# US 5,331,061 A · Thermoplastically processable elastomeric block copolyetheresteretheramides and processes for the production and use thereof

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- Number: US 5,331,061 A
- Document ID: US5331061A
- Status: Granted
- Kind: A
- Application number: 07/988,346
- Filed: 1992-12-09
- Granted: 1994-07-19
- Earliest claimed: 1989-05-24
- Assignees: EMS-Inventa AG
- Inventors: Hanns-Jorg Liedloff
- Web page: https://patentgrep.com/patent/US5331061A

## CPC

- C08G 69/44: Polyester-amides
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

Thermoplastically processable elastomeric block copolyetheresteretheramides from recurring units of the formula ##STR1## in which ##STR2## represents a polyamide segment containing terminal carboxyl groups and having an average molar mass of 700 to 10 000, --O--E--O-- is a poly-(oxytetramethylene)-segment having an average molar mass of 600 to 3 500, --NH--F--NH-- represents a poly-(oxy-1,2-propylene)-segment containing terminal amino groups and having an average molar mass of 350 to 2 500, x and y are integers from 3 to 35 and indicate the number of the respective, randomly arranged, recurring units, the ratio x:y of components A and B varying between 5:1 and 1:5. The ether amides of the present invention can optionally be mixed with additives, fillers, modifiers, or other compatible polymers normally used in the processing of polyamides and which are suitable for the production of molded articles, for example by injection molding, coinjection, extrusion, blow molding, etc.

## Claims

### Claim 1

A thermoplastically processable, elastomeric, block copolyetheresteretheramide compound which consists of randomly arranged, recurring polyetheresteramide units A and polyetheramide units B in a ratio of units A to units B of 5:1 to 1:5, said units A and said units B being connected through ester and/or amide linkages,
said units A being of Formula I ##STR5## there being 3 to 35 of said Formula I in each of said units A; said units B being of Formula II ##STR6## there being 3 to 35 of said Formula II in each of said units B; and wherein
D represents a divalent radical which remains after the removal of the carboxylic groups from a polyamide with terminal carboxylic groups having a molar mass of 700 to 10000 g/mol, and
E is a divalent radical which remains after the removal of the hydroxyl groups from poly(oxytetramethylene) with terminal hydroxyl groups having a molar mass of 600 to 3500 g/mol, and
F is a divalent radical which remains after the removal of the amino groups from poly-(oxy-1,2-propylene) with terminal amino groups having a molar mass of 350 to 2500 g/mol,
said compounds having a modulus of flexural elasticity of about 40 to about 700 N/mm.sup.2.

### Claim 2 (depends on 1)

The compound of claim 1 wherein said polyamide with terminal carboxylic groups comprises a reaction product of dicarboxylic acids with a monomer selected from the group consisting of lactams, .omega.-amino-.omega.-carboxylic acids, and mixtures thereof.

### Claim 3 (depends on 2)

The compound of claim 2 wherein said lactams have 6 to 12 carbon atoms.

### Claim 4 (depends on 2)

The compound of claim 2 wherein said .omega.-amino-.alpha.-carboxylic acids have 6 to 12 carbon atoms.

### Claim 5 (depends on 2)

The compound of claim 2 wherein said lactams and said .omega.-amino-.alpha.-carboxylic acids have 11 or 12 carbon atoms.

### Claim 6 (depends on 2)

The compound of claim 2 wherein said dicarboxylic acids have 6 to 36 carbon atoms.

### Claim 7 (depends on 2)

The compound of claim 2 wherein said lactams are caprolactam, lauryl lactam, or mixtures thereof.

### Claim 8 (depends on 1)

The compound of claim 1 wherein said polyamide segment is derived from .omega.-aminocarboxylic acid, adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, dimerized fatty acid, or mixtures thereof.

### Claim 9 (depends on 8)

The compound of claim 8 wherein said .omega.-aminocarboxylic acid is selected from the group consisting of .omega.-aminoundecanoic acid, .omega.-aminolauric acid, and mixtures thereof.

### Claim 10 (depends on 1)

The process for the production of the compound of claim 1 comprising polycondensation of carboxylic terminated polyamides with an equimolar quantity of .alpha.-.omega.-dihydroxy-poly(oxytetramethylene) and .alpha.-.omega.-diaminopolyoxy-1,2-propylene.