# US 5,346,564 A · Method of safely preparing an explosive emulsion composition

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- Number: US 5,346,564 A
- Document ID: US5346564A
- Status: Granted
- Kind: A
- Application number: 08/077,686
- Filed: 1993-06-16
- Granted: 1994-09-13
- Earliest claimed: 1993-06-16
- Assignees: Nelson Brothers, Inc.
- Inventors: Ricky T. Vance; George L. Griffith; Dennis J. Brown
- Web page: https://patentgrep.com/patent/US5346564A

## CPC

- C06B 47/145: {Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase}
- C06B 21/00: Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B 47/00: Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B: EXPLOSIVES OR THERMIC COMPOSITIONS (blasting F42D); MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES (compounds in general C01, C07 or C08; {demolition agents based on cementitious or like materials C04B41/0009})

## Abstract

The invention relates to a method of safely preparing stable water-in-oil emulsion explosives. After formation of the emulsion explosive, it is cooled in a heat exchanger which uniformly cools the emulsion. The physical characteristics of the heat exchanger also limit the extent of detonation if it should occur. In order to improve stability of the emulsion explosive, the oxidizer is blended with the emulsion subsequent to cooling the emulsion.

## Claims

### Claim 1

A method of preparing an explosive composition comprising:
(a) forming a water-in-oil emulsion explosive;
(b) uniformly cooling said emulsion using a shell and tube heat exchanger; and
(c) adding an oxidizer to said emulsion.

### Claim 2 (depends on 1)

A method according to claim 1, wherein the effective diameter of each tube of said heat exchanger is less than the critical diameter necessary to sustain detonation.

### Claim 3 (depends on 2)

A method according to claim 2, wherein said heat exchanger is provided with static mixer elements within the tubes of said heat exchanger.

### Claim 4 (depends on 1)

A method according to claim 1, wherein said heat exchanger maintains a constant temperature within said emulsion exiting said exchanger.

### Claim 5 (depends on 1)

A method according to claim 1, wherein said cooling is conducted prior to adding salt oxidizer.

### Claim 6 (depends on 1)

A method according to claim 1, wherein said oxidizer comprises an inorganic nitrate.

### Claim 7 (depends on 1)

A method according to claim 1, wherein said oxidizer comprises ammonium nitrate prills.

### Claim 8

A method of preparing an emulsion explosive composition comprising:
(a) forming a water-in-oil emulsion explosive;
(b) uniformly cooling said emulsion using a shell and tube heat exchanger, said heat exchanger provided with tubes having an effective diameter less than the critical diameter necessary to sustain detonation of said emulsion; and
(c) adding an oxidizer to said emulsion.

### Claim 9

A method of preparing a stable emulsion explosive composition comprising:
(a) forming a water-in-oil emulsion explosive; and
(b) uniformly cooling said emulsion explosive using a shell and tube heat exchanger prior to adding an oxidizer.

### Claim 10 (depends on 9)

A method according to claim 9, wherein the effective diameter of each tube of said shell and tube heat exchanger is less than the critical diameter necessary to sustain detonation.

### Claim 11 (depends on 9)

A method according to claim 9, wherein said heat exchanger is provided with static mixer elements within the tubes of said heat exchanger.

### Claim 12 (depends on 9)

A method according to claim 9, wherein said heat exchanger maintains a constant temperature with emulsion exiting the heat exchanger.