# US 5,345,397 A · Optimal composite curing system and method

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- Number: US 5,345,397 A
- Document ID: US5345397A
- Status: Granted
- Kind: A
- Application number: 07/796,933
- Filed: 1991-11-25
- Granted: 1994-09-06
- Earliest claimed: 1991-11-25
- Assignees: The Boeing Company
- Inventors: Paul I. Handel; Matthew J. Patterson; Daniel Guerin; Nicholas C. Strauss; Steven B. Helton; Thomas M. Barrett; Lisa K. Koelewyn; James D. Waterman
- Web page: https://patentgrep.com/patent/US5345397A

## CPC

- B29C 35/0288: {Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process (controlling or regulating chemical, physical or physico- chemical processes in general B01J19/0006)}
- B29C 2037/903: {by means of a computer}
- B29K 2105/06: containing reinforcements, fillers or inserts
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS

## Abstract

An intelligent control system for directing a process for curing parts made of fiber-reinforced composite material in an autoclave. The system uses data gathered during the curing processing to calculate repetitively the temperature of the autoclave required to establish and maintain a predetermined cure temperature. The system accounts for heat generated by the exothermal reaction of the resin during polymerization. The control recalculates an optimal autoclave temperature at periodic intervals during the cure cycle on the basis of temperature data from the part being cured and temperature within the autoclave. The optimal autoclave temperature is determined from calculated values representing resin heat, maximum offset, lag time and degree of cure of the resin. Control signals produced by a computer that executes control algorithms stored in electronic memory accessible to the processor cause corresponding changes in the temperature of the autoclave needed to cure the part without overheating and in less time than with a conventional autoclave temperature control.

## Claims

### Claim 1

A method for controlling the curing process of a part formed of fiber-reinforced thermosetting resin composite material in an autoclave with the aid of a digital computer, comprising the steps of:
placing a part of composite material in an autoclave and initiating a curing process of the part;
repetitively measuring the temperature of the autoclave during the curing process;
repetitively measuring the temperature of the part during the curing process;
repetitively measuring the time elapsed during the curing process;
increasing the autoclave temperature;
providing the computer with autoclave temperature, part temperature, elapsed time, and properties of the resin
repetitively calculating in the computer at frequent intervals during the curing process lag time before the temperature of the part being cured rises to a predetermined temperature lower than a temperature where resin reaction produces heat;
repetitively calculating in the computer at frequent intervals during the curing process the degree of cure;
repetitively determining in the computer at frequent intervals during the curing process the time rate of change of the degree of cure;
repetitively calculating resin heat in the computer at frequent intervals during the curing process after the part temperature exceeds the predetermined temperature;
repetitively determining the maximum offset in the computer at frequent intervals;
determining optimal autoclave temperature from current degree of cure and current maximum offset; and
changing current autoclave temperature to the current optimal autoclave temperature.

### Claim 2 (depends on 1)

The method of claim 1 further comprising the steps of:
continuing to change the temperature of the autoclave until the elapsed time reaches a predetermined limit; and
reducing the temperature of the autoclave at a predetermined rate until the temperature of the part to be cured reaches the optimal autoclave temperature.

### Claim 3 (depends on 1)

The method of claim 1 further comprising the steps of:
supporting the part to be cured on a support surface;
sealing the part to be cured air-tight in a space;
evacuating said space during the curing process; and
forcing the part into contact with the support surface by pressurizing the ambient atmosphere.

### Claim 4 (depends on 2)

The method of claim 2 further comprising the steps of:
supporting the part to be cured on a support surface;
sealing the part to be cured air-tight in a space;
evacuating said space during the curing process; and
forcing the part to be cured into contact with the support surface by pressurizing the ambient atmosphere.

### Claim 5 (depends on 1)

The method of claim 1 wherein the resin is epoxy.

### Claim 6 (depends on 1)

The method of claim 1 wherein the fiber is selected from the group consisting of glass, boron, graphite, carbon and organic fiber.

