Propylene (co)polymer and process for the preparation of the same
AssigneeKao Corporation
InventorsYoshihiro Hasebe, Takayuki Amiya, Yutaka Yasuda
Life of this patent
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Abstract
A propylene (co) polymer terminated with a reactive group and a process for the preparation of the same. A graft copolymer having a specific side chain and a process for the preparation of the same. The propylene (co) polymer is usable as a radial- or ion-polymerizable propylene macromonomer or as an intermediate for the preparation of a block polymer. Examples of the application thereof include compatibizing agent for polymers, light- or laser-curable plastic, viscosity index and surface modifier. The graft copolymer is useful as a surface modifier or compatibilizing agent for polypropylene or a dispersant for fillers.
Claims16
A process for the preparation of a propylene (co)polymer having a polymerizable group represented by the following general formula ##STR11## at one terminal thereof, comprising the steps of:
- (a) (co)polymerizing propylene in the presence of polymerization catalysts comprising a catalyst component (x) containing a vanadium compound represented by the general formula (III):
- ##STR12## wherein R.sup.3 to R.sup.5 each represents a hydrogen atom or a hydrocarbyl group having 1 to 8 carbon atoms, except a case wherein the three groups are simultaneously hydrogen atoms, and an organometallic compound (y) having a metal of a Group I, II or III of the periodic table to form a propylene (co)polymer having a reactive terminal;
- (b) reacting the propylene (co)polymer having a reactive terminal of step (a) with an aromatic divinyl compound represented by the following general formula (IV):
- ##STR13## wherein the relative position of the two substituents on the benzene ring may be any of the o-, m- and p-positions;
- and (c) reacting the resulting propylene (co)polymer of step (b) with a proton donor or a halogen molecule.
A graft copolymer comprising a main chain originated from a vinyl compound and a side chain originated from a propylene (co)polymer having a polymerizable group of the formula ##STR15## at one terminal thereof.
Dependencies are inferred from the claim text.