Tough high performance composite matrix
AssigneeThe United States of America as represented by the Administrator of the National Aeronautics and Space Administration
InventorsRuth H. Pater, Norman J. Johnston
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Abstract
This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit. ##STR1## wherein Z=C or SO.sub.2. Provided is an improved high temperature matrix resin which is capable of performing in the 200.degree. to 300.degree. C. range. This resin has significantly improved toughness and microcracking resistance, excellent processability, mechanical performance and moisture and solvent resistances.
Claims3
A process for preparing a semi-interpenetrating polymer network which process comprises reacting an uncrosslinked, nadic end-capped thermosetting polyimide prepolymer with a polyamic acid precursor of a linear thermoplastic polyimide having the following repeating unit:
- ##STR13## wherein Z.dbd.O.dbd.C or SO.sub.2, to form a semi-2-interpenetrating polymer network, wherein the thermosetting polyimide has a repeating unit which is not identical to the repeating unit of the thermoplastic polyimide.
A process for preparaing a semi-interpenetrating polymer network, which process comprises crosslinking an uncrosslined, nadic end-capped thermosetting polyimide prepolymer in the presence of a linear thermoplastic polyimide having the following repeating unit:
- ##STR14## wherein Z.dbd.O.dbd.C or SO.sub.2, to form a sequential semi-2-interpenetrating polymer network, wherein the thermosetting polymide has a repeating unit which is not identical to the repeating unit of the thermoplastic polyimide.
A process for preparing a semi-interpenetratingpolymer network, which process comprises mixign monomer precursors of a thermosetting polyimide having a nadic end group acting as a crosslinking site, and monomer precursors of a linear thermoplastic polyimide having the following repeating unit:
- ##STR15## wherein Z.dbd.O.dbd.C or SO.sub.2, and allowing all said precursors to react randomly to form a simultaneous semi-interpenetrating polymer network, wherein the thermosetting polyimide has a repeating unit which is not identical to the repeating unit for the thermoplastic polyimide.
Dependencies are inferred from the claim text.