# US 5,344,477 A · Prealloyed high-vanadium, cold work tool steel particles

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- Number: US 5,344,477 A
- Document ID: US5344477A
- Status: Granted
- Kind: A
- Application number: 08/026,013
- Filed: 1993-03-04
- Granted: 1994-09-06
- Earliest claimed: 1991-05-22
- Assignees: Crucible Materials Corporation
- Inventors: William Stasko; Kenneth E. Pinnow
- Web page: https://patentgrep.com/patent/US5344477A

## CPC

- C22C 33/0292: {with more than 5% preformed carbides, nitrides or borides}
- Y10S 75/956: Producing particles containing a dispersed phase
- C22C: ALLOYS (treatment of alloys C21D, C22F)
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

Prealloyed high-vanadium, cold work tool steel particles are provided for use in the powder-metallurgy production of tool steel articles. The particles are of a cold work tool steel alloy having an MC-type vanadium carbide dispersion of a carbide particle size substantially entirely less than 6 microns and in an amount of 18.5 to 34.0% by volume. The particles are produced by atomizing a molten tool steel alloy at a temperature above 2910.degree. F. and rapidly cooling the atomized alloy to form solidified particles therefrom. The particles have the MC-type vanadium carbide dispersion therein.

## Claims

### Claim 1

In prealloyed cold work tool steel particles for use in the powder-metallurgy production of tool steel articles, the improvement comprising:
said particles comprise a cold work tool steel alloy having a substantially uniform MC vanadium carbide dispersion of a carbide particle size substantially entirely less than 6 microns and in an amount of 18.5 to 34.0% by volume,
wherein said particles have a grindability index of above 0.7, as defined herein, a Charpy C-notch impact strength above 3 ft-lbs, as defined herein, and a pin abrasion test weight loss of less than 32 milligrams, as defined herein.

### Claim 2 (depends on 1)

The prealloyed cold work tool steel particles of claim 1, having a carbide particle size substantially entirely less than 4 microns.

### Claim 3 (depends on 1)

The prealloyed cold work tool steel particles of claim 1, constituting gas-atomized, spherical particles.

### Claim 4 (depends on 1, 2)

The prealloyed cold work tool steel particles of claims 1, 2, or 3, wherein said tool steel alloy thereof consists essentially of, in weight percent, 2.6 to 4.70 carbon, up to 0.15 nitrogen, 0.2 to 2.0 manganese, up to 2.0 silicon, 1.5 to 6.0 chromium, up to 6.0 molybdenum, up to 0.30 sulfur, 11.5 to 20.0 vanadium and balance iron and incidental impurities, wherein the carbon and nitrogen are balanced according to the formulas,
percent (C+N).sub.minimum =0.30+0.20 (% V)
percent (C+N).sub.maximum =0.70+0.20 (% V).

### Claim 5 (depends on 1, 2)

The prealloyed cold work tool steel particles of claims 1, 2, or 3, wherein said tool steel alloy thereof consists essentially of, in weight percent, 2.7 to 4.30 carbon, up to 0.15 nitrogen, 0.2 to 1.0 manganese, up to 2.0 silicon, 4.0 to 6.0 chromium, 0.5 to 2.0 molybdenum, up to 0.10 sulfur, 12.0 to 18.0 vanadium and balance iron and incidental impurities, wherein the carbon and nitrogen are balanced according to the formulas,
percent (C+N).sub.minimum =0.30+0.20 (% V)
percent (C+N).sub.maximum =0.70+0.20 (% V).

### Claim 6 (depends on 1, 2)

The prealloyed cold work tool steel particles of claims 1, 2, or 3, wherein said tool steel alloy thereof consists essentially of, in weight percent, 2.7 to 3.90 carbon, up to 0.15 nitrogen, 0.2 to 1.0 manganese, up to 2.0 silicon, 4.5 to 5.5 chromium, 0.5 to 2.0 molybdenum, up to 0.10 sulfur, 12.0 to 16.0 vanadium and balance iron and incidental impurities, wherein the carbon and nitrogen are balanced according to the formulas,
percent (C+N).sub.minimum =0.30+0.20 (% V)
percent (C+N).sub.maximum =0.70+0.20 (% V).