Process for the production of disposable products from metal chlorides in a titanium dioxide chloride process
AssigneeKronos, Inc.
InventorsDieter Schinkitz, Hans Thumm
Life of this patent
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Abstract
In order to treat metal chlorides obtained in the form of dust collector solids in the production of titanium dioxide by the chloride process, the inert constituents, especially particulate coke, is separated then the metals are selectively precipitated and a maturing phase under oxidative conditions is provided for. The residue consisting of metal hydroxides is also not thixotropic in the absence of inerts. As a result, the material to be deposited has been cut in half.
Claims16
A process for treating metal chlorides obtained in a form of dust collector solids in production of titanium dioxide by the chloride process, to render said metal chloride dumpable, comprising the steps of
- slurrying the dust collector solids in at least one member selected from the group consisting of water and acid to dissolve said metal chlorides,
- separating inert constituents of the dust collector solids from the slurry,
- selectively precipitating metals as metal hydroxides by gradually increasing the pH in the slurry filtrate with a pH value of 5 up to pH values below 12 only after adding an oxidizing agent in a pH range of about 4.2 to 5,
- and making the precipitated metal hydroxides into non-thixotropic filter cake disposable in an environmentally sound waste facility.
Dependencies are inferred from the claim text.