Bleaching composition
AssigneeKao Corporation
InventorsKohshiro Sotoya, Muneo Aoyagi, Nobuyuki Ogura, Youhei Kaneko
Life of this patent
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Abstract
A bleaching composition comprises (a) hydrogen or a peroxide to produce hydrogen peroxide in its aqueous solution and (b) an organic peracid precursor having the formula (I) in which a quaternary ammonium is connected with an alkyl through an ether, an amide or an ester. ##STR1##
Claims17
A bleaching composition which comprises (a) a peroxygen compound capable of yielding hydrogen peroxide in an aqueous solution and (b) an organic peracid precursor having the formula (I):
- ##STR30## where R.sub.1 is selected from the group consisting of a straight-chain or branched-chain C.sub.1 -C.sub.20 alkyl or alkenyl group which may have a substituent group and, an unsubstituted or C.sub.1 -C.sub.20 alkyl-substituted aryl group;
- X is selected from the group consisting of ##STR31## Y is selected from the group consisting of ##STR32## where n is an integer of 1 to 10,
- R.sub.2 and R.sub.3 each is selected from the group consisting of a C.sub.1 -C.sub.3 alkyl group which may have a substituent group,
- R.sub.4 and R.sub.5 each is selected from the group consisting of a C.sub.1 -C.sub.12 alkylene group which may have a substituent group, ##STR33## L is a leaving group selected from the group consisting of ##STR34## where R.sub.6 and R.sub.9 each is a alkyl group, R.sub.7 and R.sub.8 each is selected from the group consisting of hydrogen or an alkyl group, and M.sup.+ denotes an alkali metal ion or hydrogen ion or a glycerin residue or sugar residue, and X is selected from the group consisting of an inorganic or organic counter ion, provided that when L is selected from the group consisting of ##STR35## X.sup.- does not exist.
A bleaching composition which comprises (a) a peroxygen compound capable of yielding hydrogen peroxide in an aqueous solution and (b) an organic peracid precursor having the formula (I):
- ##STR37## where R.sub.1 is selected from the group consisting of a straight-chain or branched-chain C.sub.1 -C.sub.20 alkyl or alkenyl group which may have a substituent group, an unsubstituted or C.sub.1 -C.sub.20 alkyl-substituted aryl group;
- X is ##STR38## Y is selected from the group consisting of ##STR39## where n is an integer of 1 to 10, R.sub.2 and R.sub.3 each is selected from the group consisting of a C.sub.1 -C.sub.3 alkyl group which may have a substituent group,
- R.sub.4 and R.sub.5 each is selected from the group consisting of a C.sub.1 -C.sub.12 alkylene group which may have a substituent group, ##STR40## L is a leaving group selected from the group consisting of ##STR41## where R.sub.6 and R.sub.9 each is an alkyl group, R.sub.7 and R.sub.8 each is selected from the group consisting of hydrogen or an alkyl group, and M.sup.+ denotes an alkali metal ion or hydrogen ion or a glycerin residue or sugar residue, and X is selected from the group consisting of an inorganic or organic counter ion, provided that when L is selected from the group consisting of ##STR42## X.sup.- does not exist.
A bleaching composition which comprises (a) a peroxygen compound capable of yielding hydrogen peroxide in an aqueous solution and (b) an organic peracid precursor having the formula (I):
- ##STR43## where R.sub.1 is selected from the group consisting of a straight-chain or branched-chain C.sub.1 -C.sub.20 alkyl or alkenyl group which may have a substituent group, and an unsubstituted or C.sub.1 -C.sub.20 alkyl-substituted aryl group, X is
- --O--
- Y is R.sub.5
- R.sub.4 and R.sub.5 and R.sub.3 each is selected from the group consisting of a C.sub.1 -C.sub.3 alkyl group which may have a substituent group,
- R.sub.5 is selected from the group consisting of a C.sub.1 -C.sub.12 alkylene group which may have a substituent group, ##STR44## L is a leaving group selected from the group consisting of ##STR45## where R.sub.6 and R.sub.9 each is an alkyl group, R.sub.7 and R.sub.8 each is selected from the group consisting of hydrogen or an alkyl group, and M.sup.+ denotes an alkali metal ion or hydrogen ion or a glycerin residue or sugar residue, and X is selected from the group consisting of an inorganic or organic counter ion, provided that when L is selected from the group consisting of ##STR46## X.sup.- does not exist.
A bleaching composition which comprises (a) a peroxygen compound capable of yielding hydrogen peroxide in an aqueous solution and (b) an organic peracid precursor having the formula (I):
- ##STR48## where R.sub.1 is selected from the group consisting of a straight-chain or branched-chain C.sub.1 -C.sub.20 alkyl or alkenyl group which may have a substituent group, and an unsubstituted or C.sub.1 -C.sub.20 alkyl-substituted aryl group, X is ##STR49## Y is R.sub.5 R.sub.2 and R.sub.3 each is selected from the group consisting of a C.sub.1 -C.sub.3 alkyl group which may have a substituent group,
- R.sub.4 and R.sub.5 each is selected from the group consisting of a C.sub.1 -C.sub.12 alkylene group which may have a substituent group, ##STR50## L is a leaving group selected from the group consisting of ##STR51## where R.sub.6 and R.sub.9 each is an alkyl group, R.sub.7 and R.sub.8 each is selected from the group consisting of hydrogen or an alkyl group, and M.sup.+ denotes an alkali metal ion or hydrogen ion or a glycerin residue or sugar residue, and X is selected from the group consisting of an inorganic or organic counter ion, provided that when L is selected from the group consisting of ##STR52## X.sup.- does not exist.
A bleaching composition which comprises (a) a peroxygen compound capable of yielding hydrogen peroxide in an aqueous solution and (b) an organic peracid precursor having the formula (I):
- ##STR53## where R.sub.1 is selected from the group consisting of a straight-chain or branched-chain C.sub.1 -C.sub.20 alkyl or alkenyl group which may have a substituent group, and an unsubstituted or C.sub.1 -C.sub.20 alkyl-substituted aryl group, X is ##STR54## Y is R.sub.5 R.sub.2 and R.sub.3 each is selected from the group consisting of a C.sub.1 -C.sub.3 alkyl group which may have a substituent group,
- R.sub.4 and R.sub.5 each is selected from the group consisting of a C.sub.1 -C.sub.12 alkylene group which may have a substituent group, ##STR55## L is a leaving group selected from the group consisting of ##STR56## where R.sub.6 and R.sub.9 each is an alkyl group, R.sub.7 and R.sub.8 each is selected from the group consisting of hydrogen or an alkyl group, and M.sup.+ denotes an alkali metal ion or hydrogen ion or a glycerin residue or sugar residue, and X is selected from the group consisting of an inorganic or organic counter ion, provided that when L is selected from the group consisting of ##STR57## X.sup.- does not exist.
Dependencies are inferred from the claim text.