### Claim 7 (depends on 1)

The method of claim 1 wherein the temperature of the autoclave, the temperature of the part to be cured and the elapsed time are measured substantially concurrently at predetermined intervals during the curing process, and wherein the lag time is calculated from the following relationship:
T2=TF2-X*B+(T1-TF1+X-B)*EXP(-DELTA t/X)
wherein
t is time;
DELTA is the time between successive intervals;
T1 is the temperature of the part to be cured at time t.sub.1 ;
T2 is the temperature of the part to be cured at time t.sub.2 +DELTA t;
TF1 is the temperature of the autoclave at time t.sub.1 ;
TF2 is the temperature of the autoclave at t.sub.2 +DELTA t;
B is the temperature of the autoclave heat rate;
EXP is an exponential function;
X is the lag time.

### Claim 8 (depends on 1)

The method of claim 1 wherein the temperature of the autoclave, the temperature of the part to be cured and the elapsed time are measured substantially concurrently at predetermined intervals during the curing process, and wherein the degree of cure, ALPHA, is calculated from the following relationships:
d(ALPHA)/dT=(K1+K2*ALPHA) (1-ALPHA) (BETA-ALPHA)
if ALPHA is equal to or less than 0.3, and
d(i ALPHA)/dT=K3 (1-ALPHA)
if ALPHA is less than 0.3
where,
K1=A1 EXP(-DELTA E1/R*T1)
K2=A2 EXP(-DELTA E2/R*T1)
K3=A3 EXP(-DELTA E3/R*T1)
t is time;
DELTA t is time between successive intervals;
T1 is the temperature of the part to be cured at time t.sub.1 ;
T2 is the temperature of the part to be cured at time t.sub.2 +DELTA t;
EXP is an exponential function;
D(ALPHA)/DT is the time rate of change of cure;
A1, A2, A3 are material properties of the resin;
DELTA AE1, DELTA AE2, DELTA AE3 are resin properties;
R is the universal gas constant;
T is temperature; and
BETA is a resin property.

### Claim 9 (depends on 1)

The method of claim 1 wherein the temperature of the autoclave, the temperature of the part to be cured and the elapsed time ae measured substantially concurrently at predetermined intervals during the curing process, and wherein the lag time is calculated fro the following relationships:
T2=TF2-X*B+(T1-TF1+X*B)*EXP(-DELTA t/X)+DELTA T (d ALPHA/dt) (RESIN HEAT)
T2=TF2-X*B+(T1-TF1+X-B)*EXP(-DELTA t/X)
wherein
t is time;
DELTA t is the time between successive intervals;
T1 is the temperature of the part to be cured at time t.sub.1 ;
T2 is the temperature of the part to be cured at time t.sub.2 +DELTA t;
TF1 is the temperature of the autoclave at time t.sub.1 ;
TF2 is the temperature of the autoclave at t.sub.2 +DELTA t;
B is the temperature of the autoclave heat rate;
EXP is an exponential function;
X is a lag time; and
D(ALPHA)/DT is the time rate of change of the degree of cure.

### Claim 10

A method for controlling the curing process of a part formed of fiber-reinforced thermosetting resin composite material, comprising the steps of:
measuring the ambient temperature surrounding the part to be cured;
measuring the temperature of the part to be cured;
measuring the time elapsed during the curing process;
increasing the ambient temperature;
calculating the lag time from the ambient temperature and the temperature of the part to be cured before the temperature of the part to be cured rises to a predetermined temperature lower than the temperature where resin reaction produces heat;
calculating the degree of cure from the temperature of the part to be cured and the properties of the resin;
determining the time rate of change of the degree of cure;
calculating resin heat from the ambient temperature, the temperature of the part to be cured and the time rate of change of the degree of cure after the temperature of the part to be cured exceeds the predetermined temperature;
determining maximum offset;
determining the optimal temperature of the autoclave from the degree of cure and the maximum offset; and
changing the ambient temperature to the optimal temperature of the autoclave.

### Claim 11 (depends on 10)

The method of claim 10, further comprising the steps of:
supporting the part to be cured on a support surface;
sealing the part to be cured air-tight in a space;
evacuating said space during the curing process; and
forcing the part into contact with the support surface by pressurizing the ambient atmosphere.

### Claim 12 (depends on 10)

The method of claim 10 wherein the resin is epoxy.

### Claim 13 (depends on 10)

The method of claim 10 wherein the fiber is selected from the group consisting of glass, boron, graphite, carbon and organic fiber.

