Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
AssigneeEastman Kodak Company
InventorYeong-Jen Kuo
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Abstract
Disclosed are catalyst compositions comprised of the oxides of copper, zinc, and a third element selected from the group consisting of aluminum, magnesium, zirconium, and mixtures thereof, and the use of such catalyst compositions in the hydrogenation of carbonyl compounds such as carboxylate esters to obtain the alcohol corresponding to the acid residue of the ester.
Claims10
A process for hydrogenating a carbonyl compound to the alcohol which corresponds to the carbonyl compound which comprises contacting the carbonyl compound with hydrogen in the presence of a catalyst comprising the oxides of copper, zinc, and a third element selected from the group consisting of aluminum, magnesium, zirconium and mixtures thereof wherein the amount of the oxide of the third component is not more than 4 weight percent under hydrogenation conditions of temperature and pressure.
A process for hydrogenating an ester of an aliphatic or cycloaliphatic carboxylic acid to obtain the alcohol corresponding to the acid residue of the ester which comprises contacting the ester with hydrogen in the presence of a catalyst composition comprising from 10 to about 80 weight percent copper oxide (calculated as CuO), from 10 to 80 weight percent zinc oxide (calculated as ZnO), and from 0.1 to 4 weight percent of an oxide of a third component selected from the group consisting of alumina, magnesia, zirconia and mixtures thereof (calculated as the oxide).
A process for hydrogenating an ester of an aliphatic or cycloaliphatic carboxylic acid to obtain the alcohol corresponding to the acid residue of the ester which comprises contacting the ester with hydrogen in the presence of the catalyst composition consisting essentially of about 35 to 65 weight percent copper oxide, about 35 to 65 weight percent zinc oxide, and 0.1 to 3 weight percent of the third metal oxide selected from the group consisting of alumina, magnesia, zirconia and mixtures thereof (calculated as the oxide) at a hydrogen pressure of about 68 to 170 bars absolute and at a temperature of about 220.degree. to 300.degree. C.
Dependencies are inferred from the claim text.