Copolyester of cyclohexanedimethanol and process for producing such polyester
AssigneeEastman Chemical Company
InventorsCheuk C. Yau, Clinton Cherry
Life of this patent
Estimating the term…
Abstract
Disclosed is a process for producing copolyesters having repeat units from a dicarboxylic acid component comprising at least 90 mol % terephthalic acid and a glycol component comprising about 10-95 mol % 1,4-cyclohexanedimethanol and from about 90-5 mol % ethylene glycol comprising reacting the dicarboxylic acid component and the glycol component at temperatures sufficient to effect esterification or transesterification and polycondensing the reaction product in the presence of a catalyst and inhibitor system consisting essentially of Mn, Zn, Ti, Ge and P, all parts by weight based on the weight of the copolyester.
Claims7
Process for producing copolyester having repeat units from a dicarboxylic acid component comprising repeat units from at least 90 mol % terephthalic acid and a glycol component comprising repeat units from about 10-95 mol % 1,4-cyclohexanedimethanol and from about 90-5 mol % ethylene glycol comprising reacting said dicarboxylic acid component and said glycol component at temperatures sufficient to effect esterification or trans-esterification and polycondensing said reaction product under absolute pressure of less than 10 mm Hg for a time of more than about 2 to about 5 hours in the presence of a catalyst and inhibitor system consisting essentially of about 0-75 ppm Mn, about 25-100 ppm Zn, about 0.5-15 ppm Ti, about 5-80 ppm P, and 0 to about 60 ppm of an organic blue toning agent, all parts by weight based on the weight of the copolyester.
Dependencies are inferred from the claim text.