# US 5,344,887 A · Star polymers of dienes, vinylarenes and alkyl methacrylates as modiied viscosity index improvers

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 5,344,887 A
- Document ID: US5344887A
- Status: Granted
- Kind: A
- Application number: 07/993,740
- Filed: 1992-12-21
- Granted: 1994-09-06
- Earliest claimed: 1992-12-21
- Assignees: Shell Oil Company
- Inventors: Robert J. Sutherland; Dean A. DuBois
- Web page: https://patentgrep.com/patent/US5344887A

## CPC

- C10M 149/02: Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08F 8/04: Reduction, e.g. hydrogenation
- C08F 8/32: by reaction with amines
- C08F 297/023: {using a coupling agent}
- C10M 145/14: Acrylate; Methacrylate
- C10M 2209/084: Acrylate; Methacrylate
- C10M 2217/00: Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M 2217/02: Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M 2217/04: Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10N 2040/06: Instruments or other precision apparatus, e.g. damping fluids
- C10N 2040/08: Hydraulic fluids, e.g. brake-fluids
- C10N 2040/20: Metal working
- C10N 2040/25: Internal-combustion engines
- C10N 2040/251: {Alcohol-fuelled engines}
- C10N 2040/255: {Gasoline engines}
- C10N 2040/28: Rotary {engines}
- C10N 2070/02: {Concentrating of additives}
- C10M: LUBRICATING COMPOSITIONS (well drilling compositions C09K8/02); USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION (mould release, i.e. separating, agents for metals B22C3/00, for plastics or substances in a plastic state, in general B29C33/56, for glass C03B40/02; textile lubricating compositions D06M11/00, D06M13/00, D06M15/00; immersion oils for microscopy G02B21/33)
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C10N: INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS

## Abstract

Star polymers having first polymeric arms comprising a hydrogenated conjugated diene and smaller second polymeric arms of a methacrylate resist coupling of methacrylate blocks attached to different cores and have improved performance as viscosity index improvers. The polymerized methacrylate units are converted to amide or imide groups by reaction with a primary or secondary amine to give the viscosity index improver dispersant properties.

## Claims

### Claim 1

A polymer comprising:
an average per molecule of at least 10 first arms consisting of completely hydrogenated isoprene or styrene and completely hydrogenated isoprene, the first arms having a peak molecular weight from 10,000 to 100,000, wherein at least 5% of the polymerized isoprene is produced by 1,4-polymerization;
an average per molecule of at least 10 second arms consisting of polymerized t-butylmethacrylate, the second arms having a peak molecular weight from 1,000 to 10,000, wherein the first arms are longer than the second arms, the number of first arms is greater than or equal to the number of second arms, and at least 80% of the polymerized t-butylmethacrylate units have been converted to amide or imide groups; and
one central core per molecule, the core comprising a polymerized divinylbenzene, wherein the central cores connect the first and second arms in a star configuration and the central core is no more than 10% of the polymer molecular weight.

### Claim 2 (depends on 1)

The polymer of claim 1, wherein the first arms consist of isoprene and styrene.

### Claim 3 (depends on 1)

The polymer of claim 1, wherein the average number of first arms per polymer molecule is from 10 to 50 and the average number of second arms per polymer molecule is from 10 to 50.

### Claim 4 (depends on 1)

The polymer of claim 1, wherein the peak molecular weight of the first arms is from 10,000 to 100,000 and the peak molecular weight of the second arms is from 500 to 10,000.

### Claim 5

A process for making a polymer, comprising the steps of:
anionically polymerizing first arms comprising a conjugated diene, the first arms having a peak molecular weight from 10,000 to 200,000, wherein at least 5% of the polymerized conjugated diene is produced by 1,4-polymerization;
coupling the first arms with a bisunsaturated compound to form central cores, wherein the central cores are no more than 10% of the polymer molecular weight;
anionically polymerizing a methacrylate to grow second polymeric arms from the central cores, the second polymeric arms having a peak molecular weight from 1,000 to 10,000, wherein the first arms are longer than the second arms and the number of first arms is greater than the number of second arms;
converting at least 80% of the polymerized methacrylate units to amide or imide groups; and
completely hydrogenating the polymerized conjugate diene.

### Claim 6 (depends on 5)

The process of claim 5, wherein the first arms comprise styrene and isoprene and the methacrylate is t-butylmethacrylate.

### Claim 7 (depends on 6)

The process of claim 6, wherein the styrene and the isoprene are present in homopolymer blocks.