Solid isocyanate derivatives useful in one component polyurethane adhesives

A process for the preparation of a solid isocyanate terminated prepolymer in the form of a powder, comprising reacting a polyisocyanate with a low molecular weight polyol mixture in the presence of a urethane reaction promoting catalyst, in a solvent in which said polyisocyanate is soluble and in which said solid isocyanate terminated prepolymer is not soluble, and separating said solid isocyanate terminated prepolymer from the reaction mixture, wherein said polyisocyanate is selected from the group consisting of the toluene diisocyanates, the methylene bis(phenylisocyanate)s, the polymethylene polyphenylene polyisocyanates, and the modified isocyanates wherein two of the above isocyanate molecules are linked together with a urea, biuret, carbodiimide, uretdione, uretonimine or urethane linkage;

• wherein said low molecular weight polyol mixture comprises a mixture of simple glycols or triols optionally containing less than 30 weight percent based on the weight of the total polyol mixture of a polyoxyethylene glycol having a molecular weight below about 1000;
• wherein the simple glycol is a straight chain glycol having no more than one alkyl branch located on a carbon to which a hydroxyl group is attached when the glycol hydroxyl groups are not separated by more than two carbon atoms and wherein the monomeric isocyanate and glycol mixture is reacted in a ratio of 1.6 or more mole equivalents of isocyanate to 1 mole equivalent of glycol.