# US 5,346,509 A · Process for dyeing hair by the sequential treatment of hair with metal ion-containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid and certain derivatives thereof

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- Number: US 5,346,509 A
- Document ID: US5346509A
- Status: Granted
- Kind: A
- Application number: 08/046,462
- Filed: 1993-04-14
- Granted: 1994-09-13
- Earliest claimed: 1988-05-12
- Assignees: Clairol Incorporated
- Inventors: Thomas M. Schultz; Keith C. Brown; Leszek J. Wolfram; Giuseppe Prota
- Web page: https://patentgrep.com/patent/US5346509A

## CPC

- A61K 8/492: {having condensed rings, e.g. indol}
- A61K 8/19: containing inorganic ingredients
- A61Q 5/10: Preparations for permanently dyeing the hair
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS

## Abstract

Process for dyeing human hair by the sequential treatment of the hair with a metal ion and particularly transition metal ion containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid.

## Claims

### Claim 1

A process for dyeing human hair a brown color, the process consisting of the steps set forth below:
(a) applying to the hair an aqueous buffered hair dye composition having a pH of from about 3 to about 10, said hair dye composition consisting essentially of from about 0.01 to about 5% by weight of a colorant having the structure: ##STR2## wherein R.sub.1 is hydrogen, benzyl or an alkyl of from 1 to 6 carbon atoms and R.sub.2 is hydrogen, benzyl or an alkyl substituent group;
(b) applying an aqueous composition consisting essentially of a transition metal ion selected from the group consisting of Cu.sup.+2, Fe.sup.+2, Fe.sup.+3, Co.sup.+2, Mn.sup.+2 and Ti.sup.+2 to the hair for a period of time sufficient to deposit on the hair an amount of said metal ion effective to promote the conversion of the colorant of structure I to a melanin-type pigment,
said step (a) being conducted before or after the conduct of step (b), and
(c) optionally rinsing the hair with water following steps (a) and (b),
the hair following the completion of the process having a brown color tone.

### Claim 2 (depends on 1)

The process of claim 1 wherein the concentration of the metal ion in said aqueous composition is such as to effect said deposit in not more than about 10 minutes.

### Claim 3 (depends on 1, 2)

The process of claim 1 or 2 wherein the transition metal ion is Cu.sup.+2.

### Claim 4 (depends on 1)

The process of claim 1 wherein the colorant of structure I is 5,6-dihydroxyindole-2-carboxylic acid.

### Claim 5 (depends on 1)

The process of claim 1 wherein the colorant of structure I is 5,6-dihydroxyindole-2-carboxyalkyl ester.

### Claim 6 (depends on 1, 4, 5)

The process of claim 1, 4 or 5 wherein step (b) is conducted in advance of step (a).

### Claim 7 (depends on 1, 4, 5)

The process of claim 1, 4 or 5 wherein step (a) is conducted in advance of step (b).

### Claim 8 (depends on 1, 4, 5)

The process of claim 1, 4 or 5 wherein the hair dye composition further contains 5,6-dihydroxyindole.