewith to supply from about 70 to about 90 percent of a heat load in the column; (g) recirculating the heated fusel oil from step (f) to the fusel oil take-off zone; (h) heating the refining column in a bottoms reboiler with steam having a temperature above about 120.degree. C. and greater than the temperature of the hot process stream in step (f), to supply from about 10 to about 30 percent of the heat load to the column; and (i) withdrawing an aqueous bottoms product from the column.