# US 5,342,022 A · Method of making infrared crystalline fiber

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- Number: US 5,342,022 A
- Document ID: US5342022A
- Status: Granted
- Kind: A
- Application number: 08/013,648
- Filed: 1993-02-04
- Granted: 1994-08-30
- Earliest claimed: 1992-11-23
- Assignees: CeramOptec, Inc.
- Inventors: Vjacheslav G. Artjushenko; Wolfgang Neuberger; Alexey O. Nabatov; Eugene F. Kuzin
- Web page: https://patentgrep.com/patent/US5342022A

## CPC

- G02B 6/02033: {Core or cladding made from organic material, e.g. polymeric material (G02B1/04 takes precedence)}
- C03B 37/023: Fibres composed of different sorts of glass, {e.g. glass optical fibres, made by the double crucible technique}
- C03C 3/32: Non-oxide glass compositions, e.g. binary or ternary halides, sulfides or nitrides of germanium, selenium or tellurium
- C30B 29/12: Halides
- C30B 33/00: After-treatment of single crystals or homogeneous polycrystalline material with defined structure (C30B31/00 takes precedence)
- G02B 6/102: {for infrared and ultraviolet radiation}
- C03B 2201/84: Halide glasses other than fluoride glasses, i.e. Cl, Br or I glasses, e.g. AgCl-AgBr "glass"
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- C03B: MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C30B: SINGLE-CRYSTAL GROWTH (by using ultra-high pressure, e.g. for the formation of diamonds, B01J3/06); UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL (zone-refining of metals or alloys C22B); PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (casting of metals, casting of other substances by the same processes or devices B22D; working of plastics B29; modifying the physical structure of metals or alloys C21D, C22F); SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (for producing semiconductor devices or parts thereof H10); APPARATUS THEREFOR

## Abstract

A method of making silver halide fibers involves reducing turbulence and friction during extrusion by moving an extrusion die in a direction opposite from flowing fiber and against a stationary preform arrangement. In another embodiment, the preform is doped with AgI or is a metal compound of the formula MY wherein M is selected from Li, Na, K, Rb, Cs; or MY.sub.2 wherein M is selected from Mg, Ca, Sr, Pb, Ba, Cd or Hg, and Y is selected from Cl, Br, or I. The resulting fiber has a more even core/clad interface with decrease in grain size to fiber surface and texture elongated along the fiber axis. This structure together with strengthening and stabilizing dopants, added to fiber material, gives decreased and stabilized optical losses and a higher elasticity of fibers.

## Claims

### Claim 1

A process for extruding an optical silver halide fiber, which comprises:
providing a silver halide preform including top, bottom and lateral surfaces;
placing said preform within a cylindrical extrusion chamber comprising an extrusion die;
applying force to said preform while holding said preform in a fixed position wherein said silver halide flows through said extrusion die to produce a silver halide fiber wherein said force is provided by moving said extrusion die and a plunger within said cylindrical extrusion chamber in a direction opposite to said silver halide flow direction thereby reducing friction of said silver halide on said cylindrical chamber and reducing turbulence in said silver halide flow, said silver halide preform has a predetermined shape and cross section, and said plunger has a hollow portion having a cross section which is smaller than the cross section of said preform thus reducing contamination by impurities from lateral surfaces of said preform in the resulting silver halide fiber.

### Claim 2 (depends on 1)

A process for extruding an optical silver halide fiber as claimed in claim 1 wherein said preform within said extrusion chamber includes a core and a cladding, said cladding exhibiting a lower refractive index than said core and wherein additional cladding material is inserted into said extrusion chamber on at least the bottom surface of said preform.

### Claim 3 (depends on 1)

A process for extruding an optical silver halide fiber according to claim 1 wherein said force includes compressing said preform on at least said top and lateral surfaces with inert gas or liquid while forcing said silver halide fiber material through said extrusion die.

### Claim 4 (depends on 1)

A process for extending an optical silver halide fiber according to claim 1 wherein said preform is predeformed prior to said extrusion process by exerting pressure to said lateral surfaces to form a grain texture oriented parallel to said preform and extrusion axes with grain size decreasing from the center of said preform towards its surfaces.