### Claim 14 (depends on 10)

The method of claim 10 wherein the ambient temperature, the temperature of the part to be cured and the elapsed time are measured substantially concurrently at predetermined intervals during the curing process, and wherein the lag time is calculated from the following relationship:
T2=TF2-X*B+(T1-TF1+X*B)*EXP(-DELTA t/X)
wherein
t is time;
DELTA t is the time between successive intervals;
T1 is the temperature of the part to be cured at time t.sub.1 ;
T2 is the temperature of the part to be cured at time t.sub.2 +DELTA t;
TF1 is the ambient temperature at time t.sub.1 ;
TF2 is the ambient temperature at t.sub.2 +DELTA t;
B is the ambient temperature heat rate;
EXP is an exponential function; and
X is the lag time.

### Claim 15 (depends on 10)

The method of claim 10 wherein the ambient temperature, the temperature of the part to be cured and the elapsed time are measured substantially concurrently at predetermined intervals during the curing process, and wherein the degree of cure ALPHA is calculated from the following relationships:
d(ALPHA)/dT=(K1+K2*ALPHA) (1-ALPHA) (BETA-ALPHA)
if ALPHA is equal to or less than 0.3, and
d(ALPHA)/dT=K3 (1-ALPHA)
if ALPHA is less than 0.3
where,
K1=A1 EXP(-DELTA E1/R*T1)
K2=A2 EXP(-DELTA E2/R*T1)
K3=A3 EXP(-DELTA E3/R*T1)
t is time;
DELTA t is the time between successive intervals;
T1 is the temperature of the part to be cured at time t.sub.1 ;
T2 is the temperature of the part to be cured at time t.sub.2 +DELTA t;
EXP is an exponential function;
D(ALPHA)/DT is the time rate of change of cure;
A1, A2, A3 are material properties of the resin;
DELTA AE1, DELTA AE2, DELTA AE3 are resin properties;
R is the universal gas constant;
T is temperature; and
BETA is a resin property.

### Claim 16 (depends on 10)

The method of claim 10 wherein the ambient temperature, the temperature of the part to be cured and the elapsed time are measured substantially concurrently at predetermined intervals during the curing process, and wherein the lag time is calculated from the following relationships:
T2=TF2-X*B+(T1-TF1+X*B)*EXP(-DELTA t/X)+DELTA T (d ALPHA/dt) (RESIN HEAT)
T2=TF2-X*B+(T1-TF1+X*B)*EXP(-DELTA t/X)
wherein
t is time;
DELTA t is the time between successive intervals;
T1 is the temperature of the part to be cured at time t.sub.1 ;
T2 is the temperature of the part to be cured at time t.sub.2 +DELTA t;
TF1 is the ambient temperature at time t.sub.1
TF2 is the ambient temperature at t.sub.2 +DELTA t;
B is the ambient temperature heat rate;
EXP is an exponential function;
X is the lag time; and
D(ALPHA)/DT is the time rate of change of degree of cure.

### Claim 17 (depends on 10)

The method of claim 10 further comprising the steps of:
continuing to change the ambient temperature until the elapsed time reaches a predetermined limit; and
reducing the ambient temperature at a predetermined rate until the temperature of the part to be cured reaches the optimal autoclave temperature.

### Claim 18

A method for controlling the curing process of a part formed of fiber-reinforced thermosetting resin composite material, comprising the steps of:
measuring the ambient temperature surrounding the part during the curing process;
measuring the temperature of the part during the curing process;
measuring the time elapsed during the curing process;
increasing the ambient temperature;
calculating the lag time from the ambient temperature and the temperature of the part to be cured before the temperature of the part to be cured rises to a predetermined temperature lower than the temperature where resin reaction produces heat;
calculating the degree of cure from the temperature of the part to be cured and the properties of the resin;
determining the optimal autoclave temperature from the degree of cure; and
changing the ambient temperature to the optimal ambient temperature.

### Claim 19 (depends on 18)

The method of claim 18 further comprising the steps of:
supporting the part to be cured on a support surface;
sealing the part to be cured air-tight in a space;
evacuating said space during the curing process; and
forcing the part into contact with the support surface by pressurizing the ambient atmosphere.