Fuser member with an amino silane adhesive layer
AssigneeXerox Corporation
InventorsPatrick J. Finn, George J. Heeks, Arnold W. Henry, Alan R. Kuntz
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AssigneeXerox Corporation
InventorsPatrick J. Finn, George J. Heeks, Arnold W. Henry, Alan R. Kuntz
Estimating the term…
A fuser member for fusing thermoplastic resin toner images to a substrate has an aluminum base member and an elastomer fusing surface of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent, the elastomer having been cured from a solvent solution thereof with a nucleophilic curing agent soluble in the solution and in the presence of 5 or less than 4 parts by weight of inorganic base per 100 parts of polymer, the inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride, and an adhesive layer between the surface of said aluminum base member and the elastomer fusing surface, the adhesive layer having been cured from a solvent solution of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent and from about 6 to 20 parts by weight per 100 parts by weight of said poly(vinylidenefluoride hexafluoropropylene-tetrafluoroethylene) of an amino silane represented by the formula: ##STR1## where R can be an alkyl group having 1 to 7 carbon atoms; R' can be an alkyl group having 1 to 7 carbon atoms or a polyalkoxyalkyl group of less than 7 carbon atoms; Y is an amino group or an amino substituted alkyl, or a polyamino substituted alkyl, or an alkenylalkoxy amino, or an aryl amino group of less than 15 carbon atoms, h is 1 to 3, b is 0 to 2, q is 1 or 2 and h+b=3.
A fuser member for fusing thermoplastic resin toner images to a substrate in a fuser system of the type wherein a polymeric release agent having functional groups is applied to the surface of the fuser member, the fuser member comprising an aluminum base member and an elastomer fusing surface comprising poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent, said elastomer having been cured from a solvent solution thereof with a nucleophilic curing agent soluble in said solution and in the presence of up to 9 parts by weight of inorganic base per 100 parts of polymer, said inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride, and an adhesive layer between the surface of said aluminum base member and said elastomer fusing surface, said adhesive layer having been cured from a solvent solution of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent and from about 6 to 20 parts by weight per 100 parts by weight of said poly(vinylidenefluoride hexafluoropropylene-tetrafluoroethylene) of an amino silane represented by the formula:
The method of fusing thermoplastic resin toner images to a substrate comprising forming a film of a polymeric release agent having functional groups on the surface of a heated fuser member, said fuser member comprising an aluminum base member and an elastomer fusing surface comprising poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidene fluoride is present in an amount less than 40 mole percent, said elastomer having been cured from a solvent solution thereof with a nucleophilic curing agent soluble in said solution and in the presence of up to 9 parts by weight of inorganic base per 100 parts of polymer, said inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride;
Dependencies are inferred from the claim text.