# US 5,344,632 A · Method for reducing sulfur oxides emissions in a combustion process

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- Number: US 5,344,632 A
- Document ID: US5344632A
- Status: Granted
- Kind: A
- Application number: 08/030,753
- Filed: 1993-03-12
- Granted: 1994-09-06
- Earliest claimed: 1992-09-11
- Assignees: Foster Wheeler Energy Corporation
- Inventors: John T.-Y. Tang
- Web page: https://patentgrep.com/patent/US5344632A

## CPC

- B01D 53/508: {by treating the gases with solids}
- B01J 8/085: {Feeding reactive fluids (for solid material, see B01J8/0015)}
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

A method for reducing sulfur oxides emissions in a combustion process in which flue gases containing entrained fuel and sorbent particles are humidified so that the sulfur oxides are absorbed on the sorbent particles to reduce the discharge of the sulfur oxides into the environment.

## Claims

### Claim 1

A method of combustion comprising the steps of forming a bed of material containing limestone and fuel; introducing air into said bed to fluidize said material so that, upon combustion of said fuel, sulfur oxides are produced a portion of which are adsorbed by said limestone and a portion of which mix with said air, said mixture entraining some of said material; passing said mixture and entrained material from said bed; then separating a portion of said entrained material from said mixture; passing said separated portion of said entrained material back to said bed; then cooling said mixture and the remaining entrained material to reduce their value; then passing said mixture and remaining entrained material into a vessel at a plurality of levels thereof; breaking the stream of mixture and remaining entrained material into a plurality of smaller streams at one of said levels; dispersing water onto said mixture and remaining entrained material at said one level to evaporate and humidify said mixture at said one level, said temperature being such that said water causes a film of alkali solution of calcium hydroxide to be formed on the surface of the limestone in said entrained material, said solution adsorbing the sulfur oxides in said mixture to form calcium sulfate and calcium sulfite precipitation; and separating said mixture from said calcium sulfate and calcium sulfite precipitation.

### Claim 2 (depends on 1)

The method of claim 1 further comprising the step of maintaining a temperature in said bed sufficient to calcine at least a portion of said limestone.

### Claim 3 (depends on 1)

The method of claim 1 wherein said step of dispersing comprises the step of spraying water on said mixture and entrained material.

### Claim 4 (depends on 1)

The method of claim 1 further comprising the step of removing any additional particles of limestone from said mixture after said latter step of separating.

### Claim 5 (depends on 4)

The method of claim 4 further comprising the step of dispersing additional water on said mixture after said step of removing to evaporate and humidify said mixture.

### Claim 6 (depends on 4)

The method of claim 4 where said stream of mixture and remaining entrained material is introduced into said vessel at three levels.