# US 5,344,636 A · Anti-microorganism agent and anti-microorganism resin or rubber composition

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- Number: US 5,344,636 A
- Document ID: US5344636A
- Status: Granted
- Kind: A
- Application number: 07/979,230
- Filed: 1992-11-20
- Granted: 1994-09-06
- Earliest claimed: 1991-11-27
- Assignees: Kabushiki Kaisha Kaisui Kagaku Kenkyujo
- Inventors: Shigeo Miyata
- Web page: https://patentgrep.com/patent/US5344636A

## CPC

- C08K 3/22: of metals
- A01N 59/16: Heavy metals; Compounds thereof
- A01N 59/20: Copper
- C01G 3/00: Compounds of copper
- C01G 9/00: Compounds of zinc
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- C01G: COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts or peroxyacids C01B15/00; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium, or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds containing nitrogen, other non-metals and metal C01B21/082}; metal amides C01B21/092; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanamide C01C3/16; thiocyanates C01C3/20)

## Abstract

A anti-microorganism agent completely or nearly free of toxicity, insoluble or sparingly soluble in water or an organic solvent so as not to contaminate the environment and highly effective as such, which is composed of at least one of a composite metal hydroxide of the formula (1), (M.sub.1.sup.2+).sub.1-x (M.sub.2.sup.2+).sub.x (OH).sub.2 ( 1) wherein M.sub.1.sup.2+ is at least one of Mg.sup.2+ and Ca.sup.2+, M.sub.2.sup.2+ is at least one of Cu.sup.2+ and Zn.sup.2+, and x is defined by 0.001.ltoreq.x&lt;0.9, and a composite metal oxide of the formula (2), (M.sub.1.sup.2+).sub.1-y (M.sub.2.sup.2+).sub.y O (2) wherein M.sub.1.sup.2+ is at least one of Mg.sup.2+ and Ca.sup.2+, M.sub.2.sup.2+ is at least one of Cu.sup.2+ and Zn.sup.2+, and y is defined by 0.001.ltoreq.y.ltoreq.0.5, and an anti-microorganism resin or rubber composition containing said anti-microorganism agent.

## Claims

### Claim 1

An anti-microorganism agent composed of at least one member selected from the group consisting of a composite metal hydroxide which is a solid solution of the formula (1),
(M.sub.1.sup.2+).sub.1-x (M.sub.2.sup.2+).sub.x (OH).sub.2 ( 1)
wherein M.sub.1.sup.2+ is at least one member selected from the group consisting of Mg.sup.2+ and Ca.sup.2+, M.sub.2.sup.2+ is at least one member selected from the group consisting of Cu.sup.2+ and Zn.sup.2+, and x is defined by 0.001.ltoreq.x.ltoreq.0.4,
and
a composite metal oxide which is a solid solution of the formula (2),
(M.sub.1.sup.2+).sub.1-y (M.sub.2.sup.2+).sub.y O (2)
wherein M.sub.1.sup.2+ is at least one member selected from the group consisting of Mg.sup.2+ and Ca.sup.2+, M.sub.2.sup.2+ is at least one member selected from the group consisting of Cu.sup.2+ and Zn.sup.2+, and y is defined by 0.001.ltoreq.y.ltoreq.0.5.

### Claim 2 (depends on 1)

An anti-microorganism agent according to claim 1, wherein y in the formula (2) is defined by 0.005.ltoreq.y.ltoreq.0.4.

### Claim 3 (depends on 1)

An anti-microorganism resin or rubber composition containing 100 parts by weight of a resin or rubber and 0.001 to 50 parts by weight of the anti-micoroorganism agent as recited in claim 1.
