# US 5,346,537 A · Method and system for controlling emissions from glycol dehydrators > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,346,537 A - Document ID: US5346537A - Status: Granted - Kind: A - Application number: 08/059,490 - Filed: 1993-05-10 - Granted: 1994-09-13 - Earliest claimed: 1992-01-24 - Assignees: Gas Research Institute - Inventors: Philip S. Lowell - Web page: https://patentgrep.com/patent/US5346537A ## CPC - B01D 53/263: {by absorption} - B01D 53/1425: {Regeneration of liquid absorbents} - C10L 3/10: Working-up natural gas or synthetic natural gas - B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28) - C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS ## Abstract Method and apparatus are disclosed which are improvements in the conventional method and apparatus for extracting water from a gas stream such as a natural gas stream by contacting the stream with a glycol to absorb the water, and then regenerating the glycol for further use in extraction by heating the moist glycol in a glycol regenerator to vaporize the water contained in same as steam. The improvement enables control of emissions of volatile organic compounds which have been absorbed by the glycol during contact with the gas stream, while minimizing the contaminants in the water streams produced. The vented steam and gaseous volatile organics are flowed from the glycol regenerator as input to a cooling condenser having successive air and water-cooled condensers, to produce a condenser water stream having a relatively high content of the organic compounds. The condenser water stream is passed to a cooling tower and then through the tower in counter-current or cross-current relation to stripping air, whereby the condenser water stream is stripped of substantial parts of its organics content and emerges as a stripped water stream having low content of the organics. The stripped water stream is used to cool the water-cooled condenser. ## Claims ### Claim 1 In the method for extracting water from a gas stream containing quantities of water and of volatile organic compounds by contacting said gas stream with a glycol to absorb the water, and then regenerating the glycol for further use in said extracting by heating the moist glycol in a glycol regenerator to vaporize the water contained in same as steam and venting the steam and gasified volatile organics which have been absorbed by the glycol during contact with the gas stream; the improvement enabling control of emissions of said volatile organic compounds which have been absorbed by the glycol during contact with said gas stream, while minimizing contaminants in the produced water streams; comprising: flowing the vented steam and gasified volatile organics from the glycol regenerator as input to a cooling condenser means including in series an air-cooled condenser and a downstream water-cooled condenser, said input being condensed at said condenser means into a condenser water stream having a relatively high content of said organic compounds, an organic vent gas, and an organic liquid; passing said condenser water stream through a cooling tower in counter-current or cross-current relation to stripping air, whereby said condenser water stream is stripped of substantial parts of its organics content and emerges from the bottom of said cooling tower as a stripped water stream having relatively low content of said organics; and utilizing at least a part of the stripped water stream for cooling said water-cooled condenser. ### Claim 2 (depends on 1) A method in accordance with claim 1, wherein said cooling tower is a counter-current cooling tower, said water stream being provided to the top of said counter-current cooling tower and allowed to descend countercurrent to said stripping air. ### Claim 3 (depends on 1) A method in accordance with claim 1, wherein the stripping air having passed in counter-current or crosscurrent relation to said condenser water stream is vented to atmosphere. ### Claim 4 (depends on 1) A method in accordance with claim 1, wherein the stripping air having passed in counter-current or crosscurrent relation to said condenser water stream is used to cool said air-cooled condenser. ### Claim 5 (depends on 1) A method in accordance with claim 1, wherein the moist glycol from contact with the said gas stream is passed through a flash tank before being passed to said regenerator for moisture extraction, said flash tank effecting separation of light hydrocarbons as flash gas; and wherein said flash gas is provided as a heating source to said glycol regenerator. ### Claim 6 (depends on 1) A method in accordance with claim 1, wherein said gas stream is a produced natural gas. ### Claim 7 In a system for extracting water from a gas stream containing quantities of water and of volatile organic compounds, which system includes a glycol regenerator including a heating section for heating moist glycol provided thereto to thereby separate and vent the moisture from same as steam and gasified volatile organics which have been absorbed by the glycol during contact with the gas stream; means to provide the moist glycol having contacted the gas stream to said glycol regenerator for heating, and means for discharging the dried glycol from said regenerator and recycle same for further drying of said gas stream; the improvement enabling control of emissions of volatile organic compounds which have been absorbed by the glycol during contact with said gas stream and which are vented with said steam, while minimizing the organic contaminants in the water streams produced; comprising: a cooling condenser means including in series an air-cooled condenser and a downstream water-cooled condenser; means for flowing the vented steam and gaseous volatile organics from the glycol regenerator as an input to said cooling condenser means to produce a condenser water stream having a relatively high content of said organic compounds; a cooling tower having means for establishing a flow of stripping air; means for passing said condenser water stream as an input to said cooling tower, and thence through said tower in counter-current or cross-current relation to said stripping air, whereby said condenser water stream is stripped of substantial parts of its organics content and emerges from said cooling tower as a stripped water stream having relatively low content of said organics; and means for recirculating at least part of said stripped water stream as a coolant for said water-cooled condenser. ### Claim 8 (depends on 7) A system in accordance with claim 7, further including an accumulator for receiving the output from said water-cooled condenser, and splitting the output into water, organic liquid, and vent gas streams. ### Claim 9 (depends on 7) A system in accordance with claim 7, further including a flash tank connected to receive the moist glycol from contact with said gas stream before passing same to said regenerator for moisture extraction, and effect separation of light hydrocarbons as flash gas; said flash gas being provided to said regenerator for use as a heating fuel. ### Claim 10 (depends on 7) A system in accordance with claim 7, further including means for providing the stripping air emerging from said cooling tower as a coolant to said air-cooled condenser.