# US 5,344,878 A · Highly transparent tough polymer blends

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- Number: US 5,344,878 A
- Document ID: US5344878A
- Status: Granted
- Kind: A
- Application number: 08/025,606
- Filed: 1993-03-03
- Granted: 1994-09-06
- Earliest claimed: 1993-03-03
- Assignees: Novacor Chemicals (International) S.A.
- Inventors: Michael Colella; Brian Marcoulier
- Web page: https://patentgrep.com/patent/US5344878A

## CPC

- C08L 25/14: with unsaturated esters
- C08L 51/04: grafted on to rubbers
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

There is a demand for very clear tough polymers or polymer blends, particularly in the packaging industry. Crystal polystyrene is clear but lacks toughness. HIPS is tough but lacks the required clarity. Blends of styrene-ester polymers with a very small amount of HIPS do provide a very clear tough polymer alloy.

## Claims

### Claim 1

A polymer blend consisting essentially of:
(1) 97 to 99 weight % of a copolymer consisting essentially of:
(a) from 70 to 90 weight % of one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, p-methyl styrene, and t-butyl styrene; and
(b) from 30 to 10 weight % of one or monomers selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and butyl acrylate; and
(2) from 3 to 1 weight % of an impact modified polymer consisting essentially of:
(a) from 4 to 15 weight % of a rubbery polymer selected from the group consisting of:
(i) co- and homo-polymers of C.sub.4-6 conjugated diolefins; and
(ii) copolymers comprising:
(A) from 60 to 80 weight % of one or more C.sub.4-6 conjugated diolefins; and
(B) from 40 to 20 weight % of one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, p-methyl styrene, and t-butyl styrene,
to which has been grafted at least a portion of:
(b) from 85 to 96 weight % of a polymer prepared by polymerizing a monomer mixture comprising:
(b) from 85 to 96 % of a polymer prepared by polymerizing a monomer mixture comprising:
(i) from 100 to 70 weight % one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, p-methyl styrene, and t-butyl styrene; and
(ii) from 0 to 30 weight % of one or more monomers selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and butyl acrylate.

### Claim 2 (depends on 1)

The polymer blend according to claim 1, wherein component 1 consists essentially of:
(a) from 75 to 80 weight % of one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, p-methyl styrene, and t-butyl styrene; and
(b) from 25 to 20 weight % of one or monomers selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and butyl acrylate.

### Claim 3 (depends on 2)

The polymer blend according to claim 2, wherein component 2 is an impact modified polymer consisting essentially of:
(a) from 4 to 15 weight % of polybutadiene, to which has been grafted at least a portion of;
(b) from 96 to 85 weight % of a polymer prepared by polymerizing styrene.

### Claim 4 (depends on 3)

The polymer blend according to claim 3, wherein component 2 is an impact modified polymer consisting essentially of:
(a) from 4 to 10 weight % of polybutadiene, to which has been grafted at least a portion of;
(b) from 96 to 90 weight % of a polymer prepared by polymerizing styrene.

### Claim 5 (depends on 4)

The polymer blend according to claim 4, wherein component 1 consists essentially of:
(a) from 75 to 80 weight % of styrene; and
(b) from 25 to 20 weight % of methyl methacrylate.