# US 5,345,005 A · Hydrogenation catalyst, process for preparing and process of using said catalyst > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,345,005 A - Document ID: US5345005A - Status: Granted - Kind: A - Application number: 07/930,123 - Filed: 1992-09-18 - Granted: 1994-09-06 - Earliest claimed: 1989-09-12 - Assignees: Engelhard Corporation - Inventors: Deepak S. Thakur; Brian L. Roberts; Thomas J. Sullivan; Anita L. Vichek - Web page: https://patentgrep.com/patent/US5345005A ## CPC - B01J 23/80: with zinc, cadmium or mercury - B01J 35/40: characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) - B01J 35/45: Nanoparticles - B01J 35/613: {10-100 m2/g} - B01J 35/638: {more than 1.0 ml/g} - B01J 35/66: Pore distribution - B01J 35/70: characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) - B01J 35/77: Compounds characterised by their crystallite size - B01J 37/031: {Precipitation} - C07C 29/141: with hydrogen or hydrogen-containing gases - C07C 29/145: with hydrogen or hydrogen-containing gases - C07C 29/149: with hydrogen or hydrogen-containing gases - B01J 2235/15: X-ray diffraction - B01J 2235/30: Scanning electron microscopy; Transmission electron microscopy - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS ## Abstract In one embodiment, the invention relates to a catalyst in powdered form which comprises a major amount of the oxides of copper and zinc, and a minor amount of aluminum oxide wherein the pore volume of pores of said catalysts having a diameter between about 120 and about 1000 .ANG. is at least about 40% of the total pore volume. In another embodiment, the invention relates to a process for preparing hydrogenation catalysts comprising the oxides of copper, zinc and aluminum which comprises the steps of (A) preparing a first aqueous solution containing at least one water-soluble copper salt and at least one water-soluble zinc salt; (B) preparing a second solution containing at least one water-soluble basic aluminum salt and at least one alkaline precipitating agent; (C) mixing the first and second solutions whereby an insoluble solid is formed; (D) recovering the insoluble solid. The invention also relates to a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters with catalysts of the type described. Catalysts of the invention are useful in both fixed bed and slurry phase hydrogenation reactions. ## Claims ### Claim 1 In a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters to alcohols comprising contacting the aldehyde, ketones, acid or ester with hydrogen and a catalyst under catalytic hydrogenation conditions, the improvement comprising using a catalyst in powdered form comprising a major amount of the oxides of copper and zinc, and a minor amount of aluminum oxide wherein the pore volume of the pores in said catalyst having a diameter of between about 120 and about 1000 A is at least about 40% of the total pore volume. ### Claim 2 (depends on 1) The process of claim 1 wherein the pore volume of the pores in said catalyst having a diameter of greater than 120 .ANG. is at least about 70% of the total pore volume. ### Claim 3 (depends on 1) The process of claim 1 wherein said catalyst powders have a surface area of at least 50 square meters per gram. ### Claim 4 (depends on 1) The process of claim 1 wherein said catalyst powders have an average particle diameter of from about 8 to about 30 microns. ### Claim 5 (depends on 1) The process of claim 1 wherein the atomic ratio of copper to zinc in said catalyst is about 0.2 to about 5.5. ### Claim 6 (depends on 1) The process of claim 1 wherein the atomic ratio of copper to zinc in said catalyst is from about 0.5 to about 3.0. ### Claim 7 (depends on 1) The process of claim 1 wherein the atomic ratio of copper to zinc in said catalyst is less than 1. ### Claim 8 (depends on 1) The process of claim 1 wherein the copper to zinc atomic ratio in said catalyst is less than about 0.85. ### Claim 9 (depends on 1) The process of claim 1 wherein the atomic ratio in of copper to zinc in said catalyst is from about 0.5 to about 0.85. ### Claim 10 (depends on 1) The process of claim 1 wherein the catalyst contains from about 3 to about 50% by weight of aluminum oxide. ### Claim 11 (depends on 1) The process of claim 1 wherein the atomic ratio of copper and zinc to aluminum in said catalyst is less than about 15. ### Claim 12 (depends on 1) The process of claim 1 wherein said catalyst is free of chromium and cobalt. ### Claim 13 (depends on 1) The process of claim 1 wherein said catalyst, for atomic ratios of copper to zinc from about 0.5 to 5.5 and an aluminum content greater than about 8 wt. percent, the particle size span from the smallest 10% of the particles to the largest 10% is between 10 and 45 microns. ### Claim 14 (depends on 1) The process of claim 1 wherein said catalyst, for atomic ratios of copper to zinc from about 0.5 to 5.5 and an aluminum content greater than about 8 wt. percent, the median particle size is between 5 and 20 microns. ### Claim 15 (depends on 1) The process of claim 1 wherein said catalyst, for atomic ratios of copper to zinc of greater than about 1.5 and an aluminum content greater than about 3 wt. percent, the particle size span is between 22 and 45 microns. ### Claim 16 (depends on 1) The process of claim 1 wherein said catalyst, for atomic ratios of copper to zinc of greater than about 1.5 and an aluminum content greater than about 3 wt. percent, the median particle size is between 8 and 25 microns. ### Claim 17 In a process for hydrogenating carboxylic acid esters to alcohols comprising contacting the ester with hydrogen and a catalyst under catalytic hydrogenation conditions, the improvement comprising using a catalyst in powdered form comprising the oxides of copper, zinc and aluminum wherein the atomic ratio of copper to zinc is less than about 0.85, provided that the catalyst does not contain chromium, boron or cobalt, wherein the pore volume of the pores in said catalyst having a diameter of between about 120 and about 1000 .ANG. is at least about 40% of the total pore volume. ### Claim 18 (depends on 17) The process of claim 17 wherein the pore volume of pores in the catalyst having a diameter of greater than 120 .ANG. is at least about 70% of the total pore volume. ### Claim 19 (depends on 17) The process of claim 17 conducted in the liquid phase.