Back to results
US 5,330,686 AGranted
Temperature stable and sunlight protected photochromic articles
AssigneePPG Industries, Inc.
InventorsRobert A. Smith, Barry Van Gemert
Life of this patent
Estimating the term…
Abstract
Described is a photochromic composition which is a polymerizate of acrylate monomer(s), a crosslinking amount of anhydrous acrylic anhydride and/or anhydrous methacrylate anhydride and a photochromic amount of pyrido benzoxazine. Depending on the amount of crosslinking agents and the other components selected to form the polymerizate, the polymerizate will exhibit improved temperature stability with regard to photocolorability and/or prevention of activation in sunlight.
Claims19
A photochromic article comprising:
- (a) the polymerizate of
- i. at least one monomer selected from monomers represented by the graphic formula, ##STR4## wherein R.sub.o is selected from the group consisting of hydrogen and methyl, R is selected from the group consisting of C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 ethylenically unsaturated alkyl(alkenyl), C.sub.5 -C.sub.8 cycloalkyl, hydroxy (C.sub.1 -C.sub.4) alkyl, C.sub.1 -C.sub.4 alkoxy (C.sub.2 -C.sub.4) alkyl, C.sub.2 -C.sub.4 oxiranyl, C.sub.1 -C.sub.8 amino alkyl, C.sub.1 -C.sub.4 alkoxy (C.sub.1 -C.sub.4) alkoxy (C.sub.2 -C.sub.4) alkyl, phenyl, substituted phenyl, phenyl (C.sub.1 -C.sub.9) alkyl, substituted phenyl (C.sub.1 -C.sub.9) alkyl, phenoxy (C.sub.1 -C.sub.9) alkyl and substituted phenoxy (C.sub.1 -C.sub.9) alkyl, wherein the phenyl substituents are represented by X.sub.m and wherein X is selected from the group consisting of C.sub.1 -C.sub.9 alkyl, cyano, chloro, bromo, methoxy, nitro, amino, methylthio and m is selected from the integers 1-5, and n is selected from the integers 1-4;
- and
- ii. a crosslinking amount of a material selected from the group consisting of anhydrous methacrylic anhydride, anhydrous acrylic anhydride, and mixtures of such anhydrides;
- and
- (b) a photochromic amount of a photochromic material selected from the group consisting of spiro(indoline) pyrido benzoxazine and spiro(benzindoline) pyrido benzoxazine, said polymerizate being permeable to ultraviolet and visible light.
3 more elements
Dependencies are inferred from the claim text.