# US 5,344,727 A · Bipolar battery electrode

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- Number: US 5,344,727 A
- Document ID: US5344727A
- Status: Granted
- Kind: A
- Application number: 08/079,030
- Filed: 1993-06-21
- Granted: 1994-09-06
- Earliest claimed: 1993-06-21
- Assignees: General Motors Corporation
- Inventors: Clarence A. Meadows; James R. Bish; Robert E. Adams
- Web page: https://patentgrep.com/patent/US5344727A

## CPC

- H01M 10/18: with bipolar electrodes
- H01M 4/14: Electrodes for lead-acid accumulators
- H01M 4/82: Multi-step processes for manufacturing carriers for lead-acid accumulators
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A bipolar electrode for a Pb-acid battery comprising a lead septum plate and a porous coating on at least one face of the septum plate for anchoring at least the positive active material paste to the septum. The porous coating comprises multiple layers of lead particles fused together and to the septum face so as to define a plurality of interconnected, interstitial pores therebetween. The particles are fused droplets of lead arc-sprayed into the surface of the septum. A particular bipolar and battery construction useful with the bipolar electrode is disclosed.

## Claims

### Claim 1

A pasted bi-polar electrode for a Pb-acid storage battery comprising:
an electrolyte-impervious, lead septum;
a highly porous coating comprising multiple layers of lead particles fused to each other and to at least one face of said septum so as to define a plurality of interconnecting, interstitial pores therebetween, said pores being of sufficient size to receive and retain leady active material paste pressed thereinto;
a first leady active material paste overlaying said coating and impregnating at least a portion of said pores; and
a second leady active material overlaying and adhering to a second face of said septum opposite said one face.

### Claim 2 (depends on 1)

A bipolar electrode according to claim 1 wherein said first leady active material comprises PbO.sub.2 and said second leady active material comprises Pb.

### Claim 3 (depends on 1)

A bipolar electrode according to claim 1 wherein said coating also covers said second face.

### Claim 4 (depends on 1)

A bipolar electrode according to claim 1 wherein said particles are solidified droplets of molten lead sprayed onto said septum.

### Claim 5 (depends on 4)

A bipolar electrode according to claim 4 wherein said molten metal is arc-sprayed onto said septum.

### Claim 6 (depends on 5)

A bipolar electrode according to claim 5 wherein said coating has a thickness of about 0.002 to about 0.02 inches.

### Claim 7 (depends on 5)

A bipolar electrode according to claim 5 wherein said particles vary in size from about 10 microns to about 200 microns.

### Claim 8 (depends on 7)

A bipolar electrode according to claim 7 wherein the average size of said pores is about 30 microns to about 50 microns.