# US 5,344,528 A · Recovery of phenol from low concentrations with sodium sulfate

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- Number: US 5,344,528 A
- Document ID: US5344528A
- Status: Granted
- Kind: A
- Application number: 08/102,185
- Filed: 1993-08-04
- Granted: 1994-09-06
- Earliest claimed: 1993-08-04
- Assignees: Aristech Chemical Corporation
- Inventors: Thomas H. Bossler; Donald Glassman; Michael C. Grebinoski; Howard H. Morgan, Jr.; Jennifer L. Voss
- Web page: https://patentgrep.com/patent/US5344528A

## CPC

- B01D 3/34: with one or more auxiliary substances
- C07C 37/74: by distillation
- Y10S 203/90: Particular type of heating
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

Phenol plant waste water containing small amounts of phenol and sodium sulfate is successfully distilled through the addition of recovered sodium sulfate to enhance the volatility of the phenol relative to water; at least a portion of the sodium sulfate is recycled, while a significant portion of the phenol can be returned to the phenol plant for recovery.

## Claims

### Claim 1

Method of removing phenol values from concentrations of about 0.5 weight percent to about 4 weight percent in an aqueous solution comprising conducting a distillation of said aqueous solution in the presence of about 8 weight percent to about 18 weight percent sodium sulfate, condensing vapor from said distillation, collecting the condensate therefrom in water-rich and phenol-rich portions, and recovering phenol values from said phenol-rich portion.

### Claim 2 (depends on 1)

Method of claim 1 wherein a phenol-bearing stream is added to said solution prior to distillation, thereby attaining a phenol concentration of up to about 8%.

### Claim 3 (depends on 1)

Method of claim 1 wherein a portion of said sodium sulfate, is recovered from the bottoms of said distillation and recycled to said aqueous solution.

### Claim 4 (depends on 3)

Method of claim 3 wherein the sodium sulfate is recovered by concentrating said bottoms.

### Claim 5 (depends on 3)

Method of claim 3 wherein the sodium sulfate is recovered by evaporative crystallization from said bottoms at a pH of about 3 to about 6, and wherein heat energy is utilized from the condensation of said vapor.

### Claim 6 (depends on 5)

Method of claim 5 followed by centrifugation of said sodium sulfate to recover sodium sulfate crystals.

### Claim 7

Method of recovering phenol and sodium sulfate from an aqueous waste stream comprising sodium sulfate and about 0.5% to about 4% phenol comprising adding sodium sulfate thereto to attain about 8% to about 18% sodium sulfate, distilling said stream to obtain an overhead fraction and a bottoms stream, recovering a phenol stream and a water-rich phenol-containing stream from the overhead fraction, recovering sodium sulfate from the bottoms, recycling at least a portion of said recovered sodium sulfate to said stream at a point prior to said distillation, and recycling said water-rich phenol-containing stream to said aqueous waste stream.