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US 5,342,909 AGranted
Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
AssigneeCalifornia Institute of Technology
InventorsRobert H. Grubbs, Lynda K. Johnson, Sonbinh T. Nguyen
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Abstract
Processes for the synthesis of several new carbene compounds of ruthenium and osmium are provided. These novel complexes function as stable, well-defined catalysts for the metathesis polymerization of cyclic olefins.
Claims5
In the process of metathesis polymerization of cyclic olefins, the improvement comprising carrying out the polymerization in the presence of a catalyst of the formula ##STR35## in the presence of a solvent, wherein:
- M is Os or Ru;
- R and R.sup.1 are independently selected from hydrogen;
- C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.2 -C.sub.20 alkoxycarbonyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.1 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy or aryloxy;
- each optionally substituted with C.sub.1 -C.sub.5 alkyl, halogen, C.sub.1 -C.sub.6 alkoxy or with a phenyl group substituted with halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy;
- X and X.sup.1 are independently selected from an anionic ligand;
- and
- L and L.sup.1 are independently selected from neutral electron donor.
4 more elements
Dependencies are inferred from the claim